The University of St Andrews - Equipment Account

Lead Research Organisation: University of St Andrews
Department Name: Office of the Principal

Abstract

The purpose of this proposal is to bring together a new facility to provide state of the art capability to analyse and control functional materials at the nanoscale to underpin and drive forward critical materials research in energy materials, photonics, metamaterials and electronics. It is intended to use this facility to support approximately 180 materials researchers at the University of St Andrews and extend this capability to users outside St Andrews in both academia and industry. It builds on the outstanding record of St Andrews in high quality research and investment in advanced materials research by the University, SFC, EPSRC, and industry as well as our experience of sharing our facilities with external users.

Planned Impact

Separate document not required, please see the Case for Support for details

Publications

10 25 50
 
Description A range of new drug targets, molecules for clean synthesis and light harvesting/converting systems have been discovered and refined.

The strategic equipment grant "Designer oxides" has formed the nucleus of a new Centre at the University of St Andrews, which combines a set of unique research infrastructures, including angular resolved photoemission spectroscopy and low-temperature scanning tunneling microscopy. It has created a unique centre to study the emergent states of quantum materials and create and design novel quantum materials in thin film form, ultimately to make them amenable for device fabrication and to enable transformative advances in information processing. First results from the research enabled through this equipment have already appeared in leading journals, and demonstrate the power of our integrated approach to study quantum materials. We have been able to show how emergent states change with reduced dimensionality, showing new routes to control them and make them useful for potential future device applications.

Elucidation via computational modelling of the chemical rules governing the evolution of planetary ices (L. J. Conway et al., publication 5 in the list above).

Development of an experimental method to read out the local carrier concentration in a moiré superlattice based on optical activity of interlayer excitons (H. Baek et al., publication 6 in the list above).
Exploitation Route Published work is influencing science and industry, some systems are being dveloped in collaboration with appropriate industries

The equipment has already enabled us to attract substantial research funding, and we are working to further explore quantum materials in thin films form. Samples grown using the Molecular Beam Epitaxy system have been given to researchers outside the University of St Andrews for further study, and have been used for studies at international facilities.
Sectors Chemicals,Digital/Communication/Information Technologies (including Software),Electronics,Energy,Pharmaceuticals and Medical Biotechnology

URL http://www.cdqm.uk
 
Description The equipment has supported a range of collaborative projects with industry eg drug design, catalyst development, energy storage and conversion systems This grant has formed the heart-piece of the Centre for Designer Quantum Materials, a centre which has attracted substantial funding from ESPRC, ERC, Leverhulme, and the Royal Society as well as talented scientists (e.g. on an EPSRC fellowship) from outside the UK. The Centre provides a unique combination of infrastructure, bringing UK research on designer quantum materials to the forefront at an internationally competitive level. The Molecular Beam Epitaxy System funded through this grant enables layered growth of designer oxide heterostructures, with control over the precise composition of each layer. It opens the door to exploitation of the exciting emergent properties of transition metal oxides for novel electronics exploiting these, a route which has been suggested in the Roadmap of the International Semiconductor Technology Group as a possible way to further increase the performance of information technology. The centre has attracted substantial attraction in the press, with an opening that has been covered by STV and BBC, and which was featured by BBC shortly after its opening. The equipment of the Centre has a lifetime of a couple of decades and more, and we are expecting its socio-economic impacts to be realized only in the coming decades. • Narrative Impact (a) Workshop facilities (Edinburgh) These are housed at the University of Edinburgh, include the following equipment: o SLX 355 (CNC lathe); o SMX 3500 (CNC milling machine); o Stratasys Objet30 Prime (3D printer). This allows rapid prototyping or machining of custom experimental apparatus, as well as facilitating skills development in practical skills and technical design. This equipment is used for the training of CM-CDT students, and also supports the research of several of the CM-CDT's constituent research groups. (b) Computer cluster (Edinburgh) Currently this cluster consists of eight active nodes (512 CPU cores); six of these nodes (384 cores) were part of the original capital equipment funding. Usage remains high, with 43 users registered and 19 users active since March 2021. In total, just over 120 years' worth of CPU time were used for calculations in that time. (c) Atomic layer deposition equipment (St Andrews) The Atomic Layer Deposition (ALD) system continues to be used regularly by PhD students and PDRAs. Aligned PhD student Mohammad Biabanifard, working with Prof. Andrea DiFalco, has recently started using the ALD regularly to develop a fabrication approach for holographic metasurfaces in the visible range. This work will be a key part of his PhD and it is expected that it will lay the basis for future publications and knowledge transfer activities. The work is in the preliminary stages and hasn't yet produced any publications. (d) Hydraharp picosecond event timer The Hydraharp is used in several laboratories to measure correlation functions of photons emitted by quantum dots or entangled photons from parametric downconversion processes. Several CDT students have made use of this equipment during their training or their research. In particular, CM-CDT students Zak Koong, Aidan Campbell, Guillem Ballesteros-Garcia, Micaela Laini, Artur Branny, and Eleanor Scerri have used / are using it heavily during their PhDs. Additional PhD students at Heriot-Watt University that have used it heavily include Raphael Picard, Daniel White, Muhammad Junaid Arshad, Maximilian Kögl, Daniel Forbes, and Ted Santana. We estimate that 15 publications and around 30 conference talks have been based wholly or partly on research carried out using the Hydraharp equipment. The femtosecond laser equipment is regularly used to measure TADF materials from Eli's group by Abhishek, Stefan, Leon and Tomas Matulaitis, they use it at least two days a week, sometimes more. No external visitors in the past year but I did time-resolved PL measurements for the group of Dr. K. D. G. I. Jayawardena and Prof. S. R. P. Silva at the Department of Electrical and Electronic Engineering, University of Surrey in April 2021 of the hybrid materials for X-ray detectors based on P3HT:PCBM blends with Bi2O3 nanoparticles and in P3HSe:PCBM blends. I used time-resolved PL quenching to determine domain sizes. I attach the published paper and they are preparing a new publication on morphology. Other internal measurements were on Jonathon's and Lethy's solar cell materials and devices. The femtosecond lab funded by the equipment grant has been used about 50% of time - much of it by users from Prof Zysman-Colman's group in chemistry, and as noted below to do measurements for researchers at the University of Surrey, leading to a paper. The work for St Andrews researchers has also led to papers included above. The grant for designer oxides has resulted in follow-on funding to investigate the antiviral properties of surface, to help fight the pandemic (the relevant grant is MR/V028464/1).
First Year Of Impact 2016
Sector Chemicals,Electronics,Energy,Environment,Healthcare,Other
Impact Types Cultural,Societal

 
Title A Deep Blue Heteroatom Doped Nonacene That Exhibits MR-TADF and its Use as an Emitter in High-Performance Deep Blue Organic Light-Emitting Diodes (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/a-deep-blue-heteroatom-doped-nonacene-that-exhibi...
 
Title A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Atomic-scale imaging of emergent order at a magnetic-field induced Lifshitz transition (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/atomicscale-imaging-of-emergent-order-at-a-magnet...
 
Title Barrierless Slow Dissociation of Photogenerated Charge Pairs in High-Performance Polymer-Fullerene Solar Cells (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? Yes  
 
Title CCDC 2033769: Experimental Crystal Structure Determination 
Description Related Article: Abhishek Kumar Gupta, Wenbo Li, Arvydas Ruseckas, Cheng Lian, Cameron L. Carpenter-Warren, David B. Cordes, Alexandra M. Z. Slawin, Denis Jacquemin, Ifor D. W. Samuel, Eli Zysman-Colman|2021|ACS Applied Materials and Interfaces|13|15459|doi:10.1021/acsami.1c02248 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc2689g8&sid=DataCite
 
Title CCDC 2049645: Experimental Crystal Structure Determination 
Description Related Article: Zhen Zhang, Stefan Diesing, Ettore Crovini, Abhishek Kumar Gupta, Eduard Spuling, Xuemin Gan, Olaf Fuhr, Martin Nieger, Zahid Hassan, Ifor D. W. Samuel, Stefan Bra¨se, Eli Zysman-Colman|2021|Org.Lett.|23|6697|doi:10.1021/acs.orglett.1c02273 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc26stlf&sid=DataCite
 
Title CCDC 2060146: Experimental Crystal Structure Determination 
Description Related Article: Simon M. Vornholt, Caroline G. Elliott, Cameron M. Rice, Samantha E. Russell, Peter J. Kerr, Daniel N. Rainer, Michal Mazur, Mark R. Warren, Paul S. Wheatley, Russell E. Morris|2021|Chem.-Eur.J.|27|8537|doi:10.1002/chem.202100528 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc274rbh&sid=DataCite
 
Title CCDC 2061107: Experimental Crystal Structure Determination 
Description Related Article: Pachaiyappan Rajamalli, Federica Rizzi, Wenbo Li, Michael A. Jinks, Abhishek Kumar Gupta, Beth A. Laidlaw, Ifor D. W. Samuel, Thomas J. Penfold, Stephen M. Goldup, Eli Zysman-Colman|2021|Angew.Chem.,Int.Ed.|60|12066|doi:10.1002/anie.202101870 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc275rbj&sid=DataCite
 
Title CCDC 2086119: Experimental Crystal Structure Determination 
Description Related Article: Gloria Hong, Changfeng Si, Abhishek Kumar Gupta, Claudia Bizzarri, Martin Nieger, Ifor D. W. Samuel, Eli Zysman-Colman, Stefan Bräse|2022|J.Mater.Chem.C|10|4757|doi:10.1039/D1TC04918F 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc280s58&sid=DataCite
 
Title CCDC 2094658: Experimental Crystal Structure Determination 
Description Related Article: Abhishek Kumar Gupta, Tomas Matulaitis, David B. Cordes, Alexandra M.Z. Slawin, Ifor D.W. Samuel, Eli Zysman-Colman|2022|Can.J.Chem.|100|224|doi:10.1139/cjc-2021-0208 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc289nmw&sid=DataCite
 
Title CSD 2039327: Experimental Crystal Structure Determination 
Description Related Article: Ivalina B. Minova, Nathan S. Barrow, Andrea C. Sauerwein, Aaron B. Naden, David B. Cordes, Alexandra M.Z. Slawin, Stephen J. Schuyten, Paul A. Wright|2021|J.Catalysis|395|425|doi:10.1016/j.jcat.2021.01.012 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.25505/fiz.icsd.cc26g2rj&sid=DataCite
 
Title Cation ordering and exsolution behaviour in Cu-containing forms of the flexible zeolite Rho (Cu,M-Rho; M = H, Na) and its consequences for CO2 adsorption properties (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/cation-ordering-and-exsolution-behaviour-in-cucon...
 
Title Conformable holographic metasurfaces (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? Yes  
 
Title Constitutionally selective dynamic covalent nanoparticle assembly (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/constitutionally-selective-dynamic-covalent-nanop...
 
Title Controlled Synthesis of Large Single Crystals of Metal-Organic Framework CPO-27-Ni Prepared by a Modulation Approach: In situ Single Crystal X-ray Diffraction Studies (dataset) 
Description underpinning data for open access publication 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/controlled-synthesis-of-large-single-crystals-of-...
 
Title Coordination-Controlled Electrodeposition of Palladium/Copper Thin Films onto a Pyridine-Terminated Self-Assembled Monolayer (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/coordinationcontrolled-electrodeposition-of-palla...
 
Title Data for "Intermolecular States in Organic Dye Dispersions: Excimers vs Aggregates" 
Description Powerpoint of figures from publication 'Intermolecular States in Organic Dye Dispersions: Excimers vs Aggregates' (Journal of Materials Chemistry C, 2017, DOI: 10.1039/C7TC02655B). Underlying data is embedded in each figure and can be accessed by double-clicking. Figures are separated into files corresponding to main text and electronic supporting information files. Colour maps from streak camera measurements are provided only in ascii format in excel file (_streak camera maps). 
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? Yes  
URL https://figshare.shef.ac.uk/articles/dataset/Data_for_Intermolecular_States_in_Organic_Dye_Dispersio...
 
Title Data underpinning "Ultrafast Electronic Energy Transfer in an orthogonal molecular dyad" 
Description  
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? Yes  
 
Title Data underpinning - "Time-resolved studies of energy transfer in thin films of green and red fluorescent proteins" 
Description The attached data underpin the publication, "Time-resolved studies of energy transfer in thin films of green and red fluorescent proteins". Data for each figure panel from the paper that displays numerical data are provided in the form of ASCII text-formatted data files (.dat). 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Data underpinning - Controlling the Emission Efficiency of Blue-Green Iridium(III) Phosphorescent Emitters and Applications in Solution-Processed Organic Light-Emitting Diodes 
Description  
Type Of Material Database/Collection of data 
Year Produced 2016 
Provided To Others? Yes  
 
Title Data underpinning - Isothiourea mediated organocatalytic Michael addition-lactonization on a surface: modification of SAMs on silicon oxide substrates 
Description Data underpinning 'Isothiourea mediated organocatalytic Michael addition-lactonization on a surface: modification of SAMs on silicon oxide substrates' 
Type Of Material Database/Collection of data 
Year Produced 2016 
Provided To Others? Yes  
 
Title Data underpinning - Self-trapping and excited state absorption in fluorene homo-polymer and copolymers with benzothiadiazole and tri-phenylamine 
Description  
Type Of Material Database/Collection of data 
Year Produced 2016 
Provided To Others? Yes  
 
Title Data underpinning - Spatial distribution of phase singularities in optical random vector waves 
Description  
Type Of Material Database/Collection of data 
Year Produced 2016 
Provided To Others? Yes  
 
Title Data underpinning - Surface topology specic metasurface holograms 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Data underpinning - Ultrafast all-optical order-to-chaos transition in silicon photonic crystal chips 
Description Set of editable figures and relative dataset relative to the article 
Type Of Material Database/Collection of data 
Year Produced 2016 
Provided To Others? Yes  
 
Title Data underpinning : Switching on electrocatalytic activity in solid oxide cells 
Description  
Type Of Material Database/Collection of data 
Year Produced 2016 
Provided To Others? Yes  
 
Title Data underpinning Influence of Electrode Processing and Electrolyte Composition on Multiwall Carbon Nanotube Negative Electrodes for Sodium Ion Batteries 
Description  
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/data-underpinning-influence-of-electrode-processi...
 
Title Data underpinning: Unprecedented strongly panchromic absorption from proton switchable iridium(III) azoimidazolate complexes 
Description  
Type Of Material Database/Collection of data 
Year Produced 2015 
Provided To Others? Yes  
 
Title Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles (dataset) 
Description Nature Communications Paper 
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? Yes  
 
Title Direct organocatalytic enantioselective functionalization of SiOx surfaces (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Efficient indoor p-i-n hybrid perovskite solar cells using low temperature solution processed NiO as hole extraction layers (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Electrochemical activation applied to perovskite titanate fibres to yield supported alloy nanoparticles for electrocatalytic application (dataset) 
Description Data for the paper 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/electrochemical-activation-applied-to-perovskite-...
 
Title Electron-withdrawing Group Modified Carbazolophane Donors for Deep Blue Thermally Activated Delayed Fluorescence OLED (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/electronwithdrawing-group-modified-carbazolophane...
 
Title Engineered exciton diffusion length enhances device efficiency in small molecule photovoltaics (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Examining Operando Generated Ni-Based Alloy Nanomaterials as Fuel Electrodes in Solid Oxide Cells (dataset) 
Description The attached data files underpin the publication "Examining Operando Generated Ni-Based Alloy Nanomaterials as Fuel Electrodes in Solid Oxide Cells". The following file types and formats are included: -X-ray Diffraction data files: .xlsx and .xls(can be opened with Microsoft Excel) -Thermogravimetric analysis data files: xlsx and .xls -DC conductivity analysis data files: xlsx and .xls -Scanning electron microscopy: .tif or png and .txt -Energy dispersive spectroscopy: .xlsx -Electrochemical characterization: .xlsx 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/examining-operando-generated-nibased-alloy-nanoma...
 
Title Excited state modulation in Donor-Substituted Multi-resonant Thermally Activated Delayed Fluorescence Emitters (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/excited-state-modulation-in-donorsubstituted-mult...
 
Title Exciton Diffusion Length and Charge Extraction Yield in Organic Bilayer Solar Cells (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? Yes  
 
Title Exciton-polaron interactions in polyfluorene films with ß phase (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Flexible patches for millimeter wavelength holography 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk:443/portal/en/datasets/flexible-patches-for-millimeter-wavelength-ho...
 
Title Fluorinated Dibenzo[a,c]-phenazine-Based Green to Red Thermally Activated Delayed Fluorescent OLED Emitters (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/fluorinated-dibenzoacphenazinebased-green-to-red-...
 
Title Green Perovskite Distributed Feedback Lasers (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? Yes  
 
Title Hiding Extra-Framework Cations in Zeolites L and Y by Internal Ion Exchange and its Effect on CO2 Adsorption (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/hiding-extraframework-cations-in-zeolites-l-and-y...
 
Title Highly Twisted a-Diketone-Based Thermally Activated 1 Delayed Fluorescence Emitters and their use in Organic 2 Light-Emitting Diodes (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/highly-twisted-adiketonebased-thermally-activated...
 
Title Highly efficient green & red narrowband emissive organic light-emitting diodes employing multi-resonant thermally activated delayed fluorescence emitters (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/highly-efficient-green--red-narrowband-emissive-o...
 
Title Hole delocalization as a driving force for charge pair dissociation in organic photovoltaics (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Hot-Hole Cooling Controls the Initial Ultrafast Relaxation in Methyl Ammonium Lead Iodide Perovskite (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Hydrolytic stability in hemilabile metal-organic frameworks (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Improved efficiency of PbS quantum dot sensitized NiO photocathodes with naphthalene diimide electron acceptor bound to the surface of the nanocrystals (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title In-situ construction of ceria-metal/titanate heterostructure with controllable architectures for efficient fuel electrochemical conversion (dataset) 
Description The attached data files underpin the publication "In-situ construction of ceria-metal/titanate heterostructure with controllable architectures for efficient fuel electrochemical conversion". The following file types and formats are included: -X-ray Diffraction data files: .xlsx and .xls(can be opened with Microsoft Excel) -Scanning electron microscopy: .tif -Transmission electron microscopy: .tif -Energy dispersive spectroscopy: .xlsx -Electron energy loss spectroscopy: .xlsx -Electrochemical characterization: .xlsx and .txt 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/insitu-construction-of-ceriametaltitanate-heteros...
 
Title Influence of Sulfur Oxidation State and Substituents on Sulfur-Bridged Luminescent Copper(I) Complexes Showing Thermally Activated Delayed Fluorescence (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk:443/portal/en/datasets/influence-of-sulfur-oxidation-state-and-subst...
 
Title Interface limited hole extraction from methylammonium lead iodide films (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/interface-limited-hole-extraction-from-methylammo...
 
Title Interplay of ferromagnetism and spin-orbit coupling in Sr4Ru3O10 (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/interplay-of-ferromagnetism-and-spinorbit-couplin...
 
Title Long-range Exciton Diffusion in Non-Fullerene Acceptors and Coarse Bulk Heterojunctions Enable Highly Efficient Organic Photovoltaics (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/longrange-exciton-diffusion-in-nonfullerene-accep...
 
Title Low-Threshold Room Temperature Polariton Lasing from Fluorene-Based Oligomers (dataset) 
Description Dataset for paper 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/lowthreshold-room-temperature-polariton-lasing-fr...
 
Title Molecular Design and Synthesis of Dicarbazolophane-Based Centrosymmetric through-Space Donors for Solution-Processed Thermally Activated Delayed Fluorescence OLEDs (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/molecular-design-and-synthesis-of-dicarbazolophan...
 
Title Morphology Control of Epitaxial Monolayer Transition Metal Dichalcogenides (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/morphology-control-of-epitaxial-monolayer-transit...
 
Title Nanoscale heterogeneity in CsPbBr3 and CsPbBr3:KI perovskite films revealed by cat hodoluminescence hyperspectral imaging (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/nanoscale-heterogeneity-in-cspbbr3-and-cspbbr3ki-...
 
Title Non-obstructive intracellular nanolasers (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk:443/portal/en/datasets/nonobstructive-intracellular-nanolasers-datas...
 
Title Novel 4,8-Benzobisthiazole (BBT) copolymers and their application in OFET and OPV devices 
Description This dataset contains the raw data for Atomic Force Microscopy (AFM) Images, Cylcic Voltamomgrams (CV), UV-Vis spectra and Organic Field-Effect Transistor (OFET) devices present in the paper. Also included are Nuclear Magentic Resonance (NMR) and Thermal Gravametric Analysis (TGA) data. AFM images were generated using WSXM 5.0 are formatted in associated formats. CV, UV, TGA and OFET data are presented in .txt or .xls files that can be opened with typical graphing software, or created using OriginPro 2015 and saved in associated formats. NMR data is in the .fid or .xwp format. 
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? Yes  
 
Title Optoelectronic Applications of Lead Halide Perovskites (thesis data) 
Description Data set for this thesis including the raw data for solar cell J-V curves, laser measurements (threshold, gain, loss, and profiles), resonant ultrasound spectroscopy, PLQY data, surface profilometry, absorption spectroscopy, and time resolved photoluminescence. Also included are SEM and microscope images of samples during the optimisation process. Some of the data files will need to be viewed on Origin, and the RUS data is best viewed on IGOR, but the rest of the data is in non-proprietary format. The data files are embargoed until 20/08/2019 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Patterning Multicolour Hybrid Perovskite Films via Top-down Lithography (dataset) 
Description Datasets including surface profilometry scans, PLQY data, scanning electron microscopy images, and microscope photographs. 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Perfect secrecy cryptography via correlated mixing of chaotic waves in irreversible time-varying silicon chips (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/perfect-secrecy-cryptography-via-correlated-mixin...
 
Title Planar Semiconductor Membranes with Brightness-enhanced Embedded Quantum Dots via Electron Beam Induced Deposition of 3D Nanostructures: Implications for Solid State Lighting (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/planar-semiconductor-membranes-with-brightnessenh...
 
Title Platinum incorporation into titanate perovskites to deliver emergent active and stable platinum nanoparticles (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/platinum-incorporation-into-titanate-perovskites-...
 
Title Replacement of Ca by Ni in a Perovskite Titanate to Yield a Novel Perovskite Exsolution Architecture for Oxygen-Evolution Reactions (dataset) 
Description Supplementary Information 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk:443/portal/en/datasets/replacement-of-ca-by-ni-in-a-perovskite-titan...
 
Title Silicon Redistribution, Acid Site Loss and the Formation of a Core-Shell Texture upon Steaming SAPO-34 and their Impact on Catalytic Performance in the MTO Reaction (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/silicon-redistribution-acid-site-loss-and-the-for...
 
Title Size dependence efficiency of PbS quantum dots in NiO-based dye sensitised solar cells and mechanistic charge transfer investigation (dataset) 
Description The data files are not yet publicly available. Enquiries and requests for data should be directed to the publication's corresponding authors: Raissi, M., Sajjad, M. T., Pellegrin, Y., Roland, T. J., Jobic, S., Boujtita, M., ... Odobel, F. (2017). Size dependence of efficiency of PbS quantum dots in NiO-based dye sensitised solar cells and mechanistic charge transfer investigation. Nanoscale, 9(40), 15566-15575. DOI: 10.1039/C7NR03698A 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Spiro-based Thermally Activated Delayed Fluorescence Emitters with Reduced Non-radiative Decay for High Quantum Efficiency, Low Roll-off, Organic Light-Emitting Diodes (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/spirobased-thermally-activated-delayed-fluorescen...
 
Title Tailoring exciton diffusion and domain size in photovoltaic small molecules by processing (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title The Role of Lattice Distortion and A Site Cation in the Phase Transitions of Methylammonium Lead Halide Perovskites (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title The role of metallic dopants in improving the thermal stability of the electron transport layer in organic light-emitting diodes (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Thermally Activated Delayed Fluorescence Emitters with Intramolecular Proton Transfer for High Luminance Solution-Processed Organic LightEmitting Diodes (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/thermally-activated-delayed-fluorescence-emitters...
 
Title Triple cation perovskite solar cells for visible light communications (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/triple-cation-perovskite-solar-cells-for-visible-...
 
Title Tuning the exciton diffusion coefficient of polyfluorene based semiconducting polymers (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Ultrafast triggering of insulator-metal transition in two-dimensional VSe2 (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/ultrafast-triggering-of-insulatormetal-transition...
 
Title Understanding the Anion-Templated, OSDA-Free, Interzeolite Conversion Synthesis of High Silica ZK-5 (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/understanding-the-aniontemplated-osdafree-interze...
 
Title Use of interplay between A-site non-stoichiometry and hydroxide doping to deliver novel proton-conducting perovskite oxides (dataset) 
Description A draft for submission to a journal 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/use-of-interplay-between-asite-nonstoichiometry-a...
 
Title Using the Mechanical Bond to Tune the Performance of a Thermally Activated Delayed Fluorescence Emitter (dataset) 
Description  
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://risweb.st-andrews.ac.uk/portal/en/datasets/using-the-mechanical-bond-to-tune-the-performance...