Tunable Plasmonics for Ultrafast Switching at Telecom Wavelengths
Lead Research Organisation:
Heriot-Watt University
Department Name: Sch of Engineering and Physical Science
Abstract
Today's communication networks need to be supported by an ultra-broadband optical backbone in order to respond to the enormous demand for data exchange. Without the use of photonic components, the "magic" of being 24/7connected on a global scale just by using our portable devices would be impossible.
Recently, a new branch of science, called plasmonics, has gained great momentum in the scientific community, since it brings the promise to be complementary to photonics. For instance, in the realm of plasmonics, devices can function on a nanometric scale (1 nanometer [nm] = a billionth of a meter), with consequent advantages in terms of versatility, scalability, and reduced power consumption.
The proposed project "Tunable plasmonics for Ultrafast Switching at Telecom Wavelengths" is focused on novel materials for plasmonic applications (namely titanium nitride -TiN; and aluminum doped zinc oxide - AZO).
Besides solving fundamental issues typical of plasmonic devices such as poor transparency and low damage threshold, these two materials unable the possibility to engineer the light-matter interaction at will. This can be achieved either by changing the fabrication procedure or in a more dynamic fashion by means of an external excitation such as a laser beam or an applied voltage.
The core active material at the center of this project is a new kind of AZO developed inside the collaborative effort between Heriot-Watt University in UK, and the Birck Nanotechnology Center in USA. This "special" AZO is grown by unconventional methods and it exhibits ultrafast optical response (i.e. after the material properties are altered by an optical pulse, it restores its original behavior on a time scale shorter than 1 ps = 1/1000000000000 sec).
One fundamental goal of this project is gaining a deep knowledge of the physical mechanism behind the ultra-fast behavior of AZO (still not fully understood) and use this knowledge to further optimize the material for application in ultra-fast photonics. In addition to this, in order to properly evaluate the potentials of both AZO and TiN in the real world, this project includes the fabrication and testing of an optical modulator prototype (the modulator being the most fundamental building block for encoding information). This device will be interfaced with the external world with input/output TiN-based plasmonic waveguides and will exploit AZO as active core material for performing the ultra-fast signal encoding. Numerical simulations foresee outstanding performances in terms of compactness, reduced power consumption, and ultra-fast operational speed.
Recently, a new branch of science, called plasmonics, has gained great momentum in the scientific community, since it brings the promise to be complementary to photonics. For instance, in the realm of plasmonics, devices can function on a nanometric scale (1 nanometer [nm] = a billionth of a meter), with consequent advantages in terms of versatility, scalability, and reduced power consumption.
The proposed project "Tunable plasmonics for Ultrafast Switching at Telecom Wavelengths" is focused on novel materials for plasmonic applications (namely titanium nitride -TiN; and aluminum doped zinc oxide - AZO).
Besides solving fundamental issues typical of plasmonic devices such as poor transparency and low damage threshold, these two materials unable the possibility to engineer the light-matter interaction at will. This can be achieved either by changing the fabrication procedure or in a more dynamic fashion by means of an external excitation such as a laser beam or an applied voltage.
The core active material at the center of this project is a new kind of AZO developed inside the collaborative effort between Heriot-Watt University in UK, and the Birck Nanotechnology Center in USA. This "special" AZO is grown by unconventional methods and it exhibits ultrafast optical response (i.e. after the material properties are altered by an optical pulse, it restores its original behavior on a time scale shorter than 1 ps = 1/1000000000000 sec).
One fundamental goal of this project is gaining a deep knowledge of the physical mechanism behind the ultra-fast behavior of AZO (still not fully understood) and use this knowledge to further optimize the material for application in ultra-fast photonics. In addition to this, in order to properly evaluate the potentials of both AZO and TiN in the real world, this project includes the fabrication and testing of an optical modulator prototype (the modulator being the most fundamental building block for encoding information). This device will be interfaced with the external world with input/output TiN-based plasmonic waveguides and will exploit AZO as active core material for performing the ultra-fast signal encoding. Numerical simulations foresee outstanding performances in terms of compactness, reduced power consumption, and ultra-fast operational speed.
Planned Impact
The present project will definitely benefit the semiconductor and the photonic industry in the UK, and consolidate the collaborative bridge between world-class Universities located in UK and North America.
The possibility to have materials, such as AZO, capable of largely altering their dielectric permittivity on a sub-picosecond time scale, is the missing ingredient to investigate and develop many fundamental systems in quantum optics, analogue gravity, and terahertz science. In fact, the photon acceleration associated to a sudden and large change in the material refractive index can be used for the generation of entangled photon-pairs, to model the evolution of an expanding universe, or to design efficient THz sources and detectors. The beneficiaries of this knowhow will not be just scientists but also many middle size high-tech companies focused on the previously listed technologies and whose revenue is predicted to explode in the years to come.
In addition to this, other transparent conducting oxides have been largely used by the electronic industries to produce touch and flexible screens, and transparent electrodes for photovoltaic cells. A complete control over the peculiar properties of AZO thin films will make this material very profitable for commercial use since it can be used to enhance the efficiency of all these systems. Many semiconductor companies have already expressed their interest in the full development of the present project, and a partnership has been established with a Scottish semiconductor company, which is willing to provide a generous contribution in terms of material supply and services.
With regards to TiN instead, a full development of the nano-fabrication processes at the base of this material could enable disruptive technologies such as Heat Assisted Magnetic Recording (HAMR) and efficient thermo-photovoltaic. Both these applications could potentially trigger societal changes. While the former brings the promise to increase orders of magnitude the actual data storage capability, the latter could enhance the typical efficiency of photovoltaic modules up to 90%. Both these two applications have been extensively studied from a theoretical point of view but their implementation has been elusive because of the lack of materials with the proper conductivity and thermal resistance.
The proposed project will be carried on in collaboration with prestigious research partners in USA who are world leader in the design and fabrication of novel nano-photonic devices. This collaboration will permanently establish fundamental knowhow and facilities in UK labs for the fabrication and testing of nanophotonics devices, thus drastically straighten the partnership with existent collaborators and promote new ones with other national and international top groups.
The possibility to have materials, such as AZO, capable of largely altering their dielectric permittivity on a sub-picosecond time scale, is the missing ingredient to investigate and develop many fundamental systems in quantum optics, analogue gravity, and terahertz science. In fact, the photon acceleration associated to a sudden and large change in the material refractive index can be used for the generation of entangled photon-pairs, to model the evolution of an expanding universe, or to design efficient THz sources and detectors. The beneficiaries of this knowhow will not be just scientists but also many middle size high-tech companies focused on the previously listed technologies and whose revenue is predicted to explode in the years to come.
In addition to this, other transparent conducting oxides have been largely used by the electronic industries to produce touch and flexible screens, and transparent electrodes for photovoltaic cells. A complete control over the peculiar properties of AZO thin films will make this material very profitable for commercial use since it can be used to enhance the efficiency of all these systems. Many semiconductor companies have already expressed their interest in the full development of the present project, and a partnership has been established with a Scottish semiconductor company, which is willing to provide a generous contribution in terms of material supply and services.
With regards to TiN instead, a full development of the nano-fabrication processes at the base of this material could enable disruptive technologies such as Heat Assisted Magnetic Recording (HAMR) and efficient thermo-photovoltaic. Both these applications could potentially trigger societal changes. While the former brings the promise to increase orders of magnitude the actual data storage capability, the latter could enhance the typical efficiency of photovoltaic modules up to 90%. Both these two applications have been extensively studied from a theoretical point of view but their implementation has been elusive because of the lack of materials with the proper conductivity and thermal resistance.
The proposed project will be carried on in collaboration with prestigious research partners in USA who are world leader in the design and fabrication of novel nano-photonic devices. This collaboration will permanently establish fundamental knowhow and facilities in UK labs for the fabrication and testing of nanophotonics devices, thus drastically straighten the partnership with existent collaborators and promote new ones with other national and international top groups.
Publications
Khurgin J
(2020)
Adiabatic frequency shifting in epsilon-near-zero materials: the role of group velocity
in Optica
Bruno V
(2020)
Broad Frequency Shift of Parametric Processes in Epsilon-Near-Zero Time-Varying Media
in Applied Sciences
Clerici M
(2017)
Controlling hybrid nonlinearities in transparent conducting oxides via two-colour excitation.
in Nature communications
Carnemolla E
(2018)
Degenerate optical nonlinear enhancement in epsilon-near-zero transparent conducting oxides
in Optical Materials Express
Kim J
(2018)
Dynamic Control of Nanocavities with Tunable Metal Oxides.
in Nano letters
Bruno V
(2020)
Dynamical Control of Broadband Coherent Absorption in ENZ Films
in Micromachines
Carnemolla E.G.
(2018)
Giant nonlinear frequency shift in epsilon-near-zero aluminum zinc oxide thin films
in 2018 Conference on Lasers and Electro-Optics, CLEO 2018 - Proceedings
Bruno V
(2020)
Negative Refraction in Time-Varying Strongly Coupled Plasmonic-Antenna-Epsilon-Near-Zero Systems.
in Physical review letters
Vezzoli S
(2018)
Optical Time Reversal from Time-Dependent Epsilon-Near-Zero Media.
in Physical review letters
Ferrera M
(2018)
Ultra-fast transient plasmonics using transparent conductive oxides
in Journal of Optics
Description | My research has provided a new upper limit for the nonlinear figure of merit of bulk materials which takes into account magnitude and speed of the nonlinearities together with their energy efficiency. My study lay down the bases for the employment of transparent conductive oxides for the realisation of alternative ultra-compact and ultra-fast telecom devices and provide with key insights on the electronic structures of these complex materials. In addition to this, my research results proved for the first time simultaneous giant hybrid nonlinearities stimulated by interband and intraband optical excitation. Most recently, my research has proved that nonlinear degenerate configurations (i.e. both control signal and probe signal operate at the same wavelength) can further increase nonlinearities for optical modulation (nonlinear refractive index change) and frequency conversion (four-wave mixing, third harmonic generation). My research has also been proved applicable for creating optical logic units and for the design of ultra-compact terahertz detection devices. |
Exploitation Route | The class of transparent conducting oxides (TCOs) has been industrially developed for electro-optic applications but little is still know about their ultra-fast nonlinearities. Our findings are of general interest and even if determined on a few test materials they can be applied (as we proved) to the entire category of TCOs. This material platform is extremely promising for numerous application such as the detection and generation of THz radiation, on-chip generation of nonclassical states of light, and ultra-fast optical ALU. All the collected data which are available open source (or on request) will greatly benefit all the industrial and research entities focused on integrated photonics. My research has led to the creation of numerical models for the analysis of ultra-fast photo carrier dynamics which are of general interest for the integrated photonics community and are openly available. |
Sectors | Aerospace Defence and Marine Chemicals Digital/Communication/Information Technologies (including Software) Energy Environment Manufacturing including Industrial Biotechology |
Description | My finding have been used by different institutions (also not academic or research related) for investigating new alternative design for integrated photonic devices. The results also stimulated the discussion about the future of integrated nonlinear photonics and its commercialisation. Finally, the visibility attained was also used to promote and explain photonics to the general public. Industrial partners, involved in the semiconductor sector, have enlarged their portfolio of available thin films by including the novel conductive oxides developed in my project. My most recent findings have been fundamental to start developing a consistent, broadband, and robust non-perturabative theory for describing guided nonlinear optics in index-near-zero coupled devices and thin films. |
Sector | Digital/Communication/Information Technologies (including Software),Energy,Environment,Security and Diplomacy |
Impact Types | Cultural Societal Economic |
Description | Research Grant |
Amount | £15,000 (GBP) |
Organisation | The Royal Society |
Sector | Charity/Non Profit |
Country | United Kingdom |
Start | 11/2017 |
End | 10/2018 |
Description | Zero-Index Metasurfaces |
Amount | £15,000 (GBP) |
Organisation | Carnegie Trust |
Sector | Charity/Non Profit |
Country | United Kingdom |
Start | 08/2020 |
End | 02/2022 |
Title | Two-colour excitation Data Base |
Description | A great number of data about interband and intraband carrier recombination dynamics has been collected and made available to scientists |
Type Of Material | Database/Collection of data |
Year Produced | 2017 |
Provided To Others? | Yes |
Impact | Other scientist used the available data for computer assisted simulations where devices employing our materials were targeted |
Description | Alternative materials for plasmonic applications in the VIS-NIR |
Organisation | Helia Photonics |
Country | United Kingdom |
Sector | Private |
PI Contribution | numerical modelling of material transient optical properties and optical characterisation in linear and nonlinear regime |
Collaborator Contribution | material development and device fabrication |
Impact | The main outcome of this collaboration is related to 2 extra important published papers and a generous support for device fabrication |
Start Year | 2017 |
Description | Alternative materials for plasmonic applications in the VIS-NIR |
Organisation | Purdue University |
Department | College of Engineering |
Country | United States |
Sector | Academic/University |
PI Contribution | numerical modelling of material transient optical properties and optical characterisation in linear and nonlinear regime |
Collaborator Contribution | material development and device fabrication |
Impact | The main outcome of this collaboration is related to 2 extra important published papers and a generous support for device fabrication |
Start Year | 2017 |
Description | Optical Neural Network for ultra-fast computing |
Organisation | Optalysys Ltd |
Country | United Kingdom |
Sector | Private |
PI Contribution | Access to our characterisation facilities and sample testing |
Collaborator Contribution | samples to be characterised in the nonlinear regime PhD scholarship for one student (to be renegotiated due to COVID) |
Impact | the actual collaboration has been put on standby due to COVID disruptions |
Start Year | 2019 |
Description | BBC Scotland "Beating the electronic speed limit with light" |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | BBC article reporting my research activities in nonlinear optics using transparent conducting oxides. This article let me gain enormous visibility also among colleagues. |
Year(s) Of Engagement Activity | 2017 |
URL | http://www.bbc.co.uk/news/uk-scotland-41517202 |
Description | Good morning Scotland BBC radio interview |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Public/other audiences |
Results and Impact | A BBC reporter interviewed me for Good morning Scotland a well-known cultural radio show. After the interview I have been contacted by possible applicants for PhD projects in my group, possible investors in my research activities, and collaborators. |
Year(s) Of Engagement Activity | 2017 |
URL | http://www.bbc.co.uk/programmes/b095yr11#play |
Description | Nano meet photon |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Public/other audiences |
Results and Impact | The meeting was organised by the Italian Cultural Institute in Edinburgh and publicised on their website for quite some time. This meeting was designed to provide the audiences with a very general overview of what photonics is, how it pervades modern technologies, and the recent developments towards ultra-fast nanophotonics. I also took the chance to report in very simplified terms my recent scientific results for application in ultra-fast optics and quantum information. I received a great feedback from various audiences and the debate was very stimulating. I established contact with potential PhD candidates who wish to work in my group and with media service who would like to organise similar event in the future to enhance scientific dissemination towards the general public. |
Year(s) Of Engagement Activity | 2017 |
URL | http://www.iicedimburgo.esteri.it/iic_edimburgo/en/gli_eventi/calendario/2017/11/nano-meets-photon.h... |
Description | Participation to the 2018 CommNet2 Positive Collaborative Research Networking |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Professional Practitioners |
Results and Impact | A networking event involving scientist and industries in the field of integrated photonics and optical communication in general |
Year(s) Of Engagement Activity | 2018 |
URL | https://commnet.ac.uk/wp-content/uploads/2018/02/CommNet2-Positive-Collaborative-Research-for-ECA-Br... |
Description | SUPA newsletters (2017) |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Professional Practitioners |
Results and Impact | Scottish University Physics Alliance (SUPA) newsletters. Thanks to this press release I gained great visibility specifically within the scientific community in Scotland |
Year(s) Of Engagement Activity | 2017 |
URL | https://us12.campaign-archive.com/?u=896bf415ff507b6b1835d3708&id=cef24da760 |
Description | Seminar at the Physics student Union - Heriot-Watt University |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Undergraduate students |
Results and Impact | One-hour seminar describing the fundamental challenges to develop future nonlinear integrated photonics devices. |
Year(s) Of Engagement Activity | 2020 |
URL | https://www.facebook.com/events/heriot-watt-physics-society/colloquium-with-dr-marcello-ferrera-nano... |
Description | Seminar to the public "Nonlinear nano-photonics"- Lyell centre opening |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Public/other audiences |
Results and Impact | In occasion of the opening day of the Lyell centre, I was invited to give a 50min talk about all-optical nano-photonic technologies. In this occasion I publicised to the cereal public and students my research activities involving giant nonlinearities using alternative and sustainable transparent conductive oxides. The event had great visibility because it was multidisciplinary and people arrived from different area in Scotland for attending the event. About 20 people were present in the auditorium during my talk which stimulated a long debate afterwards. |
Year(s) Of Engagement Activity | 2018 |
URL | http://www.lyellcentre.ac.uk/docs/Press_release_opening_Our_Doors_To_The_Public_2018.pdf |