GraNet - Graphene / Polypropylene Composite Nets for Filtration

Lead Research Organisation: University of Bradford
Department Name: Faculty of Engineering and Informatics

Abstract

This project will investigate the use of Graphene to form a composite material with polypropylene, a widely used plastic. If Graphene platelets can be successfully dispersed within the polypropylene matrix then it should be possible to achieve significant improvements in material properties. The project team comprises Delstar (DS), Graphene producers Thomas Swan (TS), Graphene functionalisers Haydale (HD) and the University of Bradford (UoB). The particular target application
for this research is a special type of filtration net, which is produced by extruding a thin film layer, embossing a pattern onto the film and then stretching it to produce holes. It is anticipated that by introduction of a small percentage of Graphene into the base polymer, properties such as physical strength and operating temperature of the filtration nets can be improved, which will allow polypropylene to replace more expensive and denser plastics.

The project will explore how to achieve a good dispersion and exfoliation of Graphene platelets within the plastic without damaging them and hence reducing their benefit. Initial studies at UoB will focus on small laboratory scale extrusion
experiments using different types of Graphene (produced by TS and modified by HD) and a range of process conditions. After characterisation, the most successful compounds will be produced on a bigger scale and formed into films, which can be stretched to mimic the industrial process. Finally, after the optimum formulation and process conditions have been determined, an industrial scale batch of composite material (100kg) will be produced and used in production trials at DS. These demonstrator products will be provided to their customers for feedback in target markets. Notably, the whole supply chain for these new products, including Graphene production, compounding, extrusion/embossing and filter cartridge manufacture will be based in the UK.

Planned Impact

Beneficiaries of this research will include both the public and private sectors, particularly areas associated with Graphene and polymeric films. In the short term, the rapidly emerging UK Graphene industry will benefit from the knowledge of how Graphene features, such as platelet size and functionality, can influence the properties of a commodity polymer such as polypropylene. The polymer processing industry will benefit from a better understanding of the optimum process conditions to produce improved composite properties by achieving high levels of dispersion and exfoliation. Short-term, direct benefits will largely be realised by those sectors of the industry directly involved with Graphene and polypropylene films, however the wider understanding of polymer-Graphene composite materials will encourage further research and product development with a wider range of polymer types, production processes and applications.

The specific focus of this project is to improve the properties of filtration netting products. Filter cartridges are widely used in a number of industrial applications for the filtration of contaminants from air, water and oils. The introduction of lighter weight, higher strength and higher operating temperature products will directly benefit many sectors of UK industry by improved performance and reduced size. Notably, all links in the proposed supply chain for the manufacture of these improved filter cartridges are UK based, so there will be a tangible benefit for the UK economy through increased market share and job creation.


The UK polymer research community will also benefit from the publication of research in this emerging field. The IRC Polymer Engineering Research Group at Bradford has significant experience in processing a wide range of composite and nanocomposite materials and will benefit from the opportunity to study Graphene composites. The IRC group at Bradford has close links with the other members of the Polymer IRC (Universities of Leeds, Durham and Sheffield) and other UK University groups specialising in polymer processing, most notably Queens University, Belfast and Warwick University. It is envisaged that increased interest in Graphene polymer composites will encourage further collaboration between these groups.

Publications

10 25 50
 
Description Through the project it has been discovered that graphene nanoplatelets can successfully be incorporated into a commercial grade of polyproplyene polymer at low levels, to improve the mechanical and thermal properties of the material. The research found that various factors had a significant influence on the final material properties, including graphene platelet size, surface functionalisation and the mixing conditions used to disperse the graphene within the polymer. Melt extrusion, a conventional commercial process, was found to be sucessful in producing a well-dispersed nanocomposite. The original project objectives were to develop a graphene-polypropylene nanocomposite material which would be used to produced porous filtration media. This was completed successfully and a trial was run at the end of the project on the partners production facility.
Exploitation Route The findings may be taken forward further to develop a commercially viable filtration media product incorporating graphene. Further optimisation of the formulation and manufacturing conditions is required to fully achieve this goal.
Sectors Manufacturing, including Industrial Biotechology,Pharmaceuticals and Medical Biotechnology,Transport

 
Description Delstar 
Organisation DelStar Technologies, Inc.
Country United States 
Sector Private 
PI Contribution Delstar Technologies were the lead organisation on the Innovate UK funded project (132264) linked to this EPSRC funding. The University of Bradford was the academic partner, performing the bulk of the research. The project aimed to use graphene nanoplatelets to improve the properties of a polypropylene filtration media. Research was performed at small scale initially to select the type and functionality of graphene, before a method to disperse this within the polymer was developed. Finally an industrial scale batch of nanocomposite material was supplied to Delstar for production trials.
Collaborator Contribution Delstar coordinated the project, ran characterisations and plant trials on the materials and provided in-kind support to the project, in terms of management time, materials, testing and production time.
Impact Several contract research projects resulted form this collaboration (partially in the company's previous form as Smith and Nephew Extruded Films). The company also donated equipment to the University of Bradford Polymer IRC laboratories.
Start Year 2010
 
Description Haydale 
Organisation Haydale
Country United Kingdom 
Sector Private 
PI Contribution University of Bradford were the academic partner of the EPSRC/Innovate UK collaborative project, performing research aimed at developing a graphene-polymer nanocomposite material for applications in filtration media.
Collaborator Contribution Haydale provided surface functionalisation and characterisation of the graphane mateirals supplied by Thomas Swan. They also advised and managed the project.
Impact This collaboration was multidisciplinary, involving polymer engineering and materials science, surface chemistry. No additional outcomes have resulted form the collaboration so far.
Start Year 2014
 
Description Thomas Swan 
Organisation Thomas Swan and Co Ltd
Country United Kingdom 
Sector Private 
PI Contribution The University of Bradford were the academic partner in this EPSRC/Innovate UK collaborative project, performing the research work to develop a new graphene-polymer nanocomposite material.
Collaborator Contribution Manufacture and supply of graphene material to different specifications; advice and project management.
Impact The collaboration is multidisciplinary, involving polymer engineering and nano-materials science. No additional outcome have resulted outside of the main project, although further research is under discussion.
Start Year 2014
 
Description Conference presentation 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other audiences
Results and Impact Research papers were presented at international conferences in the UK and in Germany, to polymer related research conferences (Polymer Processing Society; Polymer Process Engineering). Sessions were attended by between 50 - 100 research professionals and industrialists.
Year(s) Of Engagement Activity 2017