Improvements in Gas Turbine Performance via Novel Plasma Spray Coatings offering Protection against Ingested Species
Lead Research Organisation:
University of Cambridge
Department Name: Materials Science & Metallurgy
Abstract
This project will involve extensive collaboration between three teams of researchers, two in the UK and one in India. The expertise and facilities of the three teams are highly complementary and together constitute a uniquely appropriate set of resources to tackle the challenges of the proposed programme. In addition, three industrial partners, all with highly relevant technical background and interests, will be actively engaged in the research. There will be extensive exchanges of samples and personnel between the partners, designed to disseminate technical expertise and facilitate the experimental programme. The work will concern an important area of manufacturing development, namely improvement of the performance of protective ceramic coatings in gas turbine engines (for both propulsion and power generation). In particular, the proposed research will lead to improved understanding of the mechanisms by which ingested species (such as sand, ash, salt etc) can cause degradation and debonding of these coatings, and also to evaluation of some promising counter-measures (which have not previously been investigated for this purpose). The coatings will be produced by plasma spraying, an advanced manufacturing technique used by several of the partners, with novel variants of the process also being available within the partnership. Experimental work will also encompass the use of a small jet engine to investigate the adhesion of ingested particulate on substrates within the turbine, complemented by extensive modelling studies.
Planned Impact
Beneficiaries
1) Suppliers of Coatings and Coating Technology. There are several UK-based firms involved in supply of (thick) ceramic coatings of the type used for thermal barrier function (and also abradable coatings for gas flow control). Prominent among these is Monitor Coatings, which is a partner in the proposed programme. They would clearly be well-placed to take advantage of information emerging from the project.
2) Suppliers of Gas Turbine Engines. AMT is a small, but rapidly growing, firm involved in the manufacture of small gas turbine aeroengines. The collaborative work planned with them should give valuable insights into the factors affecting adhesion of ingested particulate within aeroengines. Furthermore, outcomes of the programme will be of considerable benefit to various other firms involved in manufacture, supply and maintenance of gas turbines being used for various purposes.
3) Airlines and Air Travellers. Improved understanding of the effects involved should contribute to improved confidence concerning engine toleration limits. This confidence would also relate to issues such as inspection regimes after exposure. Reduction in current levels of uncertainty, both about CMAS effects generally and concerning specific volcanic ash emissions, should benefit airlines and users of air transport.
4) Researchers working on high temperature protection systems. Some project outcomes will be of interest to a wide range of researchers. These include work on the adhesion of hot ceramic particles following high speed impact onto substrates. There should also be improvements in the understanding of (impurity-enhanced) sintering phenomena, which are relevant to a wide range of situations.
Dissemination, Impacts and Timescales
Dissemination will be mainly via publication in the open literature and a project website. The UK TBC Network (see http://www.msm.cam.ac.uk/mmc/index.php/research/tbc-network), an informal grouping of researchers and industrialists in the UK, will also be utilized. A workshop will be held in Cambridge, in collaboration with the Network. Close contact will be maintained throughout between UK and Indian collaborators, and with the industrial partners. Impact will partly be in the form of improved understanding of the effects of CMAS on the performance of aeroengines, particularly via effects on TBCs. This could contribute to the evolution of international agreements concerning exposure limits and guidelines for airlines flying in the vicinity of major volcanic emissions. Development of coating formulations with improved resistance to CMAS/VA-enhanced degradation would clearly have a strong impact. The timescale for such developments is probably of the order of 5 years (from the point when confidence in the background understanding has reached a suitable level).
1) Suppliers of Coatings and Coating Technology. There are several UK-based firms involved in supply of (thick) ceramic coatings of the type used for thermal barrier function (and also abradable coatings for gas flow control). Prominent among these is Monitor Coatings, which is a partner in the proposed programme. They would clearly be well-placed to take advantage of information emerging from the project.
2) Suppliers of Gas Turbine Engines. AMT is a small, but rapidly growing, firm involved in the manufacture of small gas turbine aeroengines. The collaborative work planned with them should give valuable insights into the factors affecting adhesion of ingested particulate within aeroengines. Furthermore, outcomes of the programme will be of considerable benefit to various other firms involved in manufacture, supply and maintenance of gas turbines being used for various purposes.
3) Airlines and Air Travellers. Improved understanding of the effects involved should contribute to improved confidence concerning engine toleration limits. This confidence would also relate to issues such as inspection regimes after exposure. Reduction in current levels of uncertainty, both about CMAS effects generally and concerning specific volcanic ash emissions, should benefit airlines and users of air transport.
4) Researchers working on high temperature protection systems. Some project outcomes will be of interest to a wide range of researchers. These include work on the adhesion of hot ceramic particles following high speed impact onto substrates. There should also be improvements in the understanding of (impurity-enhanced) sintering phenomena, which are relevant to a wide range of situations.
Dissemination, Impacts and Timescales
Dissemination will be mainly via publication in the open literature and a project website. The UK TBC Network (see http://www.msm.cam.ac.uk/mmc/index.php/research/tbc-network), an informal grouping of researchers and industrialists in the UK, will also be utilized. A workshop will be held in Cambridge, in collaboration with the Network. Close contact will be maintained throughout between UK and Indian collaborators, and with the industrial partners. Impact will partly be in the form of improved understanding of the effects of CMAS on the performance of aeroengines, particularly via effects on TBCs. This could contribute to the evolution of international agreements concerning exposure limits and guidelines for airlines flying in the vicinity of major volcanic emissions. Development of coating formulations with improved resistance to CMAS/VA-enhanced degradation would clearly have a strong impact. The timescale for such developments is probably of the order of 5 years (from the point when confidence in the background understanding has reached a suitable level).
People |
ORCID iD |
Trevor Clyne (Principal Investigator) | |
Sai Gu (Co-Investigator) |
Publications

Campbell J
(2018)
Mechanical properties of sprayed overlayers on superalloy substrates, obtained via indentation testing
in Acta Materialia

Dean J
(2016)
Influence of the composition and viscosity of volcanic ashes on their adhesion within gas turbine aeroengines
in Acta Materialia

Gozali E
(2015)
Numerical investigation on effects of nanoparticles on liquid feedstock behavior in High Velocity Oxygen Fuel (HVOF) suspension spraying
in Surface and Coatings Technology

Gozali E
(2014)
Numerical Analysis of Multicomponent Suspension Droplets in High-Velocity Flame Spray Process
in Journal of Thermal Spray Technology


Katranidis V
(2017)
Experimental study of high velocity oxy-fuel sprayed WC-17Co coatings applied on complex geometries. Part A: Influence of kinematic spray parameters on thickness, porosity, residual stresses and microhardness
in Surface and Coatings Technology

Mahrukh M
(2017)
Numerical Analysis of the Effects of Using Effervescent Atomization on Solution Precursor Thermal Spraying Process
in Industrial & Engineering Chemistry Research

Mahrukh M
(2017)
Experimental Study of the Effects of Using Different Precursor Concentrations, Solvent Types, and Injection Types on Solution Precursor High-Velocity Oxygen Fuel (HVOF) Nanostructured Coating Formation
in Industrial & Engineering Chemistry Research

Mahrukh M
(2016)
Modeling the Effects of Concentration of Solid Nanoparticles in Liquid Feedstock Injection on High-Velocity Suspension Flame Spray Process
in Industrial & Engineering Chemistry Research

Mahrukh M
(2016)
Effects of angular injection, and effervescent atomization on high-velocity suspension flame spray process
in Surface and Coatings Technology
Description | Substantial advances have been made concerning the hazards presented by ingestion of volcanic ash (VA) into (aeroengine) gas turbines, and possible protective measures. In particular, experimental and modelling work has led to improved understanding of the factors affecting the adhesion of VA on solid surfaces in turbines. These include particle size and softening characteristics, which in turn are sensitive to the composition of the VA (and the type of volcano concerned). There have also been developments in the capabilities for modelling of the transport phenomena involved. |
Exploitation Route | These findings are of considerable interest to several organizations, including Rolls Royce, EasyJet and DSTL, all of which are members of the PROVIDA consortium (based in the Gordon Laboratory). Plans are being made for a joint project involving these organizations. |
Sectors | Aerospace, Defence and Marine,Energy,Transport |
URL | http://www.ccg.msm.cam.ac.uk/initiatives/provida |
Description | This project has led to extensive collaboration and interest, including the creation of a major consortium comprising about 10 organisations - see http://www.ccg.msm.cam.ac.uk/provida. It is now clear that protective measures should involve, not only monitoring of ash levels in the atmosphere, but sampling of the ash (using drones) and analysis of the particle size distribution and composition. This will allow a much higher level of confidence in making decisions about any restrictions or recommendations about flying in the vicinity of the eruption concerned. |
First Year Of Impact | 2015 |
Sector | Aerospace, Defence and Marine,Energy,Manufacturing, including Industrial Biotechology,Transport |
Impact Types | Economic |
Title | High speed impact of ash pellets |
Description | A new methodology has been developed for making large pellets of volcanic ash, heating them above their glass transition temperature, projecting them at a substrate in a gas gun (at ~100 m/s) and using high speed photography to record their in-flight and substrate impact behaviour. |
Type Of Material | Improvements to research infrastructure |
Provided To Others? | No |
Impact | It has been shown that the source (type of volcano) and composition (particularly the content of cations other than silicon) has a strong effect on the fluidity of the pellets under these high strain rate conditions, and hence on the likelihood of particles of the ash concerned adhering to surfaces inside aeroengine turbines. |
URL | http://www.ccg.msm.cam.ac.uk/initiatives/provida/overview |
Title | Use of Dilatometry for measurement of Glass Transition Temperatures of Powders |
Description | Measurement of the glass transition temperature of powders (eg volcanic ashes) is commonly carried out using TGA or DSC methods. However, this is often unsatisfactory, particularly if the glass content is relatively small. By making a powder compact, and then using dilatometry (with a small applied force on the sample), the softening that occurs on passing through the glass transition is readily detected, since it allows the compact to densify. |
Type Of Material | Improvements to research infrastructure |
Year Produced | 2014 |
Provided To Others? | Yes |
Impact | There is a consortium (http://www.ccg.msm.cam.ac.uk/provida) working on the effect of ingestion of volcanic ashes into aeroengines, and this procedure was disseminated to all partners. Since we are studying various ashes, and they have a range of glass transition temperatures (which are important in determining whether particles adhere to surfaces in the engine), this is a useful technique |
URL | http://www.ccg.msm.cam.ac.uk/provida |
Description | PROVIDA Consortium (Rolls Royce) |
Organisation | Rolls Royce Group Plc |
Country | United Kingdom |
Sector | Private |
PI Contribution | The Gordon Laboratory in Cambridge hosts the PROVIDA consortium and coordinates its activities. There are biannual meetings in Cambridge, attended by 10-15 people, and a website is provided (see the URL below). |
Collaborator Contribution | Rolls Royce attend the meetings and participate in various collaborative activities. |
Impact | This link has lead to several initiatives, including participation in a a large (invitation-only) Symposium being held in Cambridge in April 2016 (to be attended by 50 delegates). It is funded by the Helmholtz Association. |
Start Year | 2014 |
Description | PROVIDA consortium (DSTL) |
Organisation | Defence Science & Technology Laboratory (DSTL) |
Country | United Kingdom |
Sector | Public |
PI Contribution | The PROVIDA consortium is hosted in the Gordon Laboratory in Cambridge, where there are biannual meetings. These are attended by 10-15 people. There is also a website (see below) and various joint activities. |
Collaborator Contribution | DSTL attend the PROVIDA meetings and contribute actively to various collaborative activities. |
Impact | DSTL have encouraged participation in other consortia and project concerned with volcanic ash and a joint proposal is now being considered. |
Start Year | 2014 |
Description | PROVIDA consortium (EasyJet) |
Organisation | EasyJet |
Country | United Kingdom |
Sector | Private |
PI Contribution | EasyJet are part of the PROVIDA consortium, which is hosted by the Gordon Laboratory in Cambridge (see the URL below). There are biannual meetings in Cambridge, attended by 10-15 people. |
Collaborator Contribution | EasyJet attend these meetings, have funded trips to Iceland to collect volcanic ash samples and are arranging large scale aeroengine tests using ash provided by Cambridge. |
Impact | Extensive collaborative work and preparation of proposals for future funding. Other partners include Rolls Royce, DSTL, DLR and several Universities in Norway, Sweden, India and the UK. |
Start Year | 2014 |
Description | Creation of PROVIDA consortium |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Participants in your research and patient groups |
Results and Impact | The PROVIDA ("PROtection against Volcanic ash Induced Damage in Aeroengines") consortium was created as a direct result of publicity emerging from the launch of the EPSRC project. Two meetings of the consortium have already been held, with about 20 attendees in each case. About 30 individuals are involved in the consortium, representing 15 organisations (from academia, industry and government research institutes). There has already been extensive exchange of information, results and samples for experimental study. |
Year(s) Of Engagement Activity | 2014 |
URL | http://www.ccg.msm.cam.ac.uk/provida |