AEGIS (Advanced EnerGy-Absorption polymer for Impact-resistant Smart composites)

Lead Research Organisation: University of Bath
Department Name: Mechanical Engineering

Abstract

The development of a new generation of advanced fibrous composite materials plays a key role in the future evolution of the aerospace sector due to their very high weight-to-strength ratio that can lead to higher operating efficiencies per revenue passenger kilometre. However, while the fibre dominant properties guarantee excellent in-plane load-bearing characteristics, traditional composite materials exhibit weak resistance to out-of-plane loads, making them susceptible to delamination damage under impact loads that can happen during manufacturing or in service. Indeed, while for metallic media, which are homogeneous and can dissipate energy through yielding, a surface dent will only increase strain hardening locally, for composite materials it is associated with the separation of interior plies due to their intrinsic layered structure, and therefore it must be avoided since it can grow uncontrollably compromising the integrity of the entire structure and leading to severe local degradation of the mechanical properties and, in some cases, sudden critical failures. This weak impact resistance together with the complexity of the failure mechanisms typical of composite systems led in the past decade to the definition of the current design philosophy in aeronautical structures as a "no damage growth" approach, leading to overdesigned structures with high thickness and mainly quasi-isotropic layout based on the assumption of the presence of defects from the outset. Based on these premises, it appears clear the need of a comprehensive solution for the aerospace sector that matches the requirements of lightweight structures with the need for high impact resistance. AEGIS is aimed at the development of a novel hybrid composite material with exceptional energy absorption property which is based on the development of a new "smart" "pseudo non-Newtonian" polymer that can be used in traditional manufacturing processes of plate-like components and complex sandwich panels. The exceptional impact resistance of these new structures is caused by a dynamic stiffening effect given by the transient nature of a large number of crosslink bonds present in the new smart polymer, which forces the polymeric chains to dissipate a large quantity of energy in order to disentangle themselves when subjected to an external load. The development of this new polymeric layer will eliminate the issues associated with moisture absorption of traditional liquid media, allowing its efficient and rapid application on laminated structures as a "smart layer" that can be used as a superficial coating with a minimum effect on the final weight of the structure. Furthermore, due to the higher viscosity of the polymer, it will be possible to intercalate it within a scaffold material in order to develop a "smart core", guarantying ease of manufacturing and increasing the stiffness of the frequency-dependant polymer, leading to the development of novel hybrid sandwich structures.
The hybrid composite materials developed in AEGIS will be able to actively respond to specific external stimuli via dynamically enabling the entanglement of the polymeric chains only when the solicitations are above a critical threshold. By combining the exceptional in-plane specific properties of composite materials with the outstanding out-of-plane resistance of the smart polymer, AEGIS will tackle the current limitations of composite components leading to a general increase of the reliability of composite structures that can change the current design approach reducing the safety parameters and optimising the geometries of current components.

Planned Impact

The development of the impact-resistant AEGIS composite laminates will translate to the reduction of the need of over-dimensioning components, shifting manufacturing paradigms towards cheaper processes and reducing production costs and maintenance. The main beneficiaries and the direct customers of AEGIS would be companies operating in the aerospace sector with different stakeholders placed at different positions within the production chain. In particular companies that are directly involved into the manufacturing of composite structures for the aerospace industry such as Airbus would benefit of the access to the technology related to impact-resistant laminates together with suppliers of raw fibrous materials and prepregs. This will be done through directly licensing the intellectual properties that will be developed during the AEGIS project and continued through subsequent co-development projects. The outcome of AEGIS would ignite the possibility to manufacture new innovative impact resistant structures that will allow UK industry to consolidate its competitive advantage in the field of composite structures aligning its objectives with the key areas of High Value Manufacturing and Transport system of the Catapult Programme.
As a secondary objective, by developing innovative smart composites and reducing manufacturing costs, the outcome of AEGIS will help expand composite materials into other new sectors where they have been traditionally hindered by design complexity, production costs and by the catastrophic nature of their failure mechanism. Indeed in order to expand the composite market towards mass-adoption, sectors like biomedical, railways and consumer goods industries need to address large technological (i.e. the intrinsic brittle failure of composite components) and cost-related gaps (i.e. overdesign and expensive manufacturing processes) that can be filled by the solutions proposed by AEGIS. In this, AEGIS will benefit from the support of the Research & Innovation Services of the University of Bath that will facilitate the technology transfer and help developing new relationships with industry and inter-disciplinary research collaborators. Together, these stakeholder not only will maximise the impact generated by AEGIS, expanding the adoption of its outcomes outside the aerospace sector, but they will also create a network of industries and research centres that will be able to foster new collaborations and promote new researches, fuelling R&D activities and attracting inwards investments from UK and EU.
In addition, the support of the SetSquared Business Incubator will facilitate the commercialisation process of the technology developed during the AEGIS project, offering a bespoke business support to help starting a spinout company providing specialisms and expertise in marketing, legal, IP and financial sectors.
In terms of the effect of AEGIS on society, the outcomes of the project will help shed light to the current limitations of composite materials. Improving resistance of composite materials, reducing the risk of catastrophic failures would change the manufacturing approach of composite materials, leading to lighter structures with lower CO2 footprint. This in turn will allow faster transportation systems with higher capacity and lower environmental impact, potentially improving everyday life of millions of people across UK and Europe. In addition, in view of the increase of 25% tariff on steel imports and 10% on aluminium from the US, the new market opportunities (both direct and indirect) generated by the insight on properties of smart composite structures can influence policymakers, defining new strategies in terms of existing regulations and prioritising investments in the advanced materials sector in line with points P2 and P3 of the "Productive Nation" prosperity outcomes included in the EPSRC's delivery plan 2019/20.
 
Description This project investigated the employment of a non-linear polymer as means of protection of composite structures. Newtonian fluids, like water for example, are very predictable; when a force is applied on them their viscosity, their ability to flow, remains the same. Non-Newtonian fluids on the other hand see a change in their viscosity which alters their properties. The material under investigation in this project, belongs to specific category of materials called Shear Stiffening Gels which are materials that can be designed to become stiffer when a load is applied to them. Based on this principle, this project focused on the development and manufacturing of an energy absorbing gel able to respond to an external impact by changing its mechanical properties in order to be employed as a protective layer for composite structures. Indeed, composite materials due to their layered structure, have inherently poor properties through their out-of-plane direction and are susceptible to the generation of Barely Visible Impact Damage which can lead to the catastrophic failure of the component. The shear stiffening gel was successfully chemically and mechanically characterised via various methods, where its ability to absorb energy with an intriguing underlying mechanism in its polymeric network was established and quantified. During the design and synthesis phases of the project an in-depth understanding of the chemical background of the reactions leading to the formulation of these gels has been achieved which consequently led to a greater appreciation of the result data gathered during the experimental phase.
The knowledge obtained was translated into multiple embodiment where protection against dynamic loading conditions is of paramount importance. The material found use firstly as an energy absorption medium in a multi-layered coating (smart layer) which was employed as a superficial layer onto composite structures. The results from these experiments revealed that the proposed solution could offer excellent protection to the substrate, leading to reductions of damage up to 70% compared to an unprotected composite. In a different study, the material was incorporated into polyurethane foams used for core structures (smart cores) into sandwich panels and managed successfully to improve the impact resistance of the structure, modifying its energy dissipation mechanism, and opening the way for a new range of potential applications, such as sports protection equipment. In a final study, the stiffening mechanism of the proposed material was activated on demand, with the addition of iron particles, opening new possibilities for applications as a multifunctional material which can protect a substrate and at the same time provide information on its structural integrity.
Exploitation Route Although it is too early to say, the material can and will potentially find use in the future in those applications in which protection against dynamic loading conditions is demanded.
Its principal use is oriented towards main structures for load-bearing applications and in this context the process can be optimised to specific applications with an industrial processing approach rather than a lab-scaled one.
More importantly, the developed material showed very promising properties that make it a valid solution for personal protective clothing such as body armour for defence applications or safety equipment for sport applications. We have secured some internal funding to proceed with the engagement with manufacturers in the sport industry and policymakers to evaluate this opportunity.
Furthermore, we are currently investigating the possibility to implement additional features such as Structural Health Monitoring and Damage detection for aerospace/automotive applications.
Sectors Aerospace, Defence and Marine,Leisure Activities, including Sports, Recreation and Tourism,Transport

 
Description University of Bath's Impact Fund 2021-22 (Rapid Response)
Amount £1,000 (GBP)
Organisation University of Bath 
Sector Academic/University
Country United Kingdom
Start 12/2021 
End 07/2022
 
Description - Presentation at the NCC for the "National Composite Centre Technology Day - Composites Survivability" Fulvio Pinto - University of Bath - Aegis, Advanced Energy-Absorption Polymer for Impact-Resistant Smart Composites - 22 March 2022 (Contributor Session - Academics, 1:00-2:30pm) 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact The National Composites Centre is facilitating a series of Technology Days as part of the Composites Technology Forum for UK Defence. Each event will focus on a priority technology theme that has been identified and selected from a consultation with industry and the Ministry of Defence.

Each Technology Day will provide a collaborative discussion space between the Forum Steering Board, the UK industrial supply chain and academic communities that is focused around one of the priority technology themes.

The six Technology Days will be held throughout 2022 hosted by the NCC in Bristol (and/or accessible online), each providing an opportunity for participants to present novel materials and manufacturing technology from mid to low TRL around the priority theme. This will not only help direct future research projects but will also open up opportunities for collaboration with other participants.

During each Technology Day, the NCC will also outline any current or planned research relevant to the theme and details of how to participate in future NCC-directed research projects or initiatives. There will be a chance to discuss any 'open' or 'future-planned' public funding routes on this topic combined with an opportunity for the voice of the Ministry of Defence Executive agencies Dstl, AWE and SDA to be heard.
Year(s) Of Engagement Activity 2022
URL https://www.nccuk.com/sectors/defence-space/composites-technology-forum/2022-tech-days/