Coordination Chemistry for Energy and Our Sustainable Futures (ChemEnSus)
Lead Research Organisation:
University of Nottingham
Department Name: Sch of Chemistry
Abstract
This high-impact, challenging proposal brings together innovative ideas in coordination chemistry within a single inter and multidisciplinary project to open up new horizons across molecular, nanoscale and materials science. Our VISION is to apply coordination chemistry to the design and preparation of new multi-functional porous materials to deliver fundamental scientific and technological advances, and provide innovative solutions to one of the key issues of the 21st Century, that of clean, renewable energy. This will be achieved by creating paradigm shifts in the control of chemical hierarchy and interactions within the confined and multi-functionalized space generated by designed porous metal-organic framework (MOF) materials. Our STRATEGY is thus to develop a world-leading, overarching and fundamental research program with critical mass across complementary areas of physical sciences and engineering through the expertise and collaboration of six research groups. We target inter-related studies on i. porosity in the solid state in self-assembled hybrid materials for gas and volatile organic compound (voc) storage, sequestration and reactivity; ii. porosity in membranes for gas separations and purification for fuel cell applications; and iii. porosity at surfaces for sensing devices and applications. After 5 years we will deliver high capacity hydrogen storage materials that function at ambient temperatures. This will overcome a current major technological barrier unlocking the potential of hydrogen as a viable, clean replacement for fossil fuels and enabling the Hydrogen Economy to become a reality. The impact and significance of such ground-breaking advances will be huge. Our need and reliance upon fossil fuels for transport would be slashed and a new clean energy vector based on the hydrogen fuel cell with zero carbon emissions at the point of use would be achieved. However, fuel cells are notoriously sensitive to gas purity, and thus, in order to realise our overall ambition, we must also understand how hydrogen and other contaminant/competitor substrates, such as other gases, water and vocs from biomass and water electrolysis, interact, bind and are sensed within hybrid materials. Thus, issues of removal, purification, transport and sensing of hydrogen and its contaminants represent fundamental scientific and technological challenges that go hand-in-hand with the huge challenge of hydrogen storage. Programme Grant funding will support the scientific, intellectual and technological inter-dependence of the cross-disciplinary research strands of synthesis, characterisation, storage, purification and sensing. It will support the necessary coordinated and interactive effort to undertake fundamental studies and analysis of how assembled porosity behaves and how it can be controlled at different regime levels, at the micro-, meso- and macro- levels. Four inter-linked research THEMES are identified within the programme: 1. Core fundamental science: synthesis, assembly, modelling and characterisation; 2. Properties and function: gas and voc uptake, selectivity and reactivity; 3 Gas sieving, fuel cell membranes, theory, analysis and multi-scale modelling; 4. Surface templating and sensing devices.The programme of work demands the managerial and financial flexibility and freedom that consolidated funding brings in order to deliver transformative and disruptive research. The training of 10 PDRA- and 15 PhD-level scientists for future employment in the UK will be delivered in an exciting, stimulating and curiosity-driven environment. This will be interlinked to appropriate and extensive knowledge transfer and outreach activities to maximise the impact of research outputs. The application is underpinned by significant funding of 24.2M in current research income held by the PI and CIs, and by 4.57M of matched funding reflecting the unequivocal support of the host institutions for this proposal.
Planned Impact
The proposed research will have major impacts across academe, industry, commercial and financial sectors, national and international governmental agencies, and will have great relevance to societal issues. In terms of Knowledge, highly significant scientific advances in the generation and understanding of new polyfunctional materials, techniques and analysis will be produced via an innovative and transformative programme of research. In terms of People, new highly-skilled early-career scientists (10 PDRAs and 15 PhD students) will be trained across physical sciences and engineering, and will be available for employment across the UK economy. The research will in the medium to longer term contribute to the Economy via the development of a range of new energy and sustainable technologies which will contribute directly to wealth creation via new products, processes and procedures. In due course, new companies of direct importance to Society in terms of improved quality of life, international development and policy will be established based upon the principles of the new green technologies and the programme of sustainability developed in ChemEnSus. The quality of life of the UK and world populations will be enhanced though the positive impacts of this research on the mobility and security of energy, populations, climate, environment and economies. Short-term beneficiaries of the research will be academics working across physical sciences and engineering, and specifically in the multi-disciplinary areas of materials, energy, carbon capture, nanosciences, the hydrogen economy, fuel cells, electrochemistry, theory, modelling and structure determination. The proposal has a strong short-term impact by imparting a unique combination of skills to early-career scientists that can be imported to solve other key problems within the physical sciences. The project will train scientists to enhance the necessary skills-base of the UK in important and timely areas relating to energy and sustainability. The research team is already engaged with several key industries and with SMEs in the region (see Letters of Support), who will benefit through wealth creation, which will increase the economic competitiveness for UK companies and the UK in general. The University of Nottingham will benefit through a strengthening of existing and development of new research relationships with external companies, and the income that patented successful devices and materials will bring. The presence of the Business Partnership Unit (BPU) (Director: Dr Trevor Farren) within the School of Chemistry, Nottingham guarantees that any generated IP will be professionally and competently exploited. A Business Science Fellow (BSF) and the Project Manager, both embedded within the BPU, will work closely with the PI and CIs to ensure that the project will be managed to engage users and beneficiaries, and maximise impacts. All opportunities to spin-out the inventions and discoveries will be taken. Exploitation of the outputs of research during and after the lifetime of the grant will be indentified via discussion within the Programme consortium, with the BPU, the host Universities and/or the relevant industry, as appropriate. Public engagement and outreach, including presentations and experiments at public events, in schools and colleges will be managed by the BSF with Dr Samantha Tang, full-time Public Awareness Scientist. The research has high applicability to the priority areas and especially the Grand Challenges of Research Councils and Governmental Agencies within the UK and across the world. The research will inform stakeholders, funding agencies and policy makers especially in the areas of energy and sustainable development. We will be advocates in the strongest possible terms for the contributions that the Physical Sciences can make in these areas.
Publications
Stephen E
(2012)
Redox non-innocence of thioether crowns: elucidation of the electronic structure of the mononuclear Pd(III) complexes [Pd([9]aneS3)2]3+ and [Pd([18]aneS6)]3+.
in Inorganic chemistry
Stephen E
(2011)
Redox non-innocence of thioether crowns: spectroelectrochemistry and electronic structure of formal nickel(III) complexes of aza-thioether macrocycles.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Summerfield A
(2015)
Nucleation and Early Stages of Layer-by-Layer Growth of Metal Organic Frameworks on Surfaces.
in The journal of physical chemistry. C, Nanomaterials and interfaces
Summers PA
(2014)
Photochemical dihydrogen production using an analogue of the active site of [NiFe] hydrogenase.
in Inorganic chemistry
Tan C
(2011)
High capacity gas storage by a 4,8-connected metal-organic polyhedral framework.
in Chemical communications (Cambridge, England)
Tidey J
(2014)
Structural chemistry of metal coordination complexes at high pressure
in Coordination Chemistry Reviews
Tidey JP
(2016)
High-pressure studies of three polymorphs of a palladium(II) oxathioether macrocyclic complex.
in Acta crystallographica Section B, Structural science, crystal engineering and materials
Vitórica-Yrezábal IJ
(2017)
Binding CO2 by a Cr8 Metallacrown.
in Angewandte Chemie (International ed. in English)
Wang Q
(2014)
Simultaneous adsorption of Cu(II) and SO42- ions by a novel silica gel functionalized with a ditopic zwitterionic Schiff base ligand
in Chemical Engineering Journal
Warr RJ
(2016)
A Comparison of the Selectivity of Extraction of [PtCl6](2-) by Mono-, Bi-, and Tripodal Receptors That Address Its Outer Coordination Sphere.
in Inorganic chemistry
Wong HL
(2013)
Bowing to the pressure of p···p interactions: bending of phenyl rings in a palladium(II) thioether crown complex.
in Angewandte Chemie (International ed. in English)
Yan Y
(2011)
A mesoporous metal-organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra.
in Chemical communications (Cambridge, England)
Yan Y
(2017)
Porous Metal-Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage.
in Journal of the American Chemical Society
Yan Y
(2011)
Modifying cage structures in metal-organic polyhedral frameworks for H2 storage.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Yan Y
(2016)
Non-Interpenetrated Metal-Organic Frameworks Based on Copper(II) Paddlewheel and Oligoparaxylene-Isophthalate Linkers: Synthesis, Structure, and Gas Adsorption.
in Journal of the American Chemical Society
Yan Y
(2013)
Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal-organic polyhedral framework
in Chemical Science
Yan Y
(2014)
Studies on metal-organic frameworks of Cu(II) with isophthalate linkers for hydrogen storage.
in Accounts of chemical research
Yang S
(2011)
Pore with gate: enhancement of the isosteric heat of adsorption of dihydrogen via postsynthetic cation exchange in metal-organic frameworks.
in Inorganic chemistry
Yang S
(2014)
Supramolecular binding and separation of hydrocarbons within a functionalized porous metal-organic framework.
in Nature chemistry
Yang S
(2011)
Pore with gate: modulating hydrogen storage in metal-organic framework materials via cation exchange.
in Faraday discussions
Yang S
(2013)
Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide.
in Journal of the American Chemical Society
Yang S
(2014)
Inelastic neutron scattering study of binding of para-hydrogen in an ultra-microporous metal-organic framework
in Chemical Physics
Yang S
(2012)
Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host.
in Nature chemistry
Yang S
(2012)
A partially interpenetrated metal-organic framework for selective hysteretic sorption of carbon dioxide.
in Nature materials
Yang W
(2012)
Selective CO2 uptake and inverse CO2/C2H2 selectivity in a dynamic bifunctional metal-organic framework
in Chemical Science
Zavakhina MS
(2017)
Halochromic coordination polymers based on a triarylmethane dye for reversible detection of acids.
in Dalton transactions (Cambridge, England : 2003)
Zhang X
(2017)
Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal-Organic Frameworks.
in Journal of the American Chemical Society
Description | We are developing a portfolio of novel metal organic framework materials. These are porous polymers with very large internal surface areas. This property makes them ideal for further development for applications such as carbon capture & storage, hydrogen storage for on board vehicle use, methane storage and purification and hydrocarbon separation. We have developed a rage of materials that show selectivity for CO2, SO2, NO2, CH4, ethane, ethylene and acetylene. These works are supported by comprehensive structural, dynamic and spectroscopic studies. Recent work has discovered new porous materials for NO2 capture, storage and conversion to nitric acid. We have now prepared materials that are active for the catalytic reduction of NO2 to N2 |
Exploitation Route | Novel products for gas adsorption and selectivity |
Sectors | Aerospace Defence and Marine Chemicals Education Energy Environment Pharmaceuticals and Medical Biotechnology |
URL | http://www.manchester.ac.uk |
Description | We have been approached by 17 companies interested in our carbon capture MOFs. We have secured further funding to develop the commercialisation of these materials and work is ongoing in this area. Our reseach has stimulated considerable media interest and has been widely disseminated to the public through articles that featured on BBC website and radio. We have won funding via an ERC Advanced Grant and a Russian Mega Grant in collaboration with the Russian Academy of Sciences. We are now seeking to commercialise our materials for use in clean air technologies to remove toxic and polluting gases. We have prepared a series of porous metal organic framework materials that are now being commercilaised by the Wanyin Company in China. These materials selectively capture NO2 and SO2 from air, are water stable and show good capacity for storage of these corrosive and toxic gases. Recent work on ammonia storage has also been highlighted to several companies, and systems that can catalytically or photo-catalytically reduce CO2 to HCOOH are being investigated with BP. |
First Year Of Impact | 2018 |
Sector | Chemicals,Energy,Environment |
Impact Types | Societal Economic |
Description | Exhibitor at UK Materials Research Exchange, February 2014 |
Description | Meeting with Chris Leslie MP |
Description | Reference in Eight Great Technologies - David Willets |
Description | ERC Proof of Concept |
Amount | |
Organisation | European Research Council (ERC) |
Sector | Public |
Country | Belgium |
Start |
Title | Development of novel gas dosing system at STFC Diamond facility |
Description | |
Type Of Material | |
Provided To Others? | No |
Description | General Motors |
Organisation | General Motors |
Country | United States |
Sector | Private |
PI Contribution | Synthesis of MOF materials |
Collaborator Contribution | Testing of MOF materials |
Impact | Results are conifdential |
Start Year | 2009 |
Description | Johnson Matthey Technology Centre |
Organisation | Johnson Matthey |
Country | United Kingdom |
Sector | Private |
Start Year | 2005 |
Title | METAL -ORGANIC FRAMEWORKS (MOF) FOR GAS CAPTURE |
Description | The present invention relates to a metal organic framework comprising of a metal ion (M) and an organic ligand wherein more than one hydroxy ligand are present about the metal ion. Also provided is a method for synthesisng the metal-organic frameworks and their application in areas including scrubbing exhaust gas streams of acidic gases, scrubbing natural gas of acidic gases by separation or sequestration and separating C2Ha or other VOC gases from other gas mixtures. |
IP Reference | WO2013144628 |
Protection | Patent application published |
Year Protection Granted | 2013 |
Licensed | No |
Impact | Under negotiation |
Title | METAL-ORGANIC FRAMEWORKS |
Description | The present invention relates to metal-organic frameworks and, in particular, a continuous flow process for synthesising a metal-organic framework comprising the steps of: providing a ligand and a metal salt which are suitable for forming a metal-organic framework, mixing the ligand and metal salt with a solvent to form a mixture, and providing the mixture at a temperature sufficient to cause the ligand and the metal salt to react to form a metal-organic framework. The invention also relates to a method for the treatment of a metal-organic framework to extract unreacted ligand from the metal organic framework, a method for synthesising a metal-organic framework using recycled unreacted ligand, and uses for metal-organic frameworks. |
IP Reference | WO2014013274 |
Protection | Patent application published |
Year Protection Granted | 2014 |
Licensed | No |
Impact | Follow on funding secured to help commercialise the technology |
Title | Metal-Organic Frameworks |
Description | Novel MOF with high methane storage capacity |
IP Reference | GB1222522.3 |
Protection | Patent application published |
Year Protection Granted | 2012 |
Licensed | No |
Impact | High level publication |
Description | 'New Holey Material soaks up CO2' |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Article on BBC Science web pages based on our Nature Materials publication. Increased media interest in our research |
Year(s) Of Engagement Activity | 2012 |
Description | Boost for carbon capture from Non toxic adsorber |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Reuters press release on Nature Chemistry paper on new carbon capture MOF. contact from 14 companies interested in learning more about our technology |
Year(s) Of Engagement Activity | 2012 |
Description | Capter et eliminer le CO2 a la source |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Article published in Decouverte magazine produced by the Palais de la Decouverte in Paris and distributed at the museum. Article is about our research into carbon capture MOFs. Increase interest in our research |
Year(s) Of Engagement Activity | 2013 |
Description | ChemEnSus project |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Media (as a channel to the public) |
Results and Impact | University of Nottingham press release/blog about ChemEnSus project. Increased mnedia interest in our project |
Year(s) Of Engagement Activity | 2012 |
Description | High capacity MOF shows clean fuel promise |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Article in Royal Society of Chemistry Chemistry World Magazine highlighting research findings published in Chemical Science paper. Increased contact about our research |
Year(s) Of Engagement Activity | 2013 |
Description | I'm a scientist get me out of here! |
Form Of Engagement Activity | |
Part Of Official Scheme? | No |
Primary Audience | |
Year(s) Of Engagement Activity |
Description | MOF gate opens selective CO2 storage door |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Article in Royal Society Chemistry World magazine about selective CO2 adsorption in a MOF published in Chemical Science in 2012. Further enquiries about our research/materials |
Year(s) Of Engagement Activity | 2012 |
Description | New chemical sponge has potential to mitigate carbon footprint of oil industry |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Professional Practitioners |
Results and Impact | Press release with STFC about research results published in Nature Chemistry |
Year(s) Of Engagement Activity | 2014 |
URL | http://www.isis.stfc.ac.uk/science/energy/new-chemical-sponge-has-potential-to-mitigate-carbon-footp... |
Description | Potential carbon capture role for new CO2 absorbing material |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | University of Nottingham press release/web page article on CO2 capture MOFs. Enquiries from industry asking for more information on our materials |
Year(s) Of Engagement Activity | 2012 |
Description | Radio interview |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Public/other audiences |
Results and Impact | BBC Radio Nottingham Interview about new materials for carbon capture based around Nature Chemistry paper. Further media interest stimulated |
Year(s) Of Engagement Activity | 2012 |
Description | SET for Britain Event |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Policymakers/politicians |
Results and Impact | ChemSnSus PhD student Mathew Savage was selected through a national competition to present a poster of his research at the SET for Briain 2013 event hosted at the Houses of Parliament to an audience of MPs and other distinguished guests. Increase awareness of our research amongst policy makers |
Year(s) Of Engagement Activity | 2013 |
Description | Scientific discovery offers 'green' solution in fight against greenhouse gases |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Press release/web page article from University of Nottingham Communications team on latest research into carbon capture MOF materials. Media interest in our research including BBC Radio and online |
Year(s) Of Engagement Activity | 2012 |
Description | Towards a cleaner-carbon future |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | One of Science & Technology Facilities Highlights of 2012 is focused on joint ChemEnSus/STFC research into carbon capture MOFs. Further opportunities to access facilities at sTFC |
Year(s) Of Engagement Activity | 2013 |