Application of ionic liquid-liquid chromatography (ILLC) to extractions of metals
Lead Research Organisation:
University College London
Department Name: Chemical Engineering
Abstract
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People |
ORCID iD |
| Panagiota Angeli (Principal Investigator) |
Publications
Tsaoulidis D
(2015)
Effect of channel size on liquid-liquid plug flow in small channels
in AIChE Journal
Wang H
(2022)
Intensified solvent extraction of L-tryptophan in small channels using D2EHPA
in Chemical Engineering and Processing - Process Intensification
Tsaoulidis D
(2021)
Experimental and CFD scale-up studies for intensified actinide/lanthanide separations
in Chemical Engineering and Processing - Process Intensification
Tsaoulidis D
(2015)
Effect of channel size on mass transfer during liquid-liquid plug flow in small scale extractors
in Chemical Engineering Journal
Phakoukaki Y
(2023)
Flow patterns of ionic liquid based aqueous biphasic systems in small channels
in Chemical Engineering Science
Lange V
(2018)
Hydrodynamics studies of the behaviour of traditional and two-phase ionic liquid solvent systems in countercurrent chromatography (CCC)
in Chemical Engineering Science
Tsaoulidis D
(2017)
Liquid-liquid dispersions in intensified impinging-jets cells
in Chemical Engineering Science
Li Q
(2016)
Intensified Eu(III) extraction using ionic liquids in small channels
in Chemical Engineering Science
Angeli P
(2019)
Intensified Liquid-Liquid Extraction Technologies in Small Channels: A Review
in Johnson Matthey Technology Review
| Description | • Design and construction of prototype two-dimensional countercurrent chromatography (2D CCC) instrument that allows visualisation studies. • Details of the phase distribution, settling and mixing characteristics of two-phase mixtures, and phase retention within the coils for different solvent systems and operational conditions. • Ionic liquid based solvent system optimised by QUILL for metal processing exhibited unique and unexpected hydrodynamic behaviour in comparison to traditional biphasic solvent systems also investigated. • The results were used to understand the performance of CCC and to design ionic liquids for separations in different applications (including energy and pharmaceuticals). They also aid the design of scale up systems. |
| Exploitation Route | The results of this work may be useful in the design and operation of certain CCC instrumentation for ionic liquid based extractions in a wide range of applications in addition to metal processing. |
| Sectors | Chemicals,Energy,Manufacturing, including Industrial Biotechology,Pharmaceuticals and Medical Biotechnology |
| URL | https://www.ucl.ac.uk/chemical-engineering/thames-advanced-multiphase-systems |
| Description | In the project we demonstrated that ionic liquids can be used as alternatives to organic solvents for the separation (extraction) of metals in countercurrent chromatography (CCC). We also showed that a new type of CCC that has a two-dimensional column (2D CCC) can result in efficient separations compared to the standard three dimensional CCC (3D CCC). In addition, 2D CCC allows the visual observation of the mixing and settling patterns of the liquids inside the coils of the column. These can help understand the separation performance of the column. Based on these studies we found that ionic liquids form different patterns compared to conventional solvents. These findings have helped identify ionic liquid systems that are suitable for the separation of metals for a wide range of applications (including spent nuclear fuel separations and healthcare. The detailed studies of the hydrodynamics in the column have helped the design of the scale up systems. |
| First Year Of Impact | 2018 |
| Sector | Chemicals,Energy,Manufacturing, including Industrial Biotechology,Pharmaceuticals and Medical Biotechnology |
| Description | Continuous intensified solvent extraction in phrmaceutical processes using hydrophobic water microemulsions from ionic liquids |
| Amount | £85,000 (GBP) |
| Funding ID | EPSRC Voucher code 19000102 |
| Organisation | Johnson Matthey |
| Sector | Private |
| Country | United Kingdom |
| Start | 09/2019 |
| End | 08/2021 |
| Description | Novel intensified liquid-liquid contactors for mass transfer in sustainable energy generation |
| Amount | £195,000 (GBP) |
| Funding ID | EP/P034101/1 |
| Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
| Sector | Public |
| Country | United Kingdom |
| Start | 06/2017 |
| End | 12/2018 |
| Description | PREdictive Modelling with QuantIfication of UncERtainty for MultiphasE Systems (PREMIERE) |
| Amount | £6,560,538 (GBP) |
| Funding ID | EP/T000414/1 |
| Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
| Sector | Public |
| Country | United Kingdom |
| Start | 09/2019 |
| End | 09/2024 |
| Description | UK Japan Civil Nuclear Energy Collaboration Phase 4 |
| Amount | £253,038 (GBP) |
| Funding ID | EP/R019223/1 |
| Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
| Sector | Public |
| Country | United Kingdom |
| Start | 10/2017 |
| End | 03/2020 |
| Description | IProPBio |
| Organisation | Federal University of Paraná |
| Country | Brazil |
| Sector | Academic/University |
| PI Contribution | Expertise on intensified processes and particularly on liquid-liquid reactions and separations. Access to equipment for intensified processes. |
| Collaborator Contribution | Knowledge of thermodynamics, phase equilibrium measurements and thermodynamic modeling. Also process synthesis and optimization for the design of biorefineries |
| Impact | This is an international collaboration with partners from Europe, US and Brazil. The consortium has formed to apply for funding for the design, optimization and operation of sustainable biorefineries for multi product portfolios. |
| Start Year | 2017 |
| Description | IProPBio |
| Organisation | University of Patras |
| Department | Department of Mechanical Engineering and Aeronautics |
| Country | Greece |
| Sector | Academic/University |
| PI Contribution | Expertise on intensified processes and particularly on liquid-liquid reactions and separations. Access to equipment for intensified processes. |
| Collaborator Contribution | Knowledge of thermodynamics, phase equilibrium measurements and thermodynamic modeling. Also process synthesis and optimization for the design of biorefineries |
| Impact | This is an international collaboration with partners from Europe, US and Brazil. The consortium has formed to apply for funding for the design, optimization and operation of sustainable biorefineries for multi product portfolios. |
| Start Year | 2017 |
| Description | IProPBio |
| Organisation | University of Southern Denmark |
| Country | Denmark |
| Sector | Academic/University |
| PI Contribution | Expertise on intensified processes and particularly on liquid-liquid reactions and separations. Access to equipment for intensified processes. |
| Collaborator Contribution | Knowledge of thermodynamics, phase equilibrium measurements and thermodynamic modeling. Also process synthesis and optimization for the design of biorefineries |
| Impact | This is an international collaboration with partners from Europe, US and Brazil. The consortium has formed to apply for funding for the design, optimization and operation of sustainable biorefineries for multi product portfolios. |
| Start Year | 2017 |
| Description | Centre for Nature Inspired Engineering Annual Advisory Board Meeting |
| Form Of Engagement Activity | A talk or presentation |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Professional Practitioners |
| Results and Impact | Poster presentation of research work which sparked questions and discussion. |
| Year(s) Of Engagement Activity | 2018 |
| URL | https://www.natureinspiredengineering.org.uk/news/cnie-annual-advisory-board-meeting-and-conference |
| Description | Chemical Engineering Dept. Industrial Advisory Board Meeting (poster competition) |
| Form Of Engagement Activity | A talk or presentation |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Industry/Business |
| Results and Impact | Presentation of research which sparked questions and discussion. |
| Year(s) Of Engagement Activity | 2017 |
| Description | Mexican Society Engineering Meeting |
| Form Of Engagement Activity | Participation in an activity, workshop or similar |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Public/other audiences |
| Results and Impact | Dissemination of the research work on intensified liquid-liquid processes in front of a wide audience. |
| Year(s) Of Engagement Activity | 2017 |
| Description | Poster competition |
| Form Of Engagement Activity | A talk or presentation |
| Part Of Official Scheme? | No |
| Geographic Reach | Regional |
| Primary Audience | Postgraduate students |
| Results and Impact | Presentation of research work within the UCL. |
| Year(s) Of Engagement Activity | 2017 |
| Description | Website |
| Form Of Engagement Activity | Engagement focused website, blog or social media channel |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Industry/Business |
| Results and Impact | We created a website to expose our research activities on the flow and transport phenomena in complex two-phase systems. |
| Year(s) Of Engagement Activity | 2017 |
| URL | https://www.ucl.ac.uk/multiphase-advances-research/index |