Capability for Science of the Future: Ultrafast Spectroscopy Laser Centre at Sheffield, USLS

Lead Research Organisation: University of Sheffield
Department Name: Chemistry

Abstract

We propose to build an ultrafast laser spectroscopy system which, by exploiting modern technological advances, will allow us to examine in many different ways what happens to molecules and materials after they absorb light, both immediately after absorption and then the longer-term consequences.

The interaction of light with matter is one of the most important areas in modern science. It underpins the emerging technology of new photonics-based materials that can be used in the communications, computing, displays and lighting devices of the future; the economic impact of this technology sector in the short-to-medium term is predicted to be very large. Interaction of light with matter is also the basis of the conversion of sunlight into energy by photosynthesis - which is fundamental to life on earth. Natural photosynthesis is quite well understood and is sufficiently effective for Nature's needs: the goal now is to build artificial systems that mimic the key properties of natural photosynthetic systems so that we can, finally, harvest sunlight as an energy source and make a major contribution to mankind's long-term sustainable energy generation that is not fossil-fuel dependent and is not polluting. The tasks of artificial photosynthesis are extensive: not only do we need to construct molecular systems or materials that can capture light effectively, but they need to be able to use it to either generate energy directly (e.g. as electricity in photovoltaic cells), or to drive chemical reactions that provide 'stored energy' as a solar fuel (e.g. by providing energy for conversion of the waste-product CO2 to the fuel methanol).

All research in light/matter interactions - whether it is directed at understanding nature, harnessing energy, or constructing new optical communications devices - requires the ability to measure the extremely fast changes that occur in molecules and materials immediately after light is absorbed. The initial changes take place on a timescale of femtoseconds and may involve movement of electron density, or changes in bond vibrations, which can be detected. Subsequent to this the captured energy 'flows' through the molecular assembly or material, and this movement of charge or energy from place to place - which can occur on timescales from picoseconds to microseconds - can again be visualized in detail. Finally any subsequent chemical changes that may occur on timescales as slow as milliseconds will be visualized. The result will be the ability to monitor exactly what happens in materials and molecular assemblies once the photon of light is absorbed; as the energy or an electron subsequently moves through the material and/or results in structural changes; and as the energy is finally used in various ways from luminescence to triggering chemical reactions.

The facility that we will build will be unique in the UK university system as it will combine diverse aspects of ultrafast spectroscopy in a single, integrated facility which will enable the most comprehensive set of measurements possible at a single site with a single sample. The facility will combine a wide range of timescales that can be measured (all events from femtoseconds to milliseconds, which spans 11 orders of magnitude); a continuous spectrum of energies from low-energy vibrations to high-energy electronic transitions; and a wide range of interrogation techniques that allow changes in structure and electronic properties to be probed in real time. This will provide researchers both in Sheffield and the wider UK community - with whom the facility will be shared, by creating an "ultrafast hub" - access to a state-of-the-art tools for studying light-matter interactions. This will facilitate a wide range of science in areas of national importance and potentially benefit society from technological developments (such as new photonics-based materials and devices) and from cleaner and cheaper energy generation using sunlight.

Planned Impact

The wide range of research facilitated by USLS will lead to correspondingly extensive impact, beyond the academic benefit from the new scientific knowledge. There will be many important economic and societal impacts which have the potential to improve diverse aspects of our lives.

Economic impact will occur in both the medium and long terms. Medium-term benefits will be mostly from the more applied research projects, that are linked to spin-out companies or industrial sponsors. A key example is photonics technologies which currently underpin > 10% of the EU economy with a projected global market of Eur 600 Bn by 2020. These include all-optical communications, energy efficient lighting, photonic diagnostics for healthcare, safety and security, and laser-based therapies. Likewise, organic optoelectronics are predicted to be a disruptive technology enabling market growth impossible with existing technology. Use of OLED displays alone are projected to drive substantial economic growth in applications such as mobile phones, TV, notebooks, tablets, digital cameras and in cars; and OLED lighting alone is predicted to have a market value of $1.3 Bn by 2023. Key beneficiaries: photonics-based industries and users of their products from development of new technology.

Improvements in energy generation - arising from a range of research projects spanning chemistry, physics, engineering and synthetic biology - will have long term economic benefits for everyone. Although many of these projects are focussed on the blue-skies research, they have potentially huge benefits. Key beneficiaries: energy sector in the medium term, society as a whole in the long term, due to lower energy costs and greater sustainability.

Societal benefit follows economic benefit. In the long term society as a whole will have higher quality of life from the reduced costs and cleaner environment associated with improved renewable energy generation, as well as access to improved photonics technologies for day-to-day issues from communications to healthcare.

In the energy field in particular, economic benefits for a few translate into global societal benefits for all. The importance of addressing the problem of sustainable energy generation cannot be overstated. Given that our most reliable energy source is the sun, solar energy capture and solar fuel generation are expected to be the most important themes of the range of projects supported by USLS.

Knowledge:
'If you think education is expensive, try ignorance' (Bok). The new knowledge arising from USLS will initially benefit academia, but as impacts and exploitations emerge this knowledge will become integrated into the areas of commerce, education and indeed everyday life. We will ensure maximum benefit from the new knowledge via engagement with schools outreach and public understanding events. An important goal is to raise awareness of the importance of sustainable alternatives to conventional energy sources: our programme of public lectures, schools events, and Science week events will emphasise this. Key beneficiaries: the public, from improved understanding of issues surrounding applications of light-based technologies and energy in general.

People:
A major long-term impact from USLS will arise from training and development of early-career researchers. Given the importance of light-based methods in the research that underpins fields from healthcare to sustainable energy, a trained pool of young scientists will be essential to maintain the UK's competitive position in these fields, ensuring the sustainability of our science and industry base on a 10-50 years time scale. Key beneficiaries will therefore be the researchers themselves, UK research / industry in the future, and society as a whole. The conference participation and training will provide immediate transferable skills to PhDs and postdocs which will enhance their future carrier to the benefit to them, science and society.
 
Description The grant is to develop a regional laser facility for use across several EPSRC portfolio areas. The facility is presently in the testing mode and will be operational in the near future.

New developments:
The facility was officially open in March 2018, to become the Lord Porter Laser Laboratory.
The website is at https://www.sheffield.ac.uk/faculty/science/research/facilities/laserlab
Exploitation Route The equipment is used by a broad range of researchers working in several areas of the EPSRC portfolio. It is used by multiple groups at the University of Sheffield, as well as groups from Oxford, Liverpool, Imperial, and UCL.
Sectors Chemicals,Energy,Environment,Healthcare

URL https://www.sheffield.ac.uk/faculty/science/research/facilities/laserlab
 
Description The findings have been used to communicate the importance of various light-driven technologies during open days.
First Year Of Impact 2018
Sector Chemicals,Education,Energy
Impact Types Cultural,Societal

 
Description EPSRC Energy Feasibility Studies
Amount £195,000 (GBP)
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 10/2017 
End 04/2019
 
Description Maximising Shared Capability of the Ultrafast Spectroscopy Laser Laboratory at Sheffield
Amount £199,277 (GBP)
Funding ID EP/R042802/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 09/2018 
End 09/2020
 
Description Property-Enhanced Porphyrins
Amount £379,305 (GBP)
Funding ID EP/R045305/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 11/2018 
End 10/2021
 
Description Singlet Fission in Carotenoid Aggregates (SIFICA)
Amount £294,636 (GBP)
Funding ID EP/S002766/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 01/2019 
End 12/2021
 
Description Singlet Fission in Carotenoid Aggregates (SIFICA)
Amount £851,312 (GBP)
Funding ID EP/S002103/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 01/2019 
End 12/2021
 
Title broadband fluorescence upconversion 
Description Broadband ultrafast fluorescence upconversion is the technique which allows to perform time-resolved emission measurements with the time resolution limited only by laser pulse. The broadband configuration that has been installed as part of collaboration with Professor Niko Ernsting, Humboldt University Berlin, is as far as we are aware the most sensitive spectral variant of the method. There is only one of these setups in the UK. It allows to measure processes such as ultrafast intersystem crossing (relevant for example to OLEDs and POLEDs), or small changes in the fluorophore's environment (relevant to, for example, emission imaging and single molecule spectroscopy of biological samples). 
Type Of Material Improvements to research infrastructure 
Year Produced 2018 
Provided To Others? Yes  
Impact The publication is in preparation 
 
Description Biology partnership 
Organisation University of Sheffield
Country United Kingdom 
Sector Academic/University 
PI Contribution Based on the findings from this project, we began a collaboration with biologists (Hunter FRS group) to examine the biological effects of singlet fission in polyenes (eg carotenoids). We measured the samples they produced and worked together to understand the findings.
Collaborator Contribution 1 PhD student made synthetic proteins, another extracted biological carotenoid complexes. We measured their samples and together understood the findings.
Impact Grant has been written and was accepted. Papers are being prepared.
Start Year 2017
 
Description Chemistry partnership 
Organisation Imperial College London
Country United Kingdom 
Sector Academic/University 
PI Contribution We asked Prof. Martin Heeney for specific materials for singlet fission. They synthesised them, we measured them and analysed the results.
Collaborator Contribution PhD student at Imperial synthesised and performed initial characterisation on a range of polyenes for singlet fission studies. Sent them to Sheffield for ultrafast characterisation by us.
Impact Paper under preparation.
Start Year 2016
 
Description Sample provider 
Organisation University of Connecticut
Country United States 
Sector Academic/University 
PI Contribution We are characterising the ultrafast electron dynamics of the unique porphyrins that the collaborator has synthesised. He send us a couple of prophyrin series in 2016 and again in 2020.
Collaborator Contribution Prof Bruckner has provided us with unique set of porphyrins.
Impact The first set of data are acquired and analysed. Publication is to come
Start Year 2016
 
Description Theoretical support 
Organisation Federal University of Rio de Janeiro
Department Institute of Chemistry
Country Brazil 
Sector Academic/University 
PI Contribution We have provided with steady-state and kinetic data on particular porphyrins.
Collaborator Contribution They have provided with modelling that will help interpret our data.
Impact A first set of porphyrins have been modelled; modelling it now to be refined based on the data we provided and publication is to come.
Start Year 2018
 
Description Theory partnership 
Organisation University of Oxford
Country United Kingdom 
Sector Academic/University 
PI Contribution We performed experiments, Prof. Barford (Oxford Chemistry) used the basis of these measurements to begin a research effort (1 PhD student) into calculations on understanding singlet fission in polyenes.
Collaborator Contribution 1 PhD student + supervisor time for calculations.
Impact 3-year grant
Start Year 2017
 
Description 2017 Energy Symposium at the U. of Sheffield 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Postgraduate students
Results and Impact Talk and poster at the 2017 Energy Symposium at the U. of Sheffield; used to showcase the group research.
Year(s) Of Engagement Activity 2017
 
Description 2017 Krebs Symposium at the U. of Sheffield 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Postgraduate students
Results and Impact Talk at the 2017 Krebs Symposium at the U. of Sheffield, to showcase the lab's capabilities.
Year(s) Of Engagement Activity 2017
 
Description 24hr Inspire 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Postgraduate students
Results and Impact Talk at the 2017's charity event 24hr Inspire to showcase the research done and raise funds.
Year(s) Of Engagement Activity 2017
 
Description AVS 63rd International Symposium and Exhibition 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Invited talk at the AVS 63rd International Symposium and Exhibition, Nashville, USA.
Year(s) Of Engagement Activity 2016
 
Description CLF User Meeting 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other audiences
Results and Impact Talk at the CLF User Meeting; to showcase current research and foster collaboration.
Year(s) Of Engagement Activity 2019
 
Description Cafe Scientifique 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Public/other audiences
Results and Impact Outreach talk to showcase the research done at the university, to the general public.
Year(s) Of Engagement Activity 2018
 
Description Festival of the Mind exhibition 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Collaboration with 4 artists to describe the research in different ways. From this project, a picture entitled 'exciton' and a lobster-flying fairy sculpture. The posters are now up in the department, where they are discussed at open days, and mugs were produced and passed out to various audiences.
Year(s) Of Engagement Activity 2017
 
Description ISPPCC 2017 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Other audiences
Results and Impact Talk given at the 2017 ISPPCC, Oxford.
Year(s) Of Engagement Activity 2017
 
Description Ignite 2017 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Public/other audiences
Results and Impact Talk at the local Ignite event, to showcase the research facility to a general audience.
Year(s) Of Engagement Activity 2017
 
Description Invited seminar 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Invited to give a seminar at the collaborator's research group, at Universidade Federal do Rio de Janeiro.
Year(s) Of Engagement Activity 2019
 
Description Laser Lab Opening 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Postgraduate students
Results and Impact Talk to showcase the research done at opening of the laser facility.
Year(s) Of Engagement Activity 2017
 
Description Postgraduate 1st year talk 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Postgraduate students
Results and Impact This is a local event organised to give PhD students the opportunity to show their work to the wider student and staff within the university.
Year(s) Of Engagement Activity 2018
 
Description Postgraduate Poster Showcase 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Postgraduate students
Results and Impact This is a local event organised to give PhD students the opportunity to showcase the group's research.
Year(s) Of Engagement Activity 2019
 
Description St Mary's Catholic High School 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Schools
Results and Impact Outreach talk at the St Mary's Catholic High School.
Year(s) Of Engagement Activity 2016
 
Description Tetra Pyrrole Discussion (Annual) Group Meeting 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Other audiences
Results and Impact Invited talk at the regional TPDGM, Liverpool.
Year(s) Of Engagement Activity 2016