Directed assembly of nanocrystals for tuneable semiconducting polymer composites
Lead Research Organisation:
Imperial College London
Department Name: Chemistry
Abstract
Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.
Organisations
People |
ORCID iD |
Saif Haque (Principal Investigator) | |
Jenny Nelson (Co-Investigator) |
Publications
Al-Shakban M
(2017)
Novel Xanthate Complexes for the Size-Controlled Synthesis of Copper Sulfide Nanorods.
in Inorganic chemistry
Aristidou N
(2017)
Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells.
in Nature communications
Aristidou N
(2017)
Insights into the increased degradation rate of CH 3 NH 3 PbI 3 solar cells in combined water and O 2 environments
in Journal of Materials Chemistry A
Aristidou N
(2015)
The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers.
in Angewandte Chemie (International ed. in English)
Aziz A
(2019)
Understanding the Enhanced Stability of Bromide Substitution in Lead Iodide Perovskites
in Chemistry of Materials
Bear JC
(2015)
Nanoparticle-sulphur "inverse vulcanisation" polymer composites.
in Chemical communications (Cambridge, England)
Boadi N
(2016)
The deposition of PbS and PbSe thin films from lead dichalcogenoimidophosphinates by AACVD
in Inorganica Chimica Acta
Brent JR
(2017)
Precursor determined lateral size control of monolayer MoS2 nanosheets from a series of alkylammonium thiomolybdates: a reversal of trend between growth media.
in Chemical communications (Cambridge, England)
Bryant D
(2016)
Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells
in Energy & Environmental Science
Bryant D
(2016)
Correction: Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells
in Energy & Environmental Science
Ding D
(2018)
Efficient Hybrid Solar Cells Based on Solution Processed Mesoporous TiO 2 /Tin(II) Sulfide Heterojunctions
in ACS Applied Energy Materials
Ezenwa TE
(2018)
Full compositional control of PbSxSe1-x thin films by the use of acylchalcogourato lead(ii) complexes as precursors for AACVD.
in Dalton transactions (Cambridge, England : 2003)
Hu Y
(2015)
Ruthenium Dyes with Azo Ligands: Light Harvesting, Excited-State Properties and Relevance to Dye-Sensitised Solar Cells
in European Journal of Inorganic Chemistry
Kumar N
(2017)
Simultaneous topographical, electrical and optical microscopy of optoelectronic devices at the nanoscale.
in Nanoscale
Lanzetta L
(2020)
Stability of Lead and Tin Halide Perovskites: The Link between Defects and Degradation.
in The journal of physical chemistry letters
Lanzetta L
(2017)
Two-Dimensional Organic Tin Halide Perovskites with Tunable Visible Emission and Their Use in Light-Emitting Devices
in ACS Energy Letters
Lewis E
(2015)
In Situ Synthesis of PbS Nanocrystals in Polymer Thin Films from Lead(II) Xanthate and Dithiocarbamate Complexes: Evidence for Size and Morphology Control
in Chemistry of Materials
Lewis E
(2016)
Diatom Frustules as a Biomineralized Scaffold for the Growth of Molybdenum Disulfide Nanosheets
in Chemistry of Materials
MacLachlan AJ
(2015)
Polymer/Nanocrystal Hybrid Solar Cells: Influence of Molecular Precursor Design on Film Nanomorphology, Charge Generation and Device Performance.
in Advanced functional materials
Manke F
(2015)
Influence of a nearby substrate on the reorganization energy of hole exchange between dye molecules.
in Physical chemistry chemical physics : PCCP
Matthews PD
(2017)
Shining a light on transition metal chalcogenides for sustainable photovoltaics.
in Chemical science
Matthews PD
(2018)
Black phosphorus with near-superhydrophobic properties and long-term stability in aqueous media.
in Chemical communications (Cambridge, England)
McNaughter PD
(2017)
The in situ synthesis of PbS nanocrystals from lead(II) n-octylxanthate within a 1,3-diisopropenylbenzene-bisphenol A dimethacrylate sulfur copolymer.
in Royal Society open science
McNaughter PD
(2016)
The effect of alkyl chain length on the structure of lead(ii) xanthates and their decomposition to PbS in melt reactions.
in Dalton transactions (Cambridge, England : 2003)
Description | Hybrid organic-inorganic nanocomposites are attracting huge interest for range of applications such as solar cells, light emitting diodes and photonics. The ability to control the (i) structural morphology of the hybrid composite and (ii) interface function, are key challenges that have major implications for next generation optoelectronic devices. In this project, we focused on these tasks. Key highlights of this project are: 1) Development of a range of nanocrystal materials with tailored morphology and optical gap. 2) Improving the understanding of the interfacial energetics on electron and hole transfer in organic - inorganic semiconductor films. 3) Improved fundamental understanding of the factors influencing the stability of hybrid organic lead halide perovskite materials and solar cells. In particular, we have reported on the role of light and oxygen on the degradation of methyl ammonium lead triiodide perovskite films and devices. These findings are expected to impact fields beyond solar cells and will also be exploited in different areas, such as new nanomaterial-enabled technologies. |
Exploitation Route | The project team have continued to collaborate and have successfully obtained further EPSRC funding to work on hybrid solar cells and in particular perovskite devices. |
Sectors | Chemicals,Electronics,Energy,Environment |
Description | The finding have been used to publish a number of papers as indicated in this submission. The project team has continued to work together and collaborate and which has led to further EPSRC funding. |
First Year Of Impact | 2014 |
Sector | Energy,Environment |