Deuterium fractionation in ultracold collisions using trapped molecular ions
Lead Research Organisation:
University of Oxford
Department Name: Oxford Chemistry
Abstract
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Organisations
People |
ORCID iD |
Tim Softley (Principal Investigator) |
Publications
Petralia LS
(2020)
Strong inverse kinetic isotope effect observed in ammonia charge exchange reactions.
in Nature communications
Poel A
(2015)
A compact design for a magnetic synchrotron to store beams of hydrogen atoms
in New Journal of Physics
Rennick CJ
(2014)
Magnetic trapping of cold bromine atoms.
in Physical review letters
Schullian O
(2019)
Beyond direct simulation Monte Carlo (DSMC) modelling of collision environments
in Molecular Physics
Schullian O
(2015)
Simulating rotationally inelastic collisions using a direct simulation Monte Carlo method
in Molecular Physics
Steer E
(2015)
Accurate determination of the relative concentrations of ammonia isotopologues in a cold, electrostatically guided molecular beam
in Molecular Physics
Steer E
(2017)
Measurement of the orientation of buffer-gas-cooled, electrostatically-guided ammonia molecules
in Journal of Molecular Spectroscopy
Toscano J
(2019)
Evolutionary Algorithm Optimization of Zeeman Deceleration: Is It Worthwhile for Longer Decelerators?
in The journal of physical chemistry. A
Toscano J
(2020)
Cold and controlled chemical reaction dynamics.
in Physical chemistry chemical physics : PCCP
Toscano J
(2019)
Manipulating hydrogen atoms using permanent magnets: Characterisation of a velocity-filtering guide.
in The Review of scientific instruments
Description | We have developed the apparatus and capabilities to study very low temperature reactions between neutral molecules and ions, including molecules that are selectively deuterated (molecules with one or more deuterium atoms substituted for hydrogen). We have developed techniques to measure the ratio of products of different types from complex reactions and the rates of those processes. A study of the reaction of xenon ions with isotopomers of ammonia revealed a remarkable inverse isotope effect (Nature Communications 2020) We have also developed a device for making cold free radicals (species with an odd number of electrons) - a Zeeman decelerator - for future applications in cold chemical reaction studies. |
Exploitation Route | The development of novel mass spectrometric techniques, ejecting ions from laser cooled ion trap, could be of value in analytical chemistry. |
Sectors | Chemicals |
Description | Public engagement - two animations and a schools pack relating to our low temperature chemistry on the Oxford Sparks website |
First Year Of Impact | 2014 |
Sector | Education |
Impact Types | Societal |
Description | Horizon 2020 Marie Curie ITN COMIQ |
Amount | £240,000 (GBP) |
Funding ID | 607491 |
Organisation | European Union |
Sector | Public |
Country | European Union (EU) |
Start | 11/2013 |
End | 11/2017 |
Description | Wiener Anspach Foundation Research Grant |
Amount | £20,000 (GBP) |
Organisation | Wiener-Anspach Foundation |
Sector | Charity/Non Profit |
Country | Belgium |
Start | 09/2012 |
End | 09/2016 |