Bioinspired green manufacturing of next generation energy storage materials

Lead Research Organisation: University of Sheffield
Department Name: Chemical & Biological Engineering

Abstract

The ubiquity of lithium-ion batteries (LIBs) in portable electronic devices have led to an enormous volume of research on materials promising improved performance characteristics. Whether in terms of the amount of energy they can deliver, their operating lifetime or overall cost, there are pressing demands for the development of improved functional materials. In particular, Li-Ni-Co-Mn-oxides are attractive cathode materials due to their high achievable specific capacity and good long-term performance; they are also commercialised and widely used in the battery market. However, their synthesis typically requires extreme temperatures over long duration, contributing the vast majority of the energy costs. Furthermore, their manufacture is wasteful and is unsustainable. Hence the use of more sustainable synthesis routes has the potential to drastically reduce this expense.

Learning from biology, we aim to discover new bioinspired routes to produce energy storage materials. These methods will need lower temperatures, leading to reduced energy demands, and allow for superior control of materials properties on the nanoscale. This is a radically new approach, which has never been applied to energy storage materials.

Planned Impact

Our vision is to discover radically new routes for preparing battery electrode materials by using bioinspired green chemistry.

Our project will help remove the energy intensive processing of LIB electrode materials, which removes some of the barriers in place that currently inhibit widespread production. These achievements will allow for the scale-up of "academically interesting" materials towards commercially viable volumes, yet at lower costs. This represents a significant economic and societal impact.

We will develop a simple and green synthesis of LIB electrode materials, which will attract wider academic community and encourage them to utilise our methods to undertake battery research and develop useful materials.

Our focus on sustainable battery technologies which will have a wider societal impact on the understanding and perceptions of school pupils and the public. Sustainable materials outlined in this proposal are especially appealing since their principles match the ethical aspirations of public.
 
Description This project aimed to discover bioinspired (green) routes to battery electrodes. We have now generated results to show that using bioinspired additives during the synthesis of electrode materials has an effect of the properties and performance.
Exploitation Route 1. Publication of the results - a manuscript is drafted, awaiting final set of results.
2. Presentation at conferences.
3. Application for a collaborative project by using results herein as proof-of-concept.
Sectors Energy,Manufacturing, including Industrial Biotechology,Transport

 
Description EP/W018950/1 Sustainable microwave manufacturing of functional inorganic materials (SuMMa)
Amount £1,683,171 (GBP)
Funding ID EP/W018950/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 03/2022 
End 02/2025
 
Description FUSE
Amount £2,991 (GBP)
Organisation The Faraday Institution 
Sector Charity/Non Profit
Country United Kingdom
Start 06/2020 
End 08/2020
 
Description Scalable and sustainable manufacture of Si anodes for transforming commercial batteries
Amount £126,275 (GBP)
Funding ID FIRG041 
Organisation The Faraday Institution 
Sector Charity/Non Profit
Country United Kingdom
Start 06/2022 
End 05/2023
 
Description Collaboration with Serena Corr and Denis Cumming 
Organisation University of Sheffield
Country United Kingdom 
Sector Academic/University 
PI Contribution Resulted in advanced characterisation of materials
Collaborator Contribution Conducted advanced characterisation and analysis using synchrotron x-ray scattering.
Impact Led to a high profile paper: Insights into the Electrochemical Reduction Products and Processes in Silica Anodes for Next-Generation Lithium-Ion Batteries Jake E. Entwistle, Samuel G. Booth, Dean S. Keeble, Faisal Ayub, Maximilian Yan, Serena A. Corr, Denis J. Cumming, and Siddharth V. Patwardhan Adv. Energy Mater. 2020, 2001826 DOI: 10.1002/aenm.202001826
Start Year 2019
 
Description Ever Charge Energy Ltd 
Organisation Evercharge Energy Limited
Country United Kingdom 
Sector Private 
PI Contribution This company spotted our recent paper/work on battery electrodes and now we have built a couple of project/funding applications. The PI is also now an advisor to this company.
Collaborator Contribution A pathway for commercialising our inventions/outcomes.
Impact n/a yet
Start Year 2020
 
Description Greg Beaucage 
Organisation University of Cincinnati
Country United States 
Sector Academic/University 
PI Contribution We hosted Greg's visit and shared samples for USAXS.
Collaborator Contribution Greg visited us and also performed all USAXS experiments and analysis.
Impact Mechanistic understanding of pore evolution enables high performance mesoporous silicon production for lithium-ion batteries† Jake E. Entwistle, Gregory Beaucage and Siddharth V. Patwardhan J. Mater. Chem. A, 2020, 8, 4938 DOI: 10.1039/c9ta13633a
Start Year 2019
 
Description AIChE presentations 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Following two presentations were given virtually at the AIChE annual conference:
1. Mechanistic understanding and rapid electrochemical reduction of silica for lithium-ion battery anodes
2. Towards Green Manufacturing of Biologically Inspired Nanomaterials: Degree of Mixing and Mixing Time Analysis
Year(s) Of Engagement Activity 2020
 
Description Conference presentations at 5th International Conference on Bioinspired & Biobased Chemistry & Materials 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other audiences
Results and Impact Two presentation at the virtual 5th International Conference on Bioinspired & Biobased Chemistry & Materials. Unclear on the number of participants:
1. Bioinspired Green Chemistry to Design Sustainable and Scalable High Value Nanosilica
2. A Sustainable and Scalable Technology to Produce High Performance Mesoporous Silicon for Li-Ion Batteries
Year(s) Of Engagement Activity 2020
 
Description Invited presentation at the Nature-Inspired Engineering conference, Italy 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact An invited presentation on the topic of Discovery, applications and scale-up of bioinspired nanomaterials at the ECI conference.
Year(s) Of Engagement Activity 2019
 
Description Invited speaker at the KTN Emerging Technologies symposium on Nature inspired solutions, Edinburgh, 13 Feb 2020 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact This event was organised by the KTN and Heriot Watt University to build community in the area of nature inspired solutions. The talk and discussions sparked interesting future avenues, e.g. bidding for joint projects, building a UK-wide network.
Year(s) Of Engagement Activity 2020
 
Description Invited speaker at the RSC Process Chemistry Technology Group Launch Symposium, 19/11/2018 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact This was an invited presentation on the topic of From discovery to scale-up of bespoke green nanomaterials. The symposium was organised by the Royal Society of Chemistry's PCTG special interest group (SIG). As a result of this successful event and the match with the SIG's agenda, Siddharth was selected to work on the PCTG's committee.
Year(s) Of Engagement Activity 2018
URL https://www.procchem.group/
 
Description Lydgate school visit 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Schools
Results and Impact During this all-day school visit, we engaged with 120 Y6 students and their teachers in various activities relevant to bioinspired approaches to sustainable materials and manufacturing. As part of that, we included hands-on activities on energy storage, reactor engineering, nature inspired technologies, and manufacturing/process engineering.
Year(s) Of Engagement Activity 2019
URL http://www.lydgatejunior.co.uk/BlogRetrieve.aspx?PostID=809820&A=SearchResult&SearchID=1628758&Objec...
 
Description Multiple presentations at the ACS conference, San Diego 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact 6 presentations (including 2 invited) were given at the American Chemical Society's annual conference. The topics included:
Application of Bioinspired Green Chemistry to Design Sustainable and Scalable High Value Nanosilica
Magnesiothermic reduction to produce porous silicon for lithium-ion batteries
Green nanomaterials: Journey from lab to manufacturing
Bioinspired nanomaterials for water remediation
Scale-up of MOFs for Sustainable and Commercial Manufacturing
Understanding interfacial interactions to unlock the potential of bioinspired nanomaterials
Year(s) Of Engagement Activity 2019
 
Description School Visit and presentation 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Schools
Results and Impact Tapton Secondary School, July 2022, Green nanomaterials: sustainable, scalable and economical routes to functional nanomaterials.
Year(s) Of Engagement Activity 2022
 
Description Seminar at Queens University Belfast, 15/05/2019 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Professional Practitioners
Results and Impact This was an invited departmental seminar.
Year(s) Of Engagement Activity 2019
 
Description Visit to Jnana Probodhini School, Pune 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Schools
Results and Impact A presentation to Y9 school students about nanomaterials and bioinspiration.
Year(s) Of Engagement Activity 2019