SoS RARE - Security of Supply of Rare Earth Elements

Lead Research Organisation: University of St Andrews
Department Name: Earth and Environmental Sciences

Abstract

Rare earth elements (REE) are the headline of the critical metals security of supply agenda. All the REE were defined as critical by the European Union in 2010, and in subsequent analysis in 2014. Similar projects in the UK and USA have highlighted 'heavy' REE (HREE - europium through to lutetium) as the metals most likely to be at risk of supply disruption and in short supply in the near future. The REE are ubiquitous within modern technologies, including computers and low energy lighting, energy storage devices, large wind turbines and smart materials, making their supply vital to UK society. The challenge is to develop new environmentally friendly and economically viable, neodymium (Nd) and HREE deposits so that use of REE in new and green technologies can continue to expand.

The principal aims of this project are to understand the mobility and concentration of Nd and HREE in natural systems and to investigate new processes that will lower the environmental impact of REE extraction and recovery.

By concentrating on the critical REE, the research will be wide ranging in the deposits and processing techniques considered. It gives NERC and the UK a world-leading research consortium on critical REE, concentrating on deposit types identified in the catalyst phase as most likely to have low environmental impact, and on research that bridges the two goals of the SoS programme.
The project brings together two groups from the preceding catalyst projects (GEM-CRE, MM-FREE) to form a new interdisciplinary team, including the UK's leading experts in REE geology and metallurgy, together with materials science, high/low temperature fluid geochemistry, computational simulation/mineral physics, geomicrobiology and bioprocessing. The team brings substantial background IP and the key skills required. The research responds to the needs of industry partners and involves substantive international collaboration as well as a wider international and UK network across the REE value chain.

The work programme has two strands. The first centres on conventional deposits, which comprise all of the REE mines outside China and the majority of active exploration and development projects. The aim is to make a step change in the understanding of the mobility of REE in these natural deposits via mineralogical analysis, experiments and computational simulation. Then, based on this research, the aim is to optimise the most relevant extraction methods. The second strand looks to the future to develop a sustainable new method of REE extraction. The focus will be the ion adsorption deposits, which could be exploited with the lowest environmental impact of any of the main ore types using a well-controlled in-situ leaching operation.

Impact will be immediate through our industry partners engaged in REE exploration and development projects, who will gain improved deposit models and better and more efficient, and therefore more environmentally friendly, extraction techniques. There will be wider benefits for researchers in other international teams and companies as we publish our results. Security of REE supply is a major international issue and the challenges tackled in this research will be relevant to practically all REE deposits. Despite the UK not having world class REE deposits itself, the economy is reliant on REE (e.g. the functional materials and devices industry is worth ~£3 Bn p.a.) and therefore the UK must lead research into the extraction process. Manufacturers who use REE will also benefit from the research by receiving up to date information on prospects for future Nd and HREE supply. This will help plan their longer term product development, as well as shorter term purchasing strategy. Likewise, the results will be useful to inform national and European level policy and to interest, entertain and educate the wider community about the natural characters and importance of the REE.

Planned Impact

SoS RARE research will have an immediate economic impact by improving the prospects for the security of supply of neodymium (Nd) and the key heavy rare earth elements (HREE). The proposal has engaged six core industry partners involved in the exploration and development of new REE mines who will benefit immediately by introduction of our new exploration models and improved techniques for mineral extraction. Processing of REE raw materials is currently a major bottle neck in the value chain, and development of better methods will have an immediate impact on REE supply concerns. This will make projects more economically viable and environmentally friendly, helping to ensure a more stable supply. The four consultant company partners will gain key expertise and experience in exploration and processing which they will spread out into the wider REE mining and processing industries.

The unstable supply and cost of REE remains a major issue for manufacturers that make up a substantial part of the UK economy. A more secure supply chain will allow these manufacturers to better plan their short and long term product development. The research team will provide information on primary supplies, the likely development of future mines and how the supply chain will develop.

REE supply is a global concern. The project will have a global reach, through the industry partners involved (based in and working in the UK, Greenland, Malawi, Namibia, Spain, Canada and Australia), the core research collaborators in Germany, USA, Canada, Brazil and South Africa and wider international network links to Japan, France, and Madagascar. Diversity of supply is the key. This research proposal will place the UK as a centre in REE expertise and at the forefront of critical metals development.

The critical metals issue is requiring changes in UK Government and European Union policy, including increased support for research ion primary supplies, recycling of existing metal stocks and substitution. The impact of this research on the prospects for low environmental impact extraction of REE, diversity/security of supply and responsible sourcing will be directly relevant to future policy. The 'race' to engineer REE out of new technologies will be unnecessary and many new applications could be explored. Therefore major impact will occur at the policy level as the research guides the decision making in research funding and legislation for REE.

Few people had even heard of 'rare earths' until the issue of China restricting supply reached the news headlines in 2010, yet this family of elements are ubiquitous in digital and green technologies, from the slimmest mobile phones to giant wind turbines. We will exploit the realisation among the general public of the importance of REE towards their modern high technology life-style and demonstrate the importance of REE chemistry and geology. The REE are extremely interesting and ideal for creative and educational outputs to entertain and inform wider non-technical audiences. Encouraging the public, including school students, to learn more about REE in nature is a key part of our outreach programme.

Publications

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Anouk Margaretha Borst (2019) Resolving the structural state of heavy rare earth elements in lateritic ion adsorption clays in LIFE WITH ORE DEPOSITS ON EARTH, PROCEEDINGS OF THE 15TH SGA BIENNIAL MEETING, 2019, VOLS 1-4

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Beard C (2023) Alkaline-Silicate REE-HFSE Systems in Economic Geology

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Horsburgh N (2023) Lanthanide and yttrium substitution in natural fluorite in Physics and Chemistry of Minerals

 
Description 1. Current sorting technologies use X-rays and lasers as excitation methods, measuring X-ray transmission (XRT) and X-ray fluorescence (XRF) of industrial minerals, base/precious metals, and diamonds. Usually composition is explored by XRF or XRT but visible light is also emitted during X-irradiation and hence the upgrading of luminescence technology to existing sorting systems is viable. The luminescence of minerals is sufficiently varied that it can be used as a sensitive identification tool. Even if an ore mineral does not luminesce, it may be that the associated gangue gives a signal and then we remove the luminescent material and comminute that without a signal. Hence luminescence-based sorting can be a discriminator to underpin smart sorting, if the basic characterisation of target minerals is determined for the locality of interest.
2. Lateritic Ion Adsorption Deposits (IADs) are the world's dominant source for heavy rare earth elements (HREE: Gd-Lu). Potentially higher grade IADs are being explored in Brazil, Madagascar and South East Asia, and may provide alternative supplies. We characterized economically mineralised IADs from the Zhaibei granite, China, and compared them to prospective IADs from Madagascar. We used X-ray Absorption Spectroscopy (XAS) to study the distribution and coordination state of light (Nd) and heavy REE (Y). The Malagasy and Chinese laterite samples have kaolinite as the dominant REE-hosting clay phase, with minor halloysite. XAS data demonstrate that the heavy REE occur as 8-coordinated outer-sphere basal surface complexes on kaolinite, rather than 5- or 6-coordinated edge complexes, or 6- or 8-coordinated interlayer complexes, thus confirming the truly adsorbed nature of REE in lateritic IAD's from both localities.
Exploitation Route Automated smart sorting of ore before grinding - uses in the mining industry and in the core logging sector.
Sectors Energy,Other

URL http://www.adrianfinch.co.uk
 
Description Sorting of ore prior to grinding would significantly reduce energy requirements of processing. Automated sorting separates the ore material from gangue. We have communicated to several mining and core logging companies about the potential of luminescence sorting of REE minerals prior to grinding to reduce the environmental impact of mining. Characterisation of the REE coordination in key rare earth-bearing minerals has been completed. This allows mining companies to understand the exact nature of the ores, notably eudialyte (for heavy REE) and ion adsorption clays. We recognise regoliths that structurally identical to those currently exploited in South Eastern China from areas in Madagascar. We show that the materials in China are not necessarily unique and equivalent deposits may be found elsewhere in the globe.
First Year Of Impact 2018
Sector Energy,Other
Impact Types Societal,Economic

 
Description Advisor to Government Office of Science (GO-Science)
Geographic Reach National 
Policy Influence Type Participation in a guidance/advisory committee
Impact The UK national risk assessment was modified to include information provided by Adrian Finch as one of the committee members with a particular interest on critical metal policy
 
Description Symposium at Scotland House, Brussels associated with EU Critical Raw Materials Act 2022
Geographic Reach Europe 
Policy Influence Type Contribution to a national consultation/review
URL https://ec.europa.eu/info/law/better-regulation/have-your-say/initiatives/13597-European-Critical-Ra...
 
Description Smart Sorting for the Sustainable Production of Critical e-Tech Elements
Amount £29,413 (GBP)
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 03/2021 
End 07/2022
 
Title Coordination State of Metals in Mineral Systems 
Description The purpose of this doi is to host raw data associated with our publications using X-ray Absorption Spectroscopy to probe the structural state of metals in mineral systems. It includes data from several publications, divided into subdirectories, as well as data collected which were not deemed suitable for publication. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk:443/portal/en/datasets/coordination-state-of-metals-in-mineral-syste...
 
Title Quantifying metasomatic HFSE-REE transport from alkaline magmas (Supplementary Dataset) 
Description .xls file containing the geochemical whole-rock data, standards, GPS locations, and several sheets containing geometric modelling of an alkaline Illerfissalik intrusion in SW Greenland 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
Impact Licence holder to the Motzfeldt region used the data provided here to improve the genetic model and resource estimates of one of Europe's largest Ta and Nb deposits 
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/quantifying-metasomatic-hfseree-transport-from-al...
 
Description Anouk interviewed for Women in Science 
Form Of Engagement Activity A press release, press conference or response to a media enquiry/interview
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Media (as a channel to the public)
Results and Impact Interview by the Daily Record to celebrate Women in Science
Year(s) Of Engagement Activity 2017
URL https://wordpress.com/post/adrianfinchcouk.wordpress.com/310
 
Description Attendance at House of Commons select committee on mining and quarrying 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Policymakers/politicians
Results and Impact Making the committee aware of the research in SoS RARE
Year(s) Of Engagement Activity 2018
 
Description Invited Talk at Goldschmidt 2021 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Anouk Borst gave an invited talk at Goldschmidt 2021 in session 7g (Mineral-scale analysis and geochemistry in service of Economic Geology): Borst AM, Finch AA, Horsburgh NJ, Smith M, Geraki K (2021) "Alteration and weathering in peralkaline silicate-hosted REE-HFSE deposits".
Year(s) Of Engagement Activity 2021
 
Description Keynote at RawMat2021 Athena 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Adrian Finch and Nicky Horsburgh were both invited to give keynotes to the RawMat 2021 conference in Greece in September 2021. Adrian presented both presentations including one talk on the genesis of critical metal ore deposits and another presenting Nicky's PhD research on smart sorting. These were invitations coming directly from SoS RARE funded research.
Year(s) Of Engagement Activity 2021
URL https://www.rawmat2021.gr/congress/
 
Description The Fractional Crystallization Freak Zone 
Form Of Engagement Activity A press release, press conference or response to a media enquiry/interview
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Blog piece for the Volcanic Division of the European Geosciences Union on the resource potential of peralkaline rocks
Year(s) Of Engagement Activity 2017
URL https://wordpress.com/post/adrianfinchcouk.wordpress.com/302
 
Description Visit to Brazil 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Visit to University of Sao Paolo, Brazil, and mine visit to CBMM, Araxa, Brazil
Year(s) Of Engagement Activity 2017
URL https://wordpress.com/post/adrianfinchcouk.wordpress.com/316
 
Description Work Highlighted by Nature Group as one of the their highlight papers from 2020 
Form Of Engagement Activity A magazine, newsletter or online publication
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Nature group highlighted our 2020 Borst et al. Nature Communications paper as one of its 'highlight papers' for 2020.
Year(s) Of Engagement Activity 2020
URL https://www.nature.com/collections/eihfbddfac
 
Description Work Highlighted by the Rare Earth Industries Association 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact The Rare Earth Industries Association invited us to its launch in 2019. It then highlighted two our papers written as part of SOS Rare in its newsletter taking them as lead articles in both cases. Borst et al. (2020) Min Mag, Borst et al. (2020) Nature Comms.
Year(s) Of Engagement Activity 2020
URL https://mailchi.mp/94f488701c2f/reia-weekly-newsletter-4152857?e=4608875878