Sustainable Coatings by Rational Design (SusCoRD)

Lead Research Organisation: University of Manchester
Department Name: Materials

Abstract

This project will, for the first time, connect a detailed scientific understanding of the mechanisms of coatings failure with state-of-the-art machine learning to deliver a design framework for the optimization of protective coatings and nanocomposite materials. It will be game changing for an industry (paint) which is often taken for granted, despite its ubiquity - the screen you are looking at, the color of your car, the protection for the aircraft you fly in, the longevity of bridges, wind turbine masts and other infrastructure. Indeed, almost all materials are made suitable for purpose or given function by the application of coatings. In the UK there are over 10,000 employees involved in manufacturing coatings and the coatings industry directly contributes over £11bn to the economy, supporting UK manufacturing and construction sectors worth around £150bn. The annual costs of corrosion damage in the UK lies in the range of 2-3% of Gross National Product (~£60 bn, 2016) and leads to premature loss of amenity in infrastructure and equipment; hence to environmental damage through accelerated extraction and resource use. Protective organic coatings (i.e. paints) are highly cost effective in limiting early materials damage due to corrosion however these are complex products where the underlying mechanistic links between the formulation and performance are lacking. The increasing need to use environmentally sustainable materials, reduce time-to-market and increase performance requires detailed mechanistic understanding across functions and length scales from the molecular to the macroscopic.

With brands such as Dulux, Hammerite and International, AkzoNobel are one of the world's largest manufacturers of protective and decorative coatings and have extensive manufacturing and research operations in the UK. AkzoNobel invests heavily in research, both in its global research hub for performance coatings in the NE of England as well as in UK universities. In particular the company (and its predecessor bodies) has collaborated in polymer science with the University of Sheffield, and in corrosion protection with The University of Manchester, for over 30 years.

This prosperity partnership between EPSRC and AkzoNobel/ International Paint with the Universities of Manchester and Sheffield, will enable for the 1st time, a fundamental mechanistic understanding of how the performance of protective organic coatings arises - essentially it will tell us "how paint works". The scope of the program is well beyond the capacity of an individual company, institution or funder and, hence, the collaborative partnership is essential in order to tackle this problem head-on. Success will allow industry to side-step the current trial-and-error approaches and to incorporate digital design (i.e. Industry 4.0) into the development of paints and similar nanocomposite materials resulting in the confidence to utilize sustainable materials, comply with legislative and customer drivers and maintain and extend performance in more extreme environments. Overall the project will deliver understanding and tools that underpin the rapid-to-market development of environmentally sustainable protective organic coatings and nanocomposites by rational design.

Planned Impact

This research proposal delivers a close partnership between AkzoNobel (AN) and the Universities of Manchester and Sheffield significantly strengthening existing collaborative ties in the area of protective organic coatings. The project will deliver a game-changing paradigm shift for a generally fragmented industry that does not individually have the capacity or scope to tackle the problem in depth. It brings an "Industry 4.0" approach to a sector that is largely craft-based and thus will have significant impact not just for the project partners, but also the supply chain for coatings formulation, for end-users of protective coatings and for other coatings suppliers. The advantages gained in achieving a predictable performance for coatings reduces costly laboratory and field testing, reduces premature failure and associated warranty claims, offers tailored products for specific markets and, importantly, offers increased service performance/longevity with a reduced environmental impact. Since protective coatings are ubiquitous the overall impact is potentially huge across almost all industry sectors: i.e. marine, construction, automotive, aerospace, energy, electronics, etc.

AkzoNobel is proud to have a track record of an active and wide dissemination of research results and all researchers and collaborators are encouraged to publish in the highest quality journals and present at international conferences such as NACE, CoSI, ECS, Eurocorr, as well as national events such as UK Electrochem and the UK Corrosion Science Symposium. AkzoNobel will also sponsor the next meetings of the international conference series "Advances in Corrosion Protection of Organic Coatings" and "Formulating Function Films and Coatings" in order to both showcase and benchmark its results with the wider academic and industry community.

The AkzoNobel Corrosion Community of Practice (CCoP) - around 20 members from key business units in 4 continents - operates regular workshops with invited audiences (from AkzoNobel, other companies and academia) on topical subjects and these will be opened up to researchers from this project in order to promote active discussion and dissemination directly into AN's business units, its supply chain and its end-users.

The collaborative nature of the program will allow individual researchers, academic supervisors and industrial mentors to enhance their skills, merging their capabilities from their own training or discipline with skills from outside their current experience. This will upskill the current in-house AkzoNobel technologists while training a new generation of young people in a complex, often neglected, but important, discipline.

The involvement of AkzoNobel's supply chain, academic colleagues from other institutions, together with the Sir Henry Royce Institute (SHRI) in the external advisory panel of this program provides an obvious pathway to wider impact. In particular this program will be core to the coatings initiative identified by SHRI as a key technology enabler.

Finally, since everyone knows what paint is (but few have any idea what it really comprises) we will undertake focused public engagement activities that will include a short film with high production values, as well as school and community based projects supported by Manchester and Sheffield Universities including the "Festival of the Mind", the "Mobile University" and the "Standing up for Science" platforms. We will also seek to engage with the Nuffield Research Placement scheme to bring 6th formers into university research environments.

Publications

10 25 50

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Wand CR (2022) Water-Mediated Epoxy/Surface Adhesion: Understanding the Interphase Region. in Chemistry (Weinheim an der Bergstrasse, Germany)

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Morsch S (2022) Internal topology and water transport in tetrafunctional epoxy resins in Journal of Applied Polymer Science

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Morsch S (2022) Molecular origins of Epoxy-Amine/Iron oxide interphase formation. in Journal of colloid and interface science

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Morsch S (2020) Examining the early stages of thermal oxidative degradation in epoxy-amine resins in Polymer Degradation and Stability

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Morsch S (2021) Local oxidation of the buried epoxy-amine/iron oxide interphase in Progress in Organic Coatings

 
Title Pop-Up University Virtual Reality exhibition September 2019 
Description Take a trip through the fantastic world of light with two virtual reality (VR) artworks developed by artist Paul Evans in collaboration with HumanVR and researchers from the Department of Physics, Dr Andrew Parnell and Professor Richard Jones. Explore a mind-bending virtual colour environment and interact with spinning neutrons and photonic structures. The VR will help to understand how functional coatings can help to provide amazing optoelectronic properties. 
Type Of Art Film/Video/Animation 
Year Produced 2019 
Impact This exhibition was seen by ~ 4000 people from all age groups and has helped to raise the profile of our work looking at functional coatings. 
URL https://www.sheffield.ac.uk/polopoly_fs/1.862151!/file/POP-UPuniversity.pdf
 
Description Our research considers how the two main components within a paint coating act together to help protect structures from corrosion and materials damage. Active paint pigments contain ingredients that slow / inhibit corrosion processes and we have developed rules that optimise their size and distribution in the coating to achieve best performance with minimum use of resource. The polymer binder in the paint holds the pigments within the solid coating and sticks the coating to surfaces and our work also considers how the polymer can itself degrade and compromise coating adhesion and cohesion. We are applying these new ideas and existing knowledge to develop computational design models that will reduce testing time and bring new sustainable paints to market faster.
Exploitation Route Contributions to basic knowledge regarding polymer/oxide interactions, and the nature of water at polymer-metal(oxide) interfaces.

Novel coatings and formulations using more sustainable/environmentally friendly materials.

Better prediction of coating performance from laboratory and short-term testing
Sectors Aerospace, Defence and Marine,Construction,Education,Energy,Environment,Manufacturing, including Industrial Biotechology,Transport

URL https://sites.manchester.ac.uk/suscord/
 
Description The research outputs have suggested two novel corrosion protective paint formulations that are currently undergoing performance testing.
First Year Of Impact 2021
Sector Chemicals,Construction,Manufacturing, including Industrial Biotechology
Impact Types Economic

 
Description Massive On-line Open Course (MOOC): Protecting the World: Introducing Corrosion Science and Engineering
Geographic Reach Multiple continents/international 
Policy Influence Type Influenced training of practitioners or researchers
URL https://www.coursera.org/learn/corrosion
 
Description Chromate-free primer performance
Amount £282,600 (GBP)
Organisation Airbus Group 
Sector Academic/University
Country France
Start 12/2019 
End 04/2023
 
Description Industrial CASE 2020 (EPSRC + AkzoNobel): "Thermal degradation of epoxy at oxidised interfaces"
Amount £88,000 (GBP)
Funding ID ICASE award voucher #20000007 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 10/2020 
End 09/2024
 
Description AkzoNobel - University of Manchester Corrosion Protection Partnership 
Organisation AkzoNobel
Country Netherlands 
Sector Private 
PI Contribution Development and direction of fundamental scientific research strategy in corrosion protection looking ahead over a 5 year period; bi-annual engagement with world-wide AkzoNobel corrosion community to showcase research and receive feedback; development of a number of showcasing activities including International Conference held in Cambridge; tactical responses to specific issues in RD&I particularly relating to product failures and final stage product performance validation; technical and consultancy advice as needed
Collaborator Contribution Financial support for Chair, 3 PDRAs and 8 PhD students; technical support to students and researchers; close interaction with business units in UK, Italy, Sweden, Netherlands; bringing science-based, mechanistic and fundamental knowledge of corrosion protection technologies to the company to assist in formulation of novel products; respond to legislative changes for materials content and to create agility in formulation and performance testing of new and existing products; hosting university researchers at business units; close embedding of university researchers into RD&I teams in the businesses.
Impact 15 publications cited 42 times since 2014 Multidisciplinary: polymer science, electrochemistry (corrosion science), metallurgy, surface engineering
Start Year 2013
 
Description Brussels / Manchester Exchange Symposium 
Organisation Vrije Universiteit Brussel
Country Belgium 
Sector Academic/University 
PI Contribution Discussed methodology of techniques
Collaborator Contribution discussed methodology of techniques
Impact Better understanding of sample preparation and NANO IR, improved technqiues for research on microscopes.
Start Year 2020
 
Description Collaboration with Centre for Polymer Interface and Molecular Adhesion Science, Kyushu University, Japan 
Organisation Kyushu University
Country Japan 
Sector Academic/University 
PI Contribution A collaboration has been established with Prof. Tanaka and Prof. Yamamoto from the Centre for Polymer Interface and Molecular Adhesion Science, Kyushu University, Fukuoka 819-0395, Japan. The research link will be via our PhD student, Kieran Harris, who has applied for a summer internship at Kyusha in the Tanaka-Yamamoto group.
Collaborator Contribution The group has expertise and international recognition in molecular and mesoscopic modelling of polymers at interfaces (mainly metallic substrates).
Impact Prof. Tanaka and Prof. Yamamoto have developed a crosslinking modelling technique that takes into account the heat of reaction and temperature inhomogeneities in the simulation box. This can be important in some cases, although it is not evident when it is necessary to include this (making the simulations slower) nor what are the limitations of the technique. A better understanding on the methodology will be gained during the summer internship.
Start Year 2022
 
Description Collaboration with Exeter University 
Organisation University of Exeter
Country United Kingdom 
Sector Academic/University 
PI Contribution A formal agreement between the University of Manchester, AkzoNobel and the University of Exeter has established Charlie Wand, a former PDRA in the project, now a lecturer at the University of Exeter. The University of Exeter is funding 50% of a PhD studentship to work on this project
Collaborator Contribution Charlie Wand will carry on molecular simulation studies of blush formation in can coatings, complementing experimental work currently done in WP2.
Impact Jointly funded PhD project outputs.
Start Year 2022
 
Description Collaborative research with University of São Paulo 
Organisation Federal University of São Paulo
Country Brazil 
Sector Academic/University 
PI Contribution Collaborative research with University of São Paulo in Brazil on corrosion protection coatings for the new generation of Al-Cu-Li alloy is now starting. PhD student will be supervised by SusCoRD academics to conduct research at the University of Manchester for 12 months.
Collaborator Contribution The project is sponsored by Research Support Foundation of the State of São Paulo, Brazil, which will support PhD student João Victor de Sousa Araujo to conduct research at the University of Manchester for 12 months.
Impact Research outcomes from student research project
Start Year 2022
 
Description Sheffield Airbus new coatings for photo elasticity 
Organisation Airbus Group
Department Airbus Operations
Country United Kingdom 
Sector Private 
PI Contribution The project is to assess the design of novel coatings to asses the mechanics of airframes using photo-elasticity. This uses Sheffields polymer expertise as well as the strengths in materials characterisation and industrial development.
Collaborator Contribution Our collaborators have a large potential market for such materials and they would be the users of any potential products that could be commercialised.
Impact The work is still at an early stage, so there are no outputs to report yet apart from a scoping of some potential new materials which is not currently in the public domain.
Start Year 2019
 
Title SimCoat: Design protective coatings 
Description SimCoat: Design protective coatings and see if they are any good. The interactive experience will start with people getting a feel for a corrosion protection coating through use of SimCoat. Different stages of the simulation will link to showcases from our researchers who will explain the impact of the science they are doing on the performance of corrosion protection coatings. 
Type Of Technology Webtool/Application 
Year Produced 2021 
Impact This will be offered at outreach events to engage non-specialist audiences of all ages 
 
Description AzkoNobel and the the EPSRC Prosperity Partnership 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Study participants or study members
Results and Impact Showcase event highlighting the collaboration between business and university partners within the SusCoRD programme.
Year(s) Of Engagement Activity 2021
URL https://www.youtube.com/watch?v=JhdqspXAFxM&list=PLM9UK6ckT5kP92285N0Rkp6hvv24eOhbL&index=6&t=33s
 
Description Being #CompChem URG: How Diversity Enriches Us 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Undergraduate students
Results and Impact Invited talk at the Global launch of Being #CompChemURG: How Diversity Enriches Us, The Binding Site, A community for underrepresented groups in computational chemistry,
Year(s) Of Engagement Activity 2021
 
Description Being queer in academia, defying expectations, Panel discussion (Nottingham) 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Undergraduate students
Results and Impact Outreach and awareness
Year(s) Of Engagement Activity 2020
 
Description Blog post on successful ARCHER2 grant for The University of Manchester Research IT newsletter 
Form Of Engagement Activity Engagement focused website, blog or social media channel
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Study participants or study members
Results and Impact A member of the team was featured in a blog post on the successful ARCHER2 grant for the University of Manchester Research IT newsletter
Year(s) Of Engagement Activity 2021
URL https://research-it.manchester.ac.uk/news/2021/07/30/interested-applying-time-archer2/
 
Description Chief Scientisit visiting UoM (Tanabe) 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Visit from member of international committee with the aim of expanding links with international markets
Year(s) Of Engagement Activity 2019
 
Description Corrosion Education article for Corrosion Management (magazine) 
Form Of Engagement Activity A magazine, newsletter or online publication
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact The corrosion & Protection Centre at the University of Manchester wrote an article about Corrosion Education for Corrosion Management, to further publicise corrosion science, our online course and the department.
Year(s) Of Engagement Activity 2019
URL https://www.icorr.org/wp-content/uploads/2019/08/CORROSION_MANAGEMENT_Issue150_LowRes.pdf
 
Description Corrosion protective coatings and sustainability 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Study participants or study members
Results and Impact Tony Ryan, Simon Gibbon and Stuart Lyon discuss sustainability with an audience of 42 from the SusCoRD research team.
Year(s) Of Engagement Activity 2021
URL https://www.youtube.com/watch?v=dm14WW4jUSU&list=PLM9UK6ckT5kP92285N0Rkp6hvv24eOhbL&index=12&t=664s
 
Description Creation of online course in corrosion engineering 
Form Of Engagement Activity Engagement focused website, blog or social media channel
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact Online course, 250 reached in engagement, aim to keep running, generates interest in corrosion science.
Year(s) Of Engagement Activity 2019
URL https://www.coursera.org/learn/corrosion
 
Description Evening Talk with Dr Andrew Parnell: Few Have Reached the First Level of Science - Wonder 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact This interactive workshop features a talk concerning the impact of John Ruskin on Science/Art.
This was followed by the opportunity to experiment with artists' pigments and observe biological specimens through the lens of a microscope.
Year(s) Of Engagement Activity 2020
URL https://www.museums-sheffield.org.uk/whats-on/events/2019/8/evening-talk-with-dr-andrew-parnell-few-...
 
Description Feature in @QueerEngineers Twitter Campaign 
Form Of Engagement Activity Engagement focused website, blog or social media channel
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Media (as a channel to the public)
Results and Impact A member of the team featured in @QueerEngineers Twitter campaign about LGBT+ Engineers
Year(s) Of Engagement Activity 2021
 
Description Presented poster at the Daphne Jackson conference 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Third sector organisations
Results and Impact Presented at conference, awareness of scheme for returning into research
Year(s) Of Engagement Activity 2019
 
Description Profile article for Schools OUT UK 
Form Of Engagement Activity Engagement focused website, blog or social media channel
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Schools
Results and Impact Profile for Schools OUT UK, a UK-based charity focussing on LGBT inclusion in schools.
Year(s) Of Engagement Activity 2021
 
Description Rawmarch Academy schools visit to Sheffield Physics January 2020 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Schools
Results and Impact The day was structured to give year 10 students a flavour of the physics behind functional coatings and how we can use thin coating materials to do amazing things.

The visit also involved artistic events to break down barriers between the researchers/academics and the schoolchildren, this helps to speak to one another in a more two way conversation.
Year(s) Of Engagement Activity 2020
URL https://twitter.com/RichardALJones/status/1220692433480179714
 
Description Talk at UoM celebrating international women`s day 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Postgraduate students
Results and Impact Gving a talk as a woman in Science - sharing accomplishments in research and interests outside of research!
Year(s) Of Engagement Activity 2020
 
Description Webinar:'Corrosion: The $2.5 Trillion Dollar Problem' 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact A free event where a panel of experts discuss new strategies which exist to prevent and combat the urgent global challenge of corrosion.
Chair:
Professor Tony Ryan OBE - Co-Director, Grantham Centre for Sustainable Futures, The University of Sheffield
Speakers:
Professor Mary Ryan - Interim Vice-Provost (Research and Enterprise), Imperial College London
Professor Richard Jones - Vice-President for Regional Innovation & Civic Engagement, The University of Manchester
Dr Mark Irwin - R&D Leader in Polymer Research, AkzoNobel
Year(s) Of Engagement Activity 2022
URL https://www.eventbrite.co.uk/e/corrosion-the-25-trillion-dollar-problem-tickets-295229388047
 
Description Young Researchers Seminar 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Claudio Fonte co-organised a Young Researchers Seminar in Toulouse, France (Baldyga Technical Seminars) where PhD Students and Early Career Researchers presented their work on experimental and modelling of fluid flow, focusing on visualisation.
Year(s) Of Engagement Activity 2022
 
Description member of IOM3 Corrosion group committee 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact N/A
Year(s) Of Engagement Activity 2019