Ultimate Control of Strain Relaxation Processes in SiGe Layers

Lead Research Organisation: University of Warwick
Department Name: Physics

Abstract

Silicon is the bedrock of the digital revolution. It occupies this position because of its unique chemical and physical properties. The low speed with which electrons and other current carriers move across silicon has traditionally been seen as a problem which can be solved by reductions in device size. As scaling of silicon devices into the nanometre regime becomes increasingly difficult and prohibitively expensive on a commercial scale, new channel materials could play a critical role that maintains the dominant position of silicon electronics well into the future. For example, the mobility of electrons, etc, may be increased, with consequent improvements in device speed and/or power consumption, by growing a thin layer of silicon on a SiGe platform which produces tensile strain in the silicon. Unfortunately current versions of these SiGe virtual substrates have high densities of defects and poor surface topography, making them unsuitable for commercial production. The proposed work concerns the development of novel and radical approaches to the development of SiGe virtual substrates of unprecedented quality in this respect.
 
Description Developed method of growing very low defect strain tuning buffer layers of silicon germanium alloy on a silicon substrate.
This work has enabled a large number of subsequent studies.
Exploitation Route Use of method for producing strained and relaxed epitaxy layers of silicon, germanium and their alloys on a silicon substrate. Allows integration of advanced electronic and photonic devices with standard silicon technology.
Sectors Digital/Communication/Information Technologies (including Software)

 
Description Creating silicon based platforms for new technologies
Amount £1,680,000 (GBP)
Funding ID EP/J001074/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 03/2012 
End 02/2017
 
Description Renaissance Germanium
Amount £1,021,000 (GBP)
Funding ID EP/F031408/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 10/2008 
End 03/2012
 
Description Silicon-based nanostructure and nanodevices for long-term nanoelectronics applications (NANOSIL NoE)
Amount £222,500 (GBP)
Funding ID INFSO-ICT-216171 
Organisation European Commission 
Department Seventh Framework Programme (FP7)
Sector Public
Country European Union (EU)
Start 01/2008 
End 03/2011
 
Title FORMATION OF LATTICE-TUNING SEMICONDUCTOR SUBSTRATES 
Description In order to reduce dislocation pile-ups in a virtual substrate, a buffer layer 32 is provided, between an underlying Si substrate 34 and an uppermost constant composition SiGe layer 36, which comprises alternating graded SiGe layers 38 and uniform SiGe layers 40. During the deposition of each of the graded SiGe layers 38 the Ge fraction x is linearly increased from a value corresponding to the Ge composition ratio of the preceding layer to a value corresponding to the Ge composition ratio of the following layer. Furthermore the Ge fraction x is maintained constant during deposition of each uniform SiGe layer 40, so that the Ge fraction x varies in step-wise fashion through the depth of the buffer layer. After the deposition of each pair of graded and uniform SiGe layers 38 and 40, the wafer is annealed at an elevated temperature greater than the temperature at which the layers have been deposited. Each graded SiGe layer is permitted to relax by pile-ups of dislocations, but the uniform SiGe layers 40 prevent the pile-ups of dislocations from extending out of the graded SiGe layers 38. Furthermore each of the subsequent annealing steps ensures that the previously applied graded and uniform SiGe layers 38 and 40 are fully relaxed in spite of the relative thinness of these layers. As a result the dislocations are produced substantially independently within successive pairs of layers 38 and 40, and are relatively evenly distributed with only small surface undulations 40 being produced. Furthermore the density of threading dislocations is greatly reduced, thus enhancing the performance of the virtual substrate by decreasing the disruption of the atomic lattice which can lead to scattering of electrons in the active devices and degradation of the speed of movement of the electrons. 
IP Reference WO03103031 
Protection Patent granted
Year Protection Granted 2003
Licensed Yes
Impact Spin out company
 
Company Name AdvanceSis/Circadian Solar 
Description Spun out as AdvanceSIs to exploit portfolio of patents around SiGe epitaxy. Refocused activity on concentrator solar cell technology, sun tracking systems and active PV elements. Changed name to Circadian Solar. Maximum employees 35, £12M of venture capital raised and spent. Company wound up in 2013. 
Year Established 2004 
Impact Developed most efficient, robust solar tracking system. Demonstrated CPV power generation at close to $1/W.