Reactive Metal Jet Fusion Printing

Lead Research Organisation: University of Liverpool
Department Name: Mech, Materials & Aerospace Engineering

Abstract

This research will develop a new way of rapidly making high-quality metal parts by Additive Manufacturing, often referred to as 3D printing. This work, if successful, will lead to faster, cheaper and more environmentally-friendly production of functional parts to be used in the UK's leading industries. It will help maintain the competitive advantage of manufacturing industries in the UK and result in enhanced industrial output and lead to improved exports. The UK academic community will gain by opening up new research opportunities to chemists, materials scientists and engineers in universities. The public will gain through the manufacture of new products and job-creation in key industrial sectors in the UK.

Planned Impact

This proposal has been designed with impact at the core, focused on a technological leap in metal binder jet printing. The proposed research will take binder jet printing far beyond the state-of-the-art and is expected to create significant benefits for UK industry. The project will impact on a range of industrial sectors including: inkjet printing and processing equipment, ink and precursor formulation, powder manufacturers, and a range of end-users such as the automotive, aerospace, medical and other industries that utilise additive manufacturing (AM).

The worldwide market for all additive manufacturing products and services was estimated to be worth $4.1 billion in 2014. The AM sector has experienced a compound annual global growth rate of 35 % over the last three years. Direct part production now represents 43 % of the total global AM revenue. The global market for AM products and services has been forecast to reach £70 billion by 2025; the UK has been predicted to win about 5 % of this rapidly growing market. The UK's predicted AM market will have a strong effect on UK employment (estimated to be 63,000 by 2020). Future growth of the UK's AM market has been forecast to be about $21 billion by 2020; this will be driven by the adoption of AM by the aerospace, medical devices, automotive and creative industries. Over the last three decades, the UK has played a leading role in the development of AM technologies. AM has become a core technology within the field of high value manufacturing. Metals are the fastest-growing segment of the AM sector, with metal printer sales growing at 48 % and feed stock material sales increasing by 32 %. There are a large number of industries that will benefit from the proposed Reactive Metal Jet Fusion printing process. For example, the automotive industry, which has not yet adopted metal AM methods for production of functional parts due to issues with production rates and part-quality. However, the Reactive Metal Jet Fusion printing process will be able to deliver new products to market quickly and predictably, significantly reducing overall vehicle development costs. The aerospace industry, which already uses AM, will be able to better realise highly complex and high performance parts with integrated mechanical function, reduce the number of assembly features and enable the creation of internal functionality. The medical sector, which also uses AM, using the Reactive Metal Jet Fusion printing process, will be able to better translate 3D medical imaging data into customised solid medical devices, implants and prostheses.

There will be economic benefits by keeping these key UK industries at the forefront of global developments. There will spin-off societal benefits in terms of both increased employment opportunities in these industries. If the technique that we are proposing replaces conventional (e.g. subtractive) manufacturing methods for metal manufacturing it would be less materials intensive and therefore will have environmental benefits.

Publications

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Description A novel way of producing metallic components with low shrinkage and high densities have been developed. This manufacturing process could be used to manufacture components in the automotive, aerospace and medical industry.
Exploitation Route Deevelopment of a new printing process which could be used to manufacture new components in a wide variety of sectors, such as automotive and aerospace.
Sectors Aerospace, Defence and Marine,Energy,Manufacturing, including Industrial Biotechology,Security and Diplomacy

 
Description The findings of the research have been the basis of founding a spin-out company called Meta Additive-Ltd that started trading in October 2019 and has since been acquired by the American company Desktop Metal in September 2021
Sector Manufacturing, including Industrial Biotechology
Impact Types Societal,Economic

 
Title ADDITIVE MANUFACTURING COMPONENTS AND METHODS 
Description A method of 3D printing a metal or alloy product comprises: providing a layer of a powder bed which comprises a compound of a first metal, and optionally also said first metal in elemental form and/or optionally other elemental metal(s) which are suitable for alloying with said first metal; jetting a functional binder onto selected parts of said layer, wherein said functional binder infiltrates into pores in the powder bed, reacts with said compound of a first metal to form said first metal in elemental form, and locally fuses elemental metal particles of the powder bed in situ, sequentially repeating said steps of applying a layer of powder on top and selectively jetting functional binder, multiple times, to provide a powder bed bonded at selected locations by printed functional binder and; taking the resultant bound 3D structure out of the powder bed. The method may use a reactive component in the powder bed and a reactive component in the binder. Products which may be made include titanium products, titanium alloy products, aluminium products and aluminium alloy products, amongst others. 
IP Reference WO2021219996 
Protection Patent application published
Year Protection Granted 2021
Licensed Yes
Impact This patent application formed the basis of the spin out company Meta additive and has since been acquired by Desktop metal in September 2021
 
Title ADDITIVE MANUFACTURING COMPONENTS AND METHODS 
Description A method of 3D printing comprises: providing a layer of a powder bed; jetting a functional binder onto selected parts of said layer, wherein said binder infiltrates into pores in the powder bed and locally fuses particles of the powder bed in situ; sequentially repeating said steps of applying a layer of powder on top and selectively jetting functional binder, multiple times, to provide a powder bed bonded at selected locations by printed functional binder; and taking the resultant bound 3D structure out of the powder bed. 
IP Reference WO2019025801 
Protection Patent application published
Year Protection Granted 2019
Licensed No
Impact This patent application is the first of a series of IP which we are sorting to protect with the intention of creating either a spin-out company or the ability to license to an industrial partner.
 
Title ADDITIVE MANUFACTURING COMPONENTS AND METHODS 
Description A method of 3D printing in which a 3D product is built up layer by layer by jetting from print heads, comprises: forming part of a 3D product by a functional binder jetting process; jetting one or more material in a 2D pattern to form a structure on said part; completing the formation of the 3D product by continuing the functional binder jetting process, so that said structure becomes embedded in said product. Said functional binder jetting may comprise the steps of: providing a layer of a powder bed; jetting a functional binder onto selected parts of said layer, wherein said functional binder infiltrates into pores in the powder bed and locally fuses particles of the powder bed in situ; sequentially repeating said steps of applying a layer of powder on top and selectively jetting functional binder, multiple times, to provide a powder bed bonded at selected locations by printed functional binder. The invention allows the embedding of functional structures such as strain gauges, sensors, actuators, security features, electronic features or smart functionality. 
IP Reference WO2021219995 
Protection Patent application published
Year Protection Granted 2021
Licensed Yes
Impact This patent formed the basis of the spin out company Meta Additive which was acquired by Desktop Metal in September 2021
 
Company Name META ADDITIVE LIMITED 
Description Meta Additive is based in Stoke-on-Trent and the University of Liverpool and provide novel binders and printers for the bespoke manufacture of metal and ceramic components. Meta's technology enables tailored material, with bespoke functional properties for the automotive, aerospace and energy sectors. 
Year Established 2019 
Impact Meta Additive is bringing bespoke printed parts that allow for mass manufacture, tailored materials and multimaterial components with embedded functionality.
Website http://meta-additive.com