Portable, high magnetic field charging of bulk superconductors for practical engineering applications

Lead Research Organisation: University of Cambridge
Department Name: Engineering

Abstract

Bulk superconductors can be used, when cooled to cryogenic temperatures, as super-strength, stable permanent magnets generating fields of several Tesla, compared to the 1.5-2 Tesla limit for conventional permanent magnets, such as neodymium magnets (Nd-Fe-B). This makes them attractive for a number of engineering applications that rely on high magnetic fields, including compact and energy-efficient motors/generators with unprecedented power densities and compact and portable magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) systems. It is now also possible for scientists to use high magnetic fields to exploit the magnetism of a material for controlling chemical and physical processes, which is attractive for magnetic separation and magnetic drug delivery systems (MDDS), for example. The chief advantage of a bulk superconductor magnet is that the available field can be up to an order of magnitude higher than conventional permanent magnets (bulk high-temperature superconductors have been shown to be capable of trapping magnetic fields greater than 17 Tesla) and no power supply and direct connection is necessary to supply the current producing the magnetic field, as in electromagnets.

The magnetisation process of a bulk superconductor essentially involves the application and removal of a large magnetic field that induces a circulating supercurrent in the material that flows without resistance. However, one significantly challenging problem currently faced is achieving a simple, reliable and portable charging technique to magnetise such superconductors, and this is crucial to producing competitive and compact designs for high-field, trapped flux-type superconducting applications. The current, best-known method for magnetising bulk superconductors practically is the pulsed field magnetisation (PFM) technique, whereby a large magnetic field is applied via a pulse on the order of milliseconds. However, the world record using PFM is only 5.2 Tesla at 29 K, which is much less than the true capability of these materials. The PFM technique has many design considerations: the magnitude and duration of the pulse(s), the number of applied pulses, the type and shape of the magnetising coil/fixture, how the bulk superconductor is cooled, and the temperature(s) at which the pulse(s) are applied. All of these considerations will be analysed through numerical modelling in order to thoroughly optimise the PFM setup in view of a portable, high-field magnet system. Numerical modelling, validated by experimental results, is a particularly important and cost-effective method to interpret experimental results and the physical mechanisms of the material during the magnetisation process. Such modelling tools can also be used to predict and propose new magnetising techniques, which is more difficult to achieve experimentally.

The primary objective of this research programme is to develop portable, high magnetic field charging of bulk superconductors for practical engineering applications, with an end goal of producing portable and commercially-viable high-field magnet systems. This will be underpinned by the tailoring the material processing and properties of bulk superconductors and magnet geometry for high field applications, developing numerical models for complete electromagnetic-thermal-mechanical analysis to avoid potential mechanical fracture when high magnetic fields are involved (> 6-7 Tesla) and carrying out experiments to validate such models, and the development of an optimised PFM technique that takes into account all of the design considerations above. Two types of pulsed charging systems will be developed around solenoid- and split-type magnetising coils, which will be used to achieve trapped fields in excess of 5 Tesla, the current record, at temperatures greater than 40 K and as a proof-of-concept for bespoke designs for specific applications.

Planned Impact

Room-temperature superconductivity was considered in the EPSRC grand challenges survey (2011) as a technology that could lead to tremendous economic and societal benefits in a number of areas, such as energy and healthcare. However, until such room-temperature superconductors are discovered, superconducting technology is strongly underpinned by the need for cryogenics, and UK-wide cryogenic activities contribute an estimated £170 million total direct GVA (gross value added) with around 1,500 people employed across around 120 companies.

The development of a portable, compact and efficient pulse charging system that can readily achieve fields of 5 Tesla or more, with inexpensive, off-the-shelf cryogenic cooling technology, will bring about a step change in applications that currently use permanent magnets, as well as technology enabled by such high fields. An industry advisory board will be formed for the project, who will meet annually during the project to advise on key technological and strategic elements of the project. With their combined knowledge and experience, the board will advise on material selection, cryogenic options, and the magnetic fields required from an applications viewpoint. A portable, high magnetic field system can be directly exploited by a variety of industries and for further academic research: healthcare (portable magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) systems, and magnetic drug delivery systems (MDDS)) and electrical power (compact, energy-efficient electrical machines) are two prime examples. A compact MRI machine that would allow small-scale, targeted scanning, for example, would complement conventional whole-body scanners that are expensive and have a large footprint because of the low-temperature superconducting wire used to wind their coils.

It is now also possible for scientists to use high magnetic fields to exploit the magnetism of a material for controlling chemical and physical processes, which is attractive for magnetic separation and MDDS. With the continued development of conventional superconducting magnets and the achievement of higher magnetic fields, even the chemical and physical processes associated with diamagnetic materials, which make up many of the materials found on earth, are significantly influenced. Portable, high-field magnets based on bulk superconductors are therefore highly attractive for magnetically-oriented growth of organic semiconductors and carbon nanotubes (CNTs). CNTs have recently emerged as one of the most important nanomaterials with the potential to drive the next industrial revolution and the UK is also well-placed at the forefront of this particular field.

The proposed market feasibility studies and the advisory board will enable accelerated diffusion of the technology by identifying the most promising applications, market sizes and the best routes to market. The portable, high magnetic field system developed during the project, aiming at providing magnetic fields > 5 Tesla at temperatures > 40 K, would be used as a proof-of-concept for bespoke designs for these applications in cooperation with an industry partner.

Publications

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Zhao C (2021) Dynamic Characteristics of a YBCO Bulk Above an Electromagnet Guideway in IEEE Transactions on Applied Superconductivity

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Moseley D (2021) Improved pulsed field magnetisation in MgB 2 trapped-field magnets in Superconductor Science and Technology

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Tsui Y (2022) Waveform Control Pulsed Field Magnetization of RE-Ba-Cu-O Bulk Superconducting Rings in IEEE Transactions on Applied Superconductivity

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Ainslie M (2022) Thickness Dependence of Trapped Magnetic Fields in Machined Bulk MgB 2 Superconductors in IEEE Transactions on Applied Superconductivity

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Tsui Y (2022) Trapped Fields >1 T in a Bulk Superconducting Ring by Pulsed Field Magnetization in IEEE Transactions on Applied Superconductivity

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Zhang K (2023) Record field in a 10 mm-period bulk high-temperature superconducting undulator in Superconductor Science and Technology

 
Description A portable, desktop high-field magnet system was built using bulk high-temperature superconductors. The magnet is capable of providing magnet fields up to 3 tesla and is able to be used as a compact and portable desktop magnetic field source for a number of medical and industrial applications, which will be explored further in the future. The details of the magnet system were reported, open access, in the journal Superconductor Science and Technology (https://iopscience.iop.org/article/10.1088/1361-6668/ac74e7/). It uses state-of-the-art cryocooler technology and a low-cost, fast and portable magnetisation system was developed based on pulsed field magnetisation. The magnet system was used to explore difficulties in pulse field-magnetising bulk superconducting rings, and the first comprehensive explanation of this magnetisation process and ways to mitigate the difficulties was reported in Superconductor Science and Technology (https://iopscience.iop.org/article/10.1088/1361-6668/ac9650/). This new understanding and the magnet system were exploited to achieve record high magnetic fields in ring-shaped bulk superconductors, as reported in the IEEE Transactions on Applied Superconductivity (https://ieeexplore.ieee.org/abstract/document/9635676; https://ieeexplore.ieee.org/abstract/document/9738473).
Exploitation Route The magnet system has been demonstrated as a compact and low cost alternative to traditional (wire-wound) superconducting magnets. The technology may be further developed in a number of areas - optimised pulsed field magnetisation techniques for bulk superconductors (in both disc- and ring-forms) and portable high-field magnet systems. With some further developed, the demonstrated magnet system could be exploited commercially.
Sectors Aerospace, Defence and Marine,Agriculture, Food and Drink,Energy,Healthcare,Pharmaceuticals and Medical Biotechnology

 
Title Dataset for 'Pulsed field magnetisation of Y-Ba-Cu-O bulk superconductors fabricated by the infiltration growth technique' 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/310055
 
Title Research data supporting "A new benchmark problem for electromagnetic modelling of superconductors: the high-Tc superconducting dynamo" 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/308877
 
Title Research data supporting "Dynamics of Magnetic Flux Propagation in Bulk, Single Grain Superconducting Rings during Pulsed Field Magnetisation" 
Description A summary of the research data supporting "Dynamics of Magnetic Flux Propagation in Bulk, Single Grain Superconducting Rings during Pulsed Field Magnetisation" The corresponding files contain the supplementary data for the paper DOI: - Modelling_Data.xlsx - Experimental_Data.xlsx - Fig17_Bz_J-Q-T-export-15-17-19ms.txt - Fig17-J-Q-higherdensity-export-15-17-19ms.txt - Fig17-J-Q-export-17p5ms.txt Detailed information about each file can be found in the READ_ME.txt file. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/341253
 
Title Research data supporting "Mitigating ab-plane Critical Current Density Inhomogeneity in Bulk HTS Rings for the Generation of NMR-Grade Magnetic Fields" 
Description Research data supporting [Mitigating ab-plane Critical Current Density Inhomogeneity in Bulk HTS Rings for the Generation of NMR-Grade Magnetic Fields]. Please see ReadMe file for more details about the data 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/334762
 
Title Research data supporting "Modeling stator versus magnet width effects in high-Tc superconducting dynamos" 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/306615
 
Title Research data supporting "Modeling the charging process of a coil by an HTS dynamo-type flux pump" 
Description Research data supporting [Modeling the charging process of a coil by an HTS dynamo-type flux pump]. The data were obtained from numerical models using the MEMEP method programmed in C++ and the segregated H-formulation built in COMSOL Multiphysics 5.4 - see the main manuscript for more details. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
Impact None 
URL https://www.repository.cam.ac.uk/handle/1810/324379
 
Title Research data supporting "Modelling and mitigating flux jumps in bulk high-temperature superconductors during quasi-static, high-field magnetisation" 
Description Research data supporting "Modelling and mitigating flux jumps in bulk high-temperature superconductors during quasi-static, high-field magnetisation." The dataset related to this publication ("Modelling Mitigating Flux Jumps Dataset 27-9-22.xlsx") can be opened in Microsoft Excel. Sheet 1: FCM 77K - Fig 3 Data from figure 3 of the manuscript, showing the trapped magnetic flux density (numerical and experimental), with radius of the bulk, measured from the top surface of the top-bulk. Numerical data generated by COMSOL Multiphyics; experimental data from reference [21] - see main manuscript. Sheet 2: FCM 23K to 40K - Fig 4 Data from figure 4 of the manuscript, describing the numerical and experimental FCM data (i.e. trapped magnetic flux density, and temperature) with time, for the series of magnetisations between 23 K and 40 K with (peak) applied fields of 15 T to 18 T. Numerical data generated by COMSOL Multiphyics; experimental data from reference [21] - see main manuscript. Sheet 3: Flux Jump from '22T-23K' model data Data from figure 5, describing the FC magnetisation of the bulk-pair, during which the flux jump occurs (and was successfully and accurately modelled). The magnetic flux density and temperature (calculated at H.P. 1/2 and T.P. 1/2) are shown, compared to the experimentally obtained data. Numerical data generated by COMSOL Multiphyics; experimental data from reference [21] - see main manuscript. Sheet 4: Extension Study: Ac Data from figures 10, 11 and 12 is given here, describing the numerical data generated from the extension study investigating the effect of varying the factor of Ac (which is loosely the cooling power of the bulk-pair, see main manuscript, section 5.1, for more information). The time dependence of the flux jump, and resulting trapped magnetic flux density on the value of Ac is given. Numerical data generated by COMSOL Multiphyics - see main manuscript. Sheet 5: Extension Study: L Data from figure 14 is given here, describing the numerical data generated from the extension study investigating a proposed composite bulk-pair consisting of a stack of (Y)-BaCuO bulks interspaced by thin copper layers (see main manuscript, section 5.2, for more information). The time dependence of the flux jump, and resulting trapped magnetic flux density on the value of layer number (L) is given. Numerical data generated by COMSOL Multiphyics - see main manuscript. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://kcl.figshare.com/articles/dataset/Research_data_supporting_Modelling_and_mitigating_flux_jum...
 
Title Research data supporting "Modelling higher trapped fields by pulsed field magnetisation of composite bulk MgB2 superconducting rings" 
Description Research data supporting [Modelling higher trapped fields by pulsed field magnetisation of composite bulk MgB2 superconducting rings]. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
Impact N/A 
URL https://www.repository.cam.ac.uk/handle/1810/328333
 
Title Research data supporting "Modelling the Frequency Dependence of the Open-Circuit Voltage of a High-Tc Superconducting Dynamo" 
Description Research data supporting [Modelling the Frequency Dependence of the Open-Circuit Voltage of a High-Tc Superconducting Dynamo]. The data were obtained from numerical models built in COMSOL Multiphysics 5.4 - see the main manuscript for more details. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/317335
 
Title Research data supporting "Origin of the DC output voltage from a high-Tc superconducting dynamo" 
Description Research data supporting [Origin of the DC output voltage from a high-Tc superconducting dynamo]. Please see the README file for a description of the dataset. 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
Impact None 
URL https://www.repository.cam.ac.uk/handle/1810/292287
 
Title Research data supporting "Portable, desktop high-field magnet systems using bulk, single-grain RE-Ba-Cu-O high-temperature superconductors" 
Description Research data supporting [Portable, desktop high-field magnet systems using bulk, single-grain RE-Ba-Cu-O high-temperature superconductors]. The Microsoft Excel file contains all data plotted in figures 1 to 8 except figure 2 in the main manuscript. Figure 2 is the schematic diagram of the experimental rigs. For all pulsed field magnetization data, the sample was first cooled down from the normal state to the superconducting state then a single pulsed field or a sequence of two pulsed fields (two-step multi-pulse) were applied to it. The values of trapped field shown in the data file are the values recorded at 15 seconds after applying each pulsed field. After reaching the set temperature the wait time before applying a magnetizing pulse was from was from ~5 min (at 77 K) to ~15 min (at 55 K) to allow sufficient time for the sample and the sample holder to reach the thermal equilibrium. Unless stated otherwise, the applied field and the trapped field were the peak value of the magnetizing pulse and the trapped field at the centre of the top surface of each sample, respectively. For the field cooling data, the sample was cooled from room temperature to 77 K, in an applied field of 1.5 T from a copper electromagnet, using a liquid nitrogen bath. The applied field was then removed and the trapped field profiles at 1.5 mm above the top surfaces of the sample were measured. A hand-held gaussmeter was also used to find the maximum trapped field on the surface of each sample. See the main manuscript for more details. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/337660
 
Title Research data supporting "Thickness Dependence of Trapped Magnetic Fields in Machined Bulk MgB2 Superconductors" 
Description A summary of the research data supporting "Thickness Dependence of Trapped Magnetic Fields in Machined Bulk MgB2 Superconductors" (https://doi.org/10.1109/TASC.2022.3147140). The dataset related to this publication ("MgB2 bulk thickness data_MA_26-1-2022.xlsx") can be opened in Microsoft Excel and is available at https://doi.org/10.17863/CAM.74840 Sheet 1: Jc(B) @ 20 K The assumed Jc(B, 20 K) characteristics for the numerical models, shown in Fig. 2 of the manuscript, based on experimental data for small specimens taken from one of the unmachined bulks (‘pre-machining Jc’ = Jc,pre) and from the final machined bulk (‘post-machining Jc’ = Jc,post). Jc of the small specimens â€" cut from the centre of the bulks with typical dimensions of 1 Ã- 1 Ã- 0.5 mm^3 â€" was calculated from the width of the magnetization hysteresis loops measured using a SQUID magnetometer (Quantum Design: MPMS-XL5s). This calculation is based on the extended Bean model (see main manuscript). The data is input into the model using a direct interpolation. Sheet 2: Trapped Field Data The trapped field data presented in Figs. 3 and 5 of the manuscript for T = 20 K. Also included are the trapped field data for T = 5, 10 and 15 K (not presented in the manuscript). The experimental data were measured using transversal cryogenic Hall sensors (HGCT-3020, Lake Shore) at the centre of both surfaces (machined and unmachined). The modelling data were obtained from COMSOL Multiphysics (see manuscript for details) and given for t = 0 and t = +10 min (to allow for flux creep, as presented in Figs. 3 and 5) for the three Jc assumptions: Jc,post, Jc,pre and Jc,mod (see equation (3) in the manuscript). Sheet 3: Analytical Results These data were derived from the analytical equation, given by equation (2) in the manuscript, based on Bean's critical state model and application of the Biot-Savart law. The equation calculates the magnetic flux density at any height, z, above a superconducting disc of radius, a, carrying an induced, persistent supercurrent of constant critical current density, Jc, taking into account the finite thickness of the bulk, t. The data are calculated from the trapped field for the unprocessed / unmachined bulk of thickness 20.243 mm at T = 20 K, for z = 0 (the centre of the top surface of the bulk) and z = +0.5 mm (slightly above the top surface, taking into account the active region of the Hall sensor; presented in Fig. 3). 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/333112
 
Title Research data supporting "Trapped Fields > 1 T in a Bulk Superconducting Ring by Pulsed Field Magnetization" 
Description Research data supporting [Trapped Fields > 1 T in a Bulk Superconducting Ring by Pulsed Field Magnetization]. The Microsoft Excel file contains all data plotted in figures 1 to 5 in the main manuscript. For all pulsed field magnetization data, the sample was first cooled down from the normal state to the superconducting state then a pulsed field or a sequence of pulsed field was applied to it. The values of trapped field shown in the data file are the values recorded at 15 seconds after applying each pulsed field. For a multi-pulse, stepwise cooling sequence, the wait time between two successive pulses was from ~5 min (at 77 K) to ~15 min (at 55 K) to allow sufficient time for the sample to return to its operating temperature before applying the next pulse. Unless stated otherwise, the applied field and the trapped field were the peak value of the magnetizing pulse and the trapped field at the centre of the sample bore, respectively. See the main manuscript for more details. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/335834
 
Title Research data supporting "Validation of a desktop-type magnet providing a quasi-microgravity space in a room-temperature bore of a high-gradient trapped field magnet (HG-TFM)" 
Description A summary of the research data supporting "Validation of a desktop-type magnet providing a quasi-microgravity space in a room-temperature bore of a high-gradient trapped field magnet (HG-TFM)". Please see ReadMe file for details of the dataset 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/334764
 
Title Research data supporting "Waveform Control Pulsed Field Magnetization of RE-Ba-Cu-O Bulk Superconducting Rings" 
Description Research data supporting [Waveform Control Pulsed Field Magnetization of RE-Ba-Cu-O Bulk Superconducting Rings]. The Microsoft Excel file contains all data plotted in figures 2 to 7 in the main manuscript. For the pulsed field magnetization data, the sample was first cooled down from the normal state to the superconducting state then a pulsed field was applied to it. The values of trapped field shown in the data file are the values recorded at 15 seconds after applying each pulsed field. For the field cooling data, the sample was cooled from room temperature to 77 K, in an applied field of 1.5 T from a copper electromagnet, using a liquid nitrogen bath. The applied field was then removed and the trapped field profiles at 1.5 mm above the top and bottom surfaces of the sample were measured. See the main manuscript for more details. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/336979
 
Title Research data supporting [Lorentz Force Velocimetry using a bulk HTS magnet system: proof-of-concept] 
Description Research data supporting [Lorentz Force Velocimetry using a bulk HTS magnet system: proof-of-concept] 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
Impact None 
URL https://www.repository.cam.ac.uk/handle/1810/276443
 
Title Research data supporting [Numerical modelling of dynamic resistance in high-temperature superconducting coated-conductor wires] 
Description Research data supporting [Numerical modelling of dynamic resistance in high-temperature superconducting coated-conductor wires] 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
Impact None 
URL https://www.repository.cam.ac.uk/handle/1810/275354
 
Title Research data supporting [Towards Optimisation of Multi-Pulse, Pulsed Field Magnetisation of Bulk High-Temperature Superconductors] 
Description Research data supporting [Towards Optimisation of Multi-Pulse, Pulsed Field Magnetisation of Bulk High-Temperature Superconductors] 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
Impact None 
URL https://www.repository.cam.ac.uk/handle/1810/273578
 
Description Over-critical currents in a superconducting dynamo (Robinson Research Institute (RRI), NZ; University of Cambridge, UK) 
Organisation Victoria University of Wellington
Country New Zealand 
Sector Academic/University 
PI Contribution I lead the development of the finite-element modelling of the electromagnetic characteristics of the dynamo.
Collaborator Contribution Dr Chris Bumby (RRI) manages the overall project and co-supervises the PhD student. Bumby takes primary responsibility for analysing and interpreting the experimental data, in order to test the 'circulating-currents' hypothesis which he originally conceived. Dr Rod Badcock leads the experimental implementation of the dynamos and data-acquisition systems that underpin our experimental programme. A PhD student, Ratu Mataira, works in a cross-disciplinary manner on both computational modelling and experimental measurements.
Impact None yet (award only recently started).
Start Year 2018