Deuterium fractionation in ultracold collisions using trapped molecular ions
Lead Research Organisation:
University of Oxford
Department Name: Oxford Chemistry
Abstract
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Organisations
People |
ORCID iD |
Tim Softley (Principal Investigator) |
Publications
Toscano J
(2018)
A magnetic guide to purify radical beams
in The Journal of Chemical Physics
Tsikritea A
(2021)
Inverse kinetic isotope effects in the charge transfer reactions of ammonia with rare gas ions.
in Chemical science
Twyman KS
(2014)
Production of cold beams of ND3 with variable rotational state distributions by electrostatic extraction of He and Ne buffer-gas-cooled beams.
in The Journal of chemical physics
Description | We have developed the apparatus and capabilities to study very low temperature reactions between neutral molecules and ions, including molecules that are selectively deuterated (molecules with one or more deuterium atoms substituted for hydrogen). We have developed techniques to measure the ratio of products of different types from complex reactions and the rates of those processes. A study of the reaction of xenon ions with isotopomers of ammonia revealed a remarkable inverse isotope effect (Nature Communications 2020) We have also developed a device for making cold free radicals (species with an odd number of electrons) - a Zeeman decelerator - for future applications in cold chemical reaction studies. |
Exploitation Route | The development of novel mass spectrometric techniques, ejecting ions from laser cooled ion trap, could be of value in analytical chemistry. |
Sectors | Chemicals |
Description | Public engagement - two animations and a schools pack relating to our low temperature chemistry on the Oxford Sparks website |
First Year Of Impact | 2014 |
Sector | Education |
Impact Types | Societal |
Description | Horizon 2020 Marie Curie ITN COMIQ |
Amount | £240,000 (GBP) |
Funding ID | 607491 |
Organisation | European Union |
Sector | Public |
Country | European Union (EU) |
Start | 11/2013 |
End | 11/2017 |
Description | Wiener Anspach Foundation Research Grant |
Amount | £20,000 (GBP) |
Organisation | Wiener-Anspach Foundation |
Sector | Charity/Non Profit |
Country | Belgium |
Start | 09/2012 |
End | 09/2016 |