Preventing Surface Degradation in Demanding Environments

Lead Research Organisation: University of Manchester
Department Name: Materials

Abstract

Surface degradation processes, such as corrosion and wear have very significant societal, economic and safety implications. These degradation processes impact a large number of industrial sectors including, transport (marine & automotive), aerospace, nuclear, oil and gas and their respective supply chains. Corrosion alone costs industry globally $2 trillion each year, of which £55 billion per annum is the cost to the UK and $1.37 billion per year the cost to the global Oil & Gas sector. The resulting cost of wear to the UK economy is estimated at £24 billion per annum, approximately 1.6% of the country's GDP. This programme seeks to tackle this age old problem through harnessing advances in computer modelling, experimental techniques at the atomic level, in operando imaging and characterisation and accessing previously untapped in-field data sets to obtain fresh insights into materials surface degradation under the demanding environments in which they operate.

BP invest heavily in research development and innovation and have developed a long term, successful collaboration with the University of Manchester (UoM). In 2012, BP founded the BP International Centre for Advanced Materials (BP-ICAM) a $100m, 10 year investment to address challenges across BP's core business.
Following a 'Materials Technology Outlook' workshop hosted by BP, surface degradation was identified as a high priority area for future research with the potential for transformational change. The workshop felt there was an opportunity to replace industrial empiricism with mechanistically driven approaches by exploiting advances in-operando techniques and multiscale modelling to ask fundamental research questions about the nucleation and growth of corrosion scales and tribofilms and how to control them through inhibitors, lubricants and surface coatings and treatments.

This Prosperity Partnership will enable us to complement the applied research undertaken within BP-ICAM asking more fundamental research questions about surface degradation than BP-ICAM could tackle. Further this challenge requires additional skills beyond those provided by the ICAM partners and so will benefit from key expertise in the behaviour of materials in high pressure environments and tribocorrosion from the Universities of Edinburgh and Leeds respectively.

The preventing surface degradation in demanding environments team will look at how both corrosion scales and tribofilms initiate, grow, and breakdown through a multiscale appreciation identify ways to inhibit or prevent degradation under very demanding environments. This project will consider both the chemical and mechanical effects of surface degradation by understanding the key interaction between the material surface and near surface (10-100nm) fluid environment. It integrates advanced surface analysis studies of realistic conditions in oil and gas operations to gain a better understanding of degradation issues. It is timely as recent advances in the power of computational modelling and imaging enable researchers to look across length and time scales and observe dynamic systems and 'real world' conditions. Finally the basic understanding developed in the laboratory will be held up against big in-field data sets from BP to inform and challenge the research.

Through these fundamental insights into the mechanisms underlying surface degradation, this programme will; develop reliable predictive multi-scale models of surface degradation; present new materials systems for protection against, and prevention of, corrosion and wear; create new standardised tests for industry to use in the evaluation of degradation and propose new mitigation strategies to extend operational lifetimes.

Planned Impact

This Prosperity Partnership will have a significant societal and economic impact through; increasing operation efficiency; the development of new products and processes across multiple sectors ranging from transport (e.g. marine and automotive) to electricity, nuclear, construction and aerospace, and enabling the UK to consolidate its position as a world leader in surface degradation and materials science and engineering.

BP actively promotes the dissemination of knowledge gained from its research projects. Researchers are actively encouraged to publish in high impact journals and present research at conferences. In addition to journal articles, members of this partnership will be encouraged to present their findings at internationally renowned conferences such as NACE, EuroCorr, OTC, STLE and World Tribology Congress.

The BP-ICAM hosts a three day annual conference in Manchester for researchers and BP staff. Members of this collaboration would be invited to this conference to enable networking, knowledge sharing and research planning.

The papers and conferences mentioned above, will be shared via BP's contacts into different sectors especially though its supply chain and through influencing International standards. BP-ICAM also has a dedicated Marketing and Communication Manager, whose expertise will be utilised by the Prosperity Partnership collaboration to ensure that research output is promoted through the a variety of channels.

The collaborative nature of this programme will enhance the skills of all researchers and industry bodies involved. This programme aims to train the next generation of engineers, giving them a unique opportunity to work simultaneously with industry and academia to address the high priority industry relevant challenges. This collaboration will also enable industry placements within BP, with the aim of at least one researcher working at BP per annum.
Beyond this programme BP will assist researchers to develop their work further, either in house with BP experts or through introductions to supply chain partners or through supporting further research council funded research. Additionally, BP has an active Venturing Business and Technology Commercialisation Team both of which will be utilised to identify and support licensing and commercialisation opportunities through a range of mechanisms including, spin out companies, licencing and collaborations with both large and SMEs.

To widen the impact we will hold a cross-sectorial workshops to engage the wider community and to ensure the current research aligns with industry needs. Attendees will include the oil and gas sector, industry leaders, corrosions scientists and supply chain representatives. Importantly, representatives from other industrial sectors such as aerospace, nuclear, transport, marine and energy will also be invited, to ensure the wider dissemination. In this way we will look at pathways by which the basic knowledge generated here can be transferred into other sectors, either though focused university research or industry funded follow-up projects.

Finally, this collaboration will enhance interaction with the Sir Henry Royce Institute at UoM which involves a number of the partners in this programme. This will allow access to state of the art equipment and expertise, in an innovative space shared by both industry and academia.

Publications

10 25 50
 
Description Despite their huge financial and operational impact to industry, the fundamental mechanisms that affect the build-up and breakdown of friction, wear and corrosion films are not well understood. We are exploiting state-of-the-art experimental techniques, such as in situ X-ray imaging/spectroscopy and in situ analytical TEM characterisation, to quantify the physical and chemical interactions that take place under extreme operating conditions at fluid-film-substrate interfaces for the first time. This is shedding new light on the nucleation, growth and critically the breakdown of corrosion scales and tribofilms at the micro- and nano-scales.

This, allied with detailed and validated multiscale computational modelling, is helping to build a picture of how the chemistries in the fluidic media interact with the nearby surfaces, and thereby generating the insights needed to develop the next generation of corrosion inhibitors, lubricant additives and material technology, that will meet operational and safety requirements, whilst offering cost and environmental benefits and energy efficiency.
Exploitation Route This project is 50% funded by BP and they meet regularly with us to look at how to take up the outcomes from this project, for example, the most cost efficient use of inhibitors to stop corrosion, . In addition, the results of our work on lubricants are being fed into bp Castrol activities and will help to generate more optimized engine oils for hybrid vehicles.

We are holding a project review meeting later in the year to identify areas of innovation and market opportunities.
Sectors Aerospace, Defence and Marine,Energy,Manufacturing, including Industrial Biotechology

 
Description Preventing Surface Degradation in Demanding Environments Our results on the action of inhibitors are contributing to the development of improved inhibitor use in the oil and gas industry. In addition, our work on lubricants are being fed into bp Castrol activities and will help to generate more optimized engine oils for hybrid vehicles. Covid did mean that PhD students became delayed but BP ICAM and the Universities have accommodated this by extending the studies.
First Year Of Impact 2020
Sector Energy
Impact Types Economic

 
Description EPSRC Doctoral Training Partnership Studentship in partnership with AC2T
Amount £85,000 (GBP)
Organisation AC2T Research 
Sector Private
Country Austria
Start 10/2021 
End 04/2025
 
Description Manufacturing the Future with Supercritical CO2 and Minimum Quantity Lubrication
Amount £758,000 (GBP)
Funding ID EP/W001950/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 04/2022 
End 03/2025
 
Description TRibology as an ENabling Technology (TRENT)
Amount £1,538,131 (GBP)
Funding ID EP/S030476/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 09/2019 
End 09/2023
 
Description The effectiveness of esters in cooling and lubricating transmission systems in electric vehicles - dielectric fluids
Amount £85,000 (GBP)
Organisation Croda Europe Ltd 
Sector Private
Country United Kingdom
Start 01/2021 
End 12/2024
 
Description Collaboration with Dr Etienne Bousser 
Organisation École Polytechnique de Montréal
Country Canada 
Sector Academic/University 
PI Contribution Use of facilities and knowledge
Collaborator Contribution Investigating the microstructural and mechanical characterisation of Plasma Electrolytic Oxidation (PEO) of aluminium alloys and Physical Vapour Deposited thin films. Also the characterisation of fracture and residual stress of hard protective coatings.
Impact A number of papers are in preparation
Start Year 2018
 
Description ICAM56 
Organisation BP (British Petroleum)
Country United Kingdom 
Sector Private 
PI Contribution Manchester - expertise of Prof Withers, Matthews, Burke, Akid, Drs Connolly, Lindsay, Muryn and Race; access to the infrastructure, training and administrative support of BP-ICAM hub, access to the infrastructure, training and facilities of Henry Royce Institute; access to the training and support network of the Materials for Demanding Environment CDT.
Collaborator Contribution Leeds - expertise of Profs Neville, Morina and Dr Barker; access to the outstanding research and training environment at Institute of Functional Surfaces; access to skills and facilities in the Bragg Centre for Advanced Functional Materials within the Integrated Centre for Engineering and Physical Sciences. Imperial - expertise of Professor Harrison, Ryan and Dr Campbell; access to the Molecular Sciences Research Hub. Cambridge - expertise of Dr Clarke; upgrades to the state of the art equipment internally and at ISIS. BP - expertise of 5 BP senior technology leadership; access to marketing, communication and event management; access to BP's High Performance Computing facilities and support for 6 PhD studentships.
Impact None yet
Start Year 2017
 
Description ICAM56 
Organisation Imperial College London
Country United Kingdom 
Sector Academic/University 
PI Contribution Manchester - expertise of Prof Withers, Matthews, Burke, Akid, Drs Connolly, Lindsay, Muryn and Race; access to the infrastructure, training and administrative support of BP-ICAM hub, access to the infrastructure, training and facilities of Henry Royce Institute; access to the training and support network of the Materials for Demanding Environment CDT.
Collaborator Contribution Leeds - expertise of Profs Neville, Morina and Dr Barker; access to the outstanding research and training environment at Institute of Functional Surfaces; access to skills and facilities in the Bragg Centre for Advanced Functional Materials within the Integrated Centre for Engineering and Physical Sciences. Imperial - expertise of Professor Harrison, Ryan and Dr Campbell; access to the Molecular Sciences Research Hub. Cambridge - expertise of Dr Clarke; upgrades to the state of the art equipment internally and at ISIS. BP - expertise of 5 BP senior technology leadership; access to marketing, communication and event management; access to BP's High Performance Computing facilities and support for 6 PhD studentships.
Impact None yet
Start Year 2017
 
Description ICAM56 
Organisation University of Cambridge
Country United Kingdom 
Sector Academic/University 
PI Contribution Manchester - expertise of Prof Withers, Matthews, Burke, Akid, Drs Connolly, Lindsay, Muryn and Race; access to the infrastructure, training and administrative support of BP-ICAM hub, access to the infrastructure, training and facilities of Henry Royce Institute; access to the training and support network of the Materials for Demanding Environment CDT.
Collaborator Contribution Leeds - expertise of Profs Neville, Morina and Dr Barker; access to the outstanding research and training environment at Institute of Functional Surfaces; access to skills and facilities in the Bragg Centre for Advanced Functional Materials within the Integrated Centre for Engineering and Physical Sciences. Imperial - expertise of Professor Harrison, Ryan and Dr Campbell; access to the Molecular Sciences Research Hub. Cambridge - expertise of Dr Clarke; upgrades to the state of the art equipment internally and at ISIS. BP - expertise of 5 BP senior technology leadership; access to marketing, communication and event management; access to BP's High Performance Computing facilities and support for 6 PhD studentships.
Impact None yet
Start Year 2017
 
Description ICAM56 
Organisation University of Edinburgh
Country United Kingdom 
Sector Academic/University 
PI Contribution Manchester - expertise of Prof Withers, Matthews, Burke, Akid, Drs Connolly, Lindsay, Muryn and Race; access to the infrastructure, training and administrative support of BP-ICAM hub, access to the infrastructure, training and facilities of Henry Royce Institute; access to the training and support network of the Materials for Demanding Environment CDT.
Collaborator Contribution Leeds - expertise of Profs Neville, Morina and Dr Barker; access to the outstanding research and training environment at Institute of Functional Surfaces; access to skills and facilities in the Bragg Centre for Advanced Functional Materials within the Integrated Centre for Engineering and Physical Sciences. Imperial - expertise of Professor Harrison, Ryan and Dr Campbell; access to the Molecular Sciences Research Hub. Cambridge - expertise of Dr Clarke; upgrades to the state of the art equipment internally and at ISIS. BP - expertise of 5 BP senior technology leadership; access to marketing, communication and event management; access to BP's High Performance Computing facilities and support for 6 PhD studentships.
Impact None yet
Start Year 2017
 
Description ICAM56 
Organisation University of Leeds
Country United Kingdom 
Sector Academic/University 
PI Contribution Manchester - expertise of Prof Withers, Matthews, Burke, Akid, Drs Connolly, Lindsay, Muryn and Race; access to the infrastructure, training and administrative support of BP-ICAM hub, access to the infrastructure, training and facilities of Henry Royce Institute; access to the training and support network of the Materials for Demanding Environment CDT.
Collaborator Contribution Leeds - expertise of Profs Neville, Morina and Dr Barker; access to the outstanding research and training environment at Institute of Functional Surfaces; access to skills and facilities in the Bragg Centre for Advanced Functional Materials within the Integrated Centre for Engineering and Physical Sciences. Imperial - expertise of Professor Harrison, Ryan and Dr Campbell; access to the Molecular Sciences Research Hub. Cambridge - expertise of Dr Clarke; upgrades to the state of the art equipment internally and at ISIS. BP - expertise of 5 BP senior technology leadership; access to marketing, communication and event management; access to BP's High Performance Computing facilities and support for 6 PhD studentships.
Impact None yet
Start Year 2017
 
Description ICAM56 
Organisation University of Manchester
Country United Kingdom 
Sector Academic/University 
PI Contribution Manchester - expertise of Prof Withers, Matthews, Burke, Akid, Drs Connolly, Lindsay, Muryn and Race; access to the infrastructure, training and administrative support of BP-ICAM hub, access to the infrastructure, training and facilities of Henry Royce Institute; access to the training and support network of the Materials for Demanding Environment CDT.
Collaborator Contribution Leeds - expertise of Profs Neville, Morina and Dr Barker; access to the outstanding research and training environment at Institute of Functional Surfaces; access to skills and facilities in the Bragg Centre for Advanced Functional Materials within the Integrated Centre for Engineering and Physical Sciences. Imperial - expertise of Professor Harrison, Ryan and Dr Campbell; access to the Molecular Sciences Research Hub. Cambridge - expertise of Dr Clarke; upgrades to the state of the art equipment internally and at ISIS. BP - expertise of 5 BP senior technology leadership; access to marketing, communication and event management; access to BP's High Performance Computing facilities and support for 6 PhD studentships.
Impact None yet
Start Year 2017
 
Description IOM3 Materials Challenge: Resourcing Net Zero Launch digital Series 2022 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact London, UK (20 October 2022) - The Institute of Materials, Minerals & Mining (IOM3) has partnered with CWP to produce a digital series exploring expertise and advances throughout the materials cycle to address the climate crisis, achieve net zero targets and accelerate the circular economy. The Henry Royce Institute is a key contributor to the series, with case study highlights including the research underway at the Royce Sustainable Materials Innovation Hub and Royce at the University of Sheffield.
Year(s) Of Engagement Activity 2022
 
Description IOM3 Surface Engineering Workshop 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact A workshop which presented the research capability and industrial landscape of surface engineering in UK and promote collaboration between academia and industry in surface engineering
Year(s) Of Engagement Activity 2020
URL https://www.royce.ac.uk/events/iom3-surface-engineering-workshop/
 
Description Invited talk at IFPEN Workshop on Low Carbon Energies (3rd/4th November) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Title: Fundamentals for Geothermal Corrosion Control Engineering: Understanding Corrosion Scales
Discussed fundamental insight we have gained on the structure of oilfield scales, and their potential importance for corrosion control engineering in geothermal power stations.
Year(s) Of Engagement Activity 2020
 
Description Novel Applications of Advanced Electron Microscopy Techniques in Materials Failure Analysis 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact The webinar used case studies to show how scanning electron and focused ion beams can be used to analyze the early stages of initiation and propagation of cracks, both to better understand the safe lifetime of existing materials, and to look toward ways of extending the life of engineering materials and components.
Year(s) Of Engagement Activity 2020
URL https://connect.asminternational.org/communities/community-home/digestviewer/viewthread?GroupId=2808...
 
Description Youtube video - Focus on: Lubricants under Pressure 
Form Of Engagement Activity Engagement focused website, blog or social media channel
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact Iain Prentice, PhD student at the University of Edinburgh, supervised by Professor Philip Camp, was involved in a Royal Society of Chemistry public-engagement video on lubricants, released in October
Year(s) Of Engagement Activity 2020
URL https://youtu.be/Wh1tmM8e-Mk