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Tailored Microstructures via Thermoelectric-Magnetohydrodynamics for Additive Manufacturing (TEAM)

Lead Research Organisation: University of Greenwich
Department Name: Mathematical Sciences, FACH

Abstract

Additive Manufacturing (AM), also termed 3D printing, involves successively adding thin layers of new material formed by melting alloy powders or wires and solidifying them onto prior layers to construct 3D components. This process directly builds intricately shaped parts impossible to create using traditional techniques. Further, AM promises to be both more energy and materials efficient. Potential applications are far reaching, including biomedical, energy and aerospace. However, AM components can suffer from microstructural features that may lead to degraded properties, such as porosity and epitaxial grain growth. Porosity can form from gas bubbles entrained in the solidification front, leading to voids in the final built. Epitaxial grain growth occurs when new grains take on the crystal orientation of the previous layer, producing often undesirable direction dependent properties. We hope to control these features using magnetic fields acting on Thermoelectric (TE) currents.

TE effects translate temperature variations at the junction of two conductive materials into electric current. They are well known in common applications such as Peltier coolers, TE generators for waste heat recovery and in thermocouples. In this proposal we aim use the interaction of thermoelectric currents and applied magnetic fields to generate fluid flow in the molten pool of metal that forms material in the AM process. This interaction is called Thermoelectric Magnetohydrodynamics, or TEMHD. Our feasibility studies indicate that TEMHD can transform the microstructure in AM components, preventing the formation of microstructural features such as porosity or epitaxial growth. We will show that thermoelectric effects are a natural and inherent part of AM processes, with high currents forming due to the huge thermal gradients encountered in AM. We will apply controlled external magnetic fields, causing these currents to interact and generate a Lorentz force that drives TEMHD flow. Our preliminary numerical predictions show that even a moderate magnetic field generated by permanent magnets is sufficient for TEMHD to dominate the melt pool hydrodynamics and that the flow magnitude is highly sensitive to the orientation and magnitude of the magnetic field. This sensitivity will enable us to modulate the heat, mass and momentum transport, enabling control of microstructural evolution, including epitaxial growth and gas entrainment. Our vision is to reveal the fundamental mechanisms that TEMHD introduces to AM and to then ultimately develop a pathway to exploit it in industrial applications producing improved and consistent material properties of components.

To achieve these goals the investigators will employ state-of-the-art experimental and numerical modelling techniques. High speed in situ synchrotron X-ray radiography of the process will generate data for validation of the numerical model and provide benchmarks for the wider scientific community. The numerical model will capture the complex interactions in the melt pool and provide understanding of the complex physical mechanisms at work. Theoretical predictions from the model will guide the experimental programme, while direct observations will guide the numerical model development. With a validated numerical model, a parametric study of the magnetic field conditions along with key AM processing conditions will be conducted to determine conditions required to produce microstructures that give the properties required for each application. The ability to use TEMHD to design the microstructures will be demonstrated in the experimental programme. Throughout the project we will seek input from our industrial partners, and during the latter stages we will hold a workshop to develop translational pathways for scaling and implementing these techniques to the next generation of AM machines.
 
Description Three of the key aims of the TEAM project were to i) understand the Thermoelectric Magnetohydrodynamic (TEMHD) phenomenon when a magnetic field is applied to the additive manufacturing process (3D printing) of metals, ii) demonstrate that this can have strong interaction with other inherent flows such as the surface tension driven Marangoni flow, therefore modifying the melt pool dynamics and the subsequent solidification behaviour and iii) show that TEMHD can be exploited in an advantageous way to benefit industrial processes.

We have achieved all of these aims, a good example is in the Laser Powder Bed Fusion (LPBF) process, highlighted in our recent paper "Magnetic modulation of keyhole instability during laser welding and additive manufacturing" published in Science. Keyholes form from evaporation of the metal and are beneficial in both welding and additive manufacturing, allowing for thicker joins or faster fabrication. However, porosity is a major problem that occurs when the end of the keyhole pinches off forming a void.

In this work, using ultra-fast X-ray imaging we demonstrated that TEMHD can reach speeds on the order of meters per second, enough to modify the overall flow. We showed that when TEMHD acts against the other inherent forces it can stabilise the keyhole preventing the initiation of the pinch off. Using permanent magnets with an intensity of 0.5 T, led to an 80% reduction in pore formation under processing conditions found in industry. In contrast, we showed that the traditional Electromagnetic Damping (EMD) phenomenon would require 5 T, an order of magnitude higher and well into the realms of super conducting magnets. A key difference is that LPBF operates at smaller length scales, e.g. 100 micron melt pool, compared to other methods such as Directed Energy Deposition (DED), where the melt pool is 1 millimetre. Due to viscous forces, both TEMHD and EMD scale inversely with the length such that high magnetic fields are needed at smaller length scales, however we found that as TEMHD scales with the thermal gradient, which increases at smaller length scales. Consequently, strong effects of TEMHD have been observed across length scales in both the LPBF and DED processes.

The TEMHD effect however does require the material to exhibit semi-conductor like properties and this effect was most pronounced in higher Silicon content Aluminium alloys that are used widely in industry.
Exploitation Route While the key objectives of this project have been met, there are still many avenues (including new ones identified from the project) to explore.

In industrial processes, the scanning strategy is geometric in nature, such as hatching, printing corners, overhangs etc. TEMHD is dependent on the temperature gradients, which in turn depends on the scan strategy. Therefore, TEMHD becomes intimately coupled to the scan strategy and it may be necessary to optimise the magnetic field for different geometries.

To scale to industry, new magnetic systems integrated with current industrial AM machines will need to be developed. There are many engineering problems to consider such as interaction of the magnetic field with the AM machine itself.

There has been considerable work in solid-state thermoelectric materials through doping. These materials are typically semi-conductors with very high Seebeck coefficients >1000 uV/K and designed to operate in thermal gradients of 100 K/m. However, in metal alloys a Seebeck coefficient of >1 uV/K is considered high, however there is a direct analogy between doping and alloy composition. This research may promote the discovery of thermoelectric alloys that have excellent physical properties e.g. strong, light-weight etc. that can then be further enhanced by TEMHD.
Sectors Aerospace

Defence and Marine

Manufacturing

including Industrial Biotechology

 
Description Why Space? The Opportunity for Materials Science and Innovation
Geographic Reach National 
Policy Influence Type Contribution to a national consultation/review
URL https://sa.catapult.org.uk/news/launch-of-the-position-paper-why-space-the-opportunity-for-materials...
 
Description Novel Manufacturing-led Structures for Electrical Machines under Extreme Working Environments
Amount £91,571 (GBP)
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 02/2024 
End 02/2025
 
Description Research England - Expanding Excellence in England (E3) Round 2
Amount £9,080,177 (GBP)
Funding ID Multi-Scale, Multi-Disciplinary, Modelling Platform (M34Impact) 
Organisation Greenwich University 
Sector Academic/University
Country Pakistan
Start 07/2024 
End 07/2029
 
Description S Bhagavath and H Chapman - Student Training and Experience for Proposals program (1st STEPs program) pilot scheme
Amount £2,000 (GBP)
Organisation University College London 
Sector Academic/University
Country United Kingdom
Start 09/2024 
End 07/2025
 
Description 'Invited industrial visit CLA Leung, PD Lee - Carpenter Additive, Widnes, 22nd May 2023 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Industry/Business
Results and Impact 'Invited industrial visit CLA Leung, PD Lee - Carpenter Additive, Widnes, 22nd May 2023
Year(s) Of Engagement Activity 2023
 
Description A Kao talk at University of Latvia 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact A Kao gave talk at the University of Latvia on research activities within TEAM. This was attended by members of the faculty, PhD students and Masters students.
Year(s) Of Engagement Activity 2024
 
Description C Tonry talk at TMS 2024 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact C Tonry talk at TMS 2024 "Solidification of Gallium Indium in Static and Pulsed Magnetic Fields", USA
Year(s) Of Engagement Activity 2024
URL https://www.tms.org/TMS2024/Home/TMS2024/Default.aspx?hkey=54504ea7-8339-4a6d-855c-30ecc0bfe027&gcli...
 
Description C.L.A. Leung hosted the 'IOM3 Road to Professional Membership and Chartership event' with UKRI RCaH, IOM3, and Renishaw plc. 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact I co-host the upcoming event: 'Road to professional membership and chartership' with the Research Complex at Harwell, IOM3 (Institute of Materials, Minerals & Mining), UCL, and Renishaw. If you want to find answers to any of the following questions, please come along to our in person event at Harwell campus (29th Nov 2023). We have got an excellent line-up of speakers, e.g. Ms Sarah Boad, Dr. Sarah Glanvill, and Prof. Mark Miodownik. The goal is to showcase professional practitioners to learn more about the following areas:

? Are you interested in joining a professional body or the benefits of being a member of one?
? Do you want to join the Institute of Materials, Minerals, and Mining (IOM3)?
? Do you know how being chartered could benefit your career?
? Do you know the process for becoming chartered?
? Do you even know what chartership is?
Year(s) Of Engagement Activity 2023
URL https://www.rc-harwell.ac.uk/events/road-professional-membership-and-chartership
 
Description CLA Leung Invited talk at Renishaw plc. lunch time seminar 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Industry/Business
Results and Impact CLA Leung Invited talk at Renishaw plc. lunch time seminar 'New Insights into the laser powder bed fusion process using advanced sensing technologies'
Year(s) Of Engagement Activity 2023
 
Description CLA Leung interview podcast Tech and Science Daily 
Form Of Engagement Activity A broadcast e.g. TV/radio/film/podcast (other than news/press)
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact CLA Leung interview podcast Tech and Science Daily - How researchers are using X-Ray vision to improve Formula 1. We're joined by Dr. Chu Lun Alex Leung an Associate Professor in Advanced Manufacturing at UCL.
Year(s) Of Engagement Activity 2025
URL https://shows.acast.com/tech-science-daily/episodes/breast-cancer-deaths-to-rise-dramatically-by-205...
 
Description H Chapman talk at TMS 2024 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact H Chapman talk at TMS 2024 "In-Situ characterisation of Directed Energy Deposition of selected nickel superalloys", USA
Year(s) Of Engagement Activity 2024
URL https://www.tms.org/TMS2024/Home/TMS2024/Default.aspx?hkey=54504ea7-8339-4a6d-855c-30ecc0bfe027&gcli...
 
Description Host an external safety audit 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Industry/Business
Results and Impact Host an external safety audit with the UK Health Security Agency, Harwell Campus, November 2023.
Year(s) Of Engagement Activity 2023
 
Description I Krastins talk at PAMIR 2024 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact I Krastins gave talk "Thermoelectric Magneto-hydro-dynamic Effects on Meltpool Dynamics and Microstructure in Additive Manufacturing" at 13th PAMIR Int. Conf. - Fundamental and Applied MHD, 19.09.2024., Carry-le-Rouet, France.
Year(s) Of Engagement Activity 2024
URL https://eumhd.com/pamir2024/
 
Description I Krastins talk at TMS 2024 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact I Krastins talk at TMS 2024 "Microstructure Control in Additive Manufacturing Using Magnetic Fields and Strategic Scanning", USA
Year(s) Of Engagement Activity 2024
URL https://www.tms.org/TMS2024/Home/TMS2024/Default.aspx?hkey=54504ea7-8339-4a6d-855c-30ecc0bfe027&gcli...
 
Description MSMaH team volunteering at Harwell Open Week 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Over 30 members of MSMaH team volunteered at the Harwell Open Week on 28 and 29 June 2024, including running a stand of using 3D pen to repair damaged turbine blades, demonstraion of 3D printing equipment, using a machine build with Lego to show concept of X-ray tomography, and presenting 3D printed organs.
Year(s) Of Engagement Activity 2024
URL https://www.harwellcampus.com/discover/stories/open-day-2024/
 
Description MSMaH team volunteering at UCL Festival of Engineering 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Over 30 members of MSMaH team volunteered at the UCL Festival of Engineering on 18-20 July 2024, including running a stand of using 3D pen to repair damaged turbine blades and presenting 3D printed human organ atlas.
Year(s) Of Engagement Activity 2024
URL https://www.eventbrite.com/cc/ucl-festival-of-engineering-friday-3185929
 
Description P Soar talk at UKCOMES 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact P Soar presented at the UK Consortium on Mesoscale Engineering annual meeting. Talk gave an overview of UoG projects in Multi-scale and Multi-disciplinary modelling.
Year(s) Of Engagement Activity 2024
URL https://www.ucl.ac.uk/mesoscale-modelling-consortium/
 
Description PD Lee & CLA Leung featured in ESRF article 
Form Of Engagement Activity A press release, press conference or response to a media enquiry/interview
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact PD Lee & CLA Leung featured in ESRF article, "Researchers find a mechanism of large pore formation in additive manufacturing"
Year(s) Of Engagement Activity 2024
URL https://www.rc-harwell.ac.uk/news/new-deep-learning-model-boosts-additive-manufacturing-x-ray-analys...
 
Description PD Lee & CLA Leung featured in Industrial Equipment News 
Form Of Engagement Activity A magazine, newsletter or online publication
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact PD Lee & CLA Leung featured in Industrial Equipment News, "Massive X-Ray Facility Shows How Magnets Can Reduce Flaws in 3D Printed Parts"
Year(s) Of Engagement Activity 2025
URL https://www.ien.com/additive-manufacturing/news/22934025/massive-xray-facility-shows-how-magnets-can...
 
Description PD Lee & CLA Leung featured in Technology Networks 
Form Of Engagement Activity A magazine, newsletter or online publication
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact PD Lee & CLA Leung featured in Technology Networks, "Magnets Could Reduce Flaws in 3D-Printed Components"
Year(s) Of Engagement Activity 2025
URL https://www.technologynetworks.com/tn/news/magnets-could-reduce-flaws-in-3d-printed-components-39646...
 
Description PD Lee & CLA Leung featured in Voxel Matters 
Form Of Engagement Activity A magazine, newsletter or online publication
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact PD Lee & CLA Leung featured in Voxel Matters, "Researchers reduce flaws in 3D printed components using magnets"
Year(s) Of Engagement Activity 2025
URL https://www.voxelmatters.com/researchers-reduce-flaws-in-3d-printed-components-using-magnets/
 
Description PD Lee & CLA Leung featured on Harwell News online 
Form Of Engagement Activity A magazine, newsletter or online publication
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact PD Lee & CLA Leung featured on Harwell News online, "New deep learning model boosts additive manufacturing X-ray analysis", UK
Year(s) Of Engagement Activity 2024
URL https://www.rc-harwell.ac.uk/news/new-deep-learning-model-boosts-additive-manufacturing-x-ray-analys...
 
Description PD Lee & CLA Leung hosted Junji Shinjo from Shimane University at Research Complex at Harwell. 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact PD Lee & CLA Leung hosted Junji Shinjo from Shimane University at Research Complex at Harwell.
Year(s) Of Engagement Activity 2024
 
Description PD Lee & CLA Leung participated at the Rolls-Royce University Technology Conference 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact CLAL Leung invited to join the interview panel for UELA studentship for UCL Faculty of Engineering, London, UK
Year(s) Of Engagement Activity 2025
 
Description PD Lee and CLA Leung hosted a Parker Aerospace visit to Harwell 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact PD Lee and CLA Leung hosted a Parker Aerospace visit to Harwell. Visitors include Diane Zanca (Director of Central Engineering), Chad Seaborn (Analytical Sciences Manager), Shane Nicholson (Senior Principal Engineer), Tom Halhead (Technical Director), Cameron Breheny (Senior Materials and Applications Engineer).
Year(s) Of Engagement Activity 2024
 
Description PD Lee hosted visits from RAEng panel at Research Complex at Harwell 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact PD Lee hosted a visit from RAEng panel at Research Complex at Harwell. Visitors include Professor Trevor Cross FREng, Dr Caroline Hargrove CBE FREng, Mr Ian Ritchie CBE FREng FRSE, Professor Rachel Williams FREng, Dr Cath Thums RAEng Programme Manager, Fjolla Krasniqi RAEng Programme Officer.
Year(s) Of Engagement Activity 2024
 
Description PD Lee on organising panel for TMS 2024 Symposium Defects and Properties of Cast Metals. 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact PD Lee on organising panel for TMS 2024 Symposium Defects and Properties of Cast Metals. Full Panel:
Lang Yuan, University of South Carolina; Andrew Kao, University of Greenwich; Brian G. Thomas, Colorado School of Mines; Peter D. Lee, University College London; Mark Roderic Jolly, Cranfield University
Alex J. Plotkowski, Oak Ridge National Laboratory
Kyle Fezi, Fort Wayne Metals
Year(s) Of Engagement Activity 2024
URL https://www.programmaster.org/PM/PM.nsf/UpcomingSymposia/D913BF93115EAF8085258947007FC71C?OpenDocume...
 
Description PD Lee talk at Queen Mary University of London departmental meeting 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact PD Lee talk at Queen Mary University of London departmental meeting, "Seeing Inside Additive Manufacturing to Intact Human Organs with Micron Resolution", London, UK
Year(s) Of Engagement Activity 2024
 
Description PD Lee talk at XFEL Town Hall 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact PD Lee talk at XFEL Town Hall, "Is XFEL needed to image additive manufacturing processes in real and reciprocal space?", Wales
Year(s) Of Engagement Activity 2024
 
Description W Li talk at TMS 2024 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact W Li talk at TMS 2024 "Deep Neural Network for Image Segmentation and Feature Quantification during Laser Powder Bed Fusion Additive Manufacturing", USA
Year(s) Of Engagement Activity 2024
URL https://www.tms.org/TMS2024/Home/TMS2024/Default.aspx?hkey=54504ea7-8339-4a6d-855c-30ecc0bfe027&gcli...
 
Description X Fan invited talk at EPM2024 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact X Fan invited talk at EPM2024, "In-situ Synchrotron Investigation of Magnetic Fields Control of Melt Flow during Solidification", Shanghai, China
Year(s) Of Engagement Activity 2024
 
Description X Fan talk at FEMS EUROMAT 2023 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact X Fan talk at FEMS EUROMAT 2023, "Magnetic field control of melt flow during additive manufacturing", Frankfurt, Germany
Year(s) Of Engagement Activity 2023
 
Description X Fan talk at Rolls-Royce Service's Technology Student Conference 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact X Fan talk at Rolls-Royce Service's Technology Student Conference, Derby, UK
Year(s) Of Engagement Activity 2023
 
Description X Fan talk at TMS 2024 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact X Fan talk at TMS 2024 "Controlling Melt Pool Dynamics during Additive Manufacturing using External Forces", USA
Year(s) Of Engagement Activity 2024
URL https://www.tms.org/TMS2024/Home/TMS2024/Default.aspx?hkey=54504ea7-8339-4a6d-855c-30ecc0bfe027&gcli...
 
Description X Fan talk at TMS 2024 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact X Fan Invited talk at TMS 2024 "Manipulating Flow during Solidification Using Magnetic Fields", USA
Year(s) Of Engagement Activity 2024
URL https://www.tms.org/TMS2024/Home/TMS2024/Default.aspx?hkey=54504ea7-8339-4a6d-855c-30ecc0bfe027&gcli...