Radiochemical Facilities for the Molten Salts in Nuclear Technologies Network

Lead Research Organisation: University of Manchester
Department Name: Chem Eng and Analytical Science

Abstract

The Molten Salt in Nuclear Technology Laboratory (MSNTL) aims to provide a network of research equipment and expertise to support the recently expanding interests in molten salt technologies for use in next generation nuclear fuel cycles. Recent world-wide interest in molten salt reactor (MSR) technology in advanced nuclear reactor designs presents an ideal opportunity to utilise the UK's established expertise in spent nuclear fuel pyroprocessing to make a vital contribution to the emerging development of this reactor type. Even though there has recently been substantial investment in MSR designs across numerous companies and institutes, there are still substantial research challenges that need to be addressed to allow the deployment of these advanced reactors. The MSNTL addresses a gap in capability by providing user access to state-of-the-art research facilities that can safely handle fluoride melts (the dominant salt type in MSRs) with radionuclides and radiation doses that will be present in these reactor process environments. The equipment provided in the MSNTL will allow the safe assessment of salt and materials behavior in process-like demanding environments, and enable the development of valid management strategies for waste streams from molten salt technologies. The MSNTL forms a key component in a large network of facilities that can provide comprehensive assessments of molten salt technologies across radioactivity levels and process scales.

Planned Impact

The MSNTL facilities will be able to provide the following key academic and industrial impacts with the associated beneficiaries:
1) Contribute to databases of physicochemical parameters pertaining to molten salt media with various compositions that are relevant to nuclear process environments
2) Structural materials performance assessments for molten salt technologies across process-like conditions, including radionuclide content, radiation doses and salt type, providing comprehensive selection criteria to determine material type/s for structural containment of molten salt technologies in nuclear processes - to be utilised by design companies in the nuclear supply chain who intend to implement molten salt technologies, like molten salt reactors and pyroprocessing. Potential for cross-over into other technology areas (see Section 2.4 below).
3) Understanding of the behaviour of nuclear graphite and other graphitic materials upon exposure to molten salt media including the impact of irradiation and interactions with radionuclides - to be utilised by molten salt reactor design companies in safety cases of molten salt reactor designs where nuclear graphite is used as moderator materials or in graphitic coated fuels.
4) Development of novel molten salt technologies for decontaminating materials from nuclear processes for reclassification to lower waste categories, and advanced processes for the effective treatment and disposal of salt-bearing nuclear waste streams as part of an integrated waste management strategy - For use by nuclear supply chain companies in decommissioning programmes. Can ensure the continuation of these companies beyond the decommissioning of the current generation of nuclear plants by providing strategies for the management of the next generation of nuclear reactors. Thereby, providing employment security and the capability to develop long-term plans for supporting local infrastructure. Benefits for the UK NDA and equivalent decommissioning bodies world-wide reducing GDF requirements and ultimately the tax-paying general public.
5) Journal and conference publications will be submitted from work performed at the MSNTL - for the benefit of the entire nuclear and molten salt technology communities. (Note: The use of Mendeley Data for the sharing of large quantities of data will be used in this programme, where appropriate. Agreements will be made between the user and the MSNTL on a case-by-case basis where open access of data may not be possible, such as IP and export control concerns.)

Publications

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Mirza M (2023) Electrochemical processing in molten salts - a nuclear perspective in Energy & Environmental Science

 
Description The design of a novel systems for testing using solid adsorbents and ion exchange materials the clean-up of high temperature molten salts, including fluoride salts, from radioactive contaminants under dynamic flow has been completed. We have also successfully designed of containment systems that will allow the exposure of materials such as stainless steel to various radiation sources (e.g. alpha, gamma) while in contact with high temperature molten salts. The systems have been constructed, and after successful commissioning and testing in our newly constructed laboratory facility for the Manchester hub of the MSNTL, will be made available to the molten salts research community.
Exploitation Route Novel equipment to be made available to the molten salts user community with interests across molten salt reactor technologies, pyroprocessing of spent nuclear fuel and in novel decontamination approaches.
Sectors Energy

 
Description A molten salt community framework for predictive modelling of critical characteristics
Amount £581,674 (GBP)
Funding ID EP/X011607/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 07/2023 
End 06/2026
 
Description Advanced Fuel Cycle Programme - Pyroprocessing
Amount £774,982 (GBP)
Organisation National Nuclear Laboratory 
Sector Public
Country United Kingdom
Start 10/2020 
End 06/2021
 
Description Measurement of melting point and density of fluoride salt mixtures
Amount £86,287 (GBP)
Funding ID 2055546 
Organisation UK Atomic Energy Authority 
Sector Public
Country United Kingdom
Start 11/2021 
End 05/2022
 
Title Irradiation rigs for materials testing in contact with molten salts. 
Description Rigs for testing the materials performance of candidate containment steel and alloys when exposed to radiation fields while in contact with molten salts have been designed. The rigs will be deployed for use with the particle accelerator (alpha particle bombardment predominantly) and the Co-60 gamma irradiator at the Dalton Cumbrian Facility. The rigs are designed to accommodate various salt types including fluorides, and allow ready sampling of salt for content analysis. The rigs have been designed and are currently being constructed. It will be made available for use after commissioning and testing. 
Type Of Material Improvements to research infrastructure 
Year Produced 2022 
Provided To Others? No  
Impact Not yet. 
 
Title Rig for testing of of solid adsorbents/ion exchange material for treatment of high temperature molten salts under dynamic flow. 
Description This rig allows for the ready testing of solid adsorbent and ion exchange materials in the clean up of molten salts from radioactive contaminants (e.g caesium and strontium) found in the pyroprocessing of spent nuclear reactors and in the fuel of certain molten salt reactor designs. The rig is column set up that test the loading of various contaminant species onto the treatment material under dynamic flow. The rig is designed to accommodate various salt types including fluorides, and allow ready sampling of salt for content analysis. The rig has been designed and is currently being constructed. It will be made available for use after commissioning and testing. 
Type Of Material Improvements to research infrastructure 
Year Produced 2022 
Provided To Others? No  
Impact None yet. 
 
Description KAIST-DAWNMANTLE 
Organisation Korea Advanced Institute of Science and Technology (KAIST)
Country Korea, Republic of 
Sector Academic/University 
PI Contribution Studies on the contamination processes of stainless steel in molten salt process operations. Particle irradiation of stainless steel materials to mimic likely the likely radiation exposure of such materials in various nuclear operations. Preparation of materials to be used to decontamination testing. All as part of the Dawnmantle consortium supported by EPSRC (UK) and NRF (Korea) through the UK-ROK Civil Nuclear partnership.
Collaborator Contribution Studies on the development of Laser Induced Breakdown Spectroscopy to monitor molten salt compositions. Effluent treatment of possible associated waste streams from molten salt operations. All as part of the Dawnmantle consortium supported by EPSRC (UK) and NRF (Korea) through the UK-ROK Civil Nuclear partnership.
Impact J. T. M. Amphlett, S. Choi, S. A. Parry, E. M. Moon, C. A. Sharrad and M. D. Ogden, Insights on uranium uptake mechanisms by ion exchange resins with chelating functionalities: Chelation vs. anion exchange, Chem. Eng. J (2020) 392, 123712. DOI: 10.1016/j.cej.2019.123712 Multidisciplinary: Chemistry, Materials Science, Chemical Engineering, Analytical Science
Start Year 2019
 
Description PSU - molten salts 
Organisation Penn State University
Department Penn State Abington
Country United States 
Sector Academic/University 
PI Contribution Part of the UK-US recently established relationships from the Nuclear Energy Universities Programme jointly supported by EPSRC in exploring high temperature molten salt behaviour to support developments in the pyroprocessing of spent nuclear fuel and molten salt reactors. Our contribution in this relationship is to provide experimental support to the programme especially where the MSNTL can provide capabilities for the study of fluoride melts.
Collaborator Contribution Penn State University will predominantly provide contributions in computational modelling that will develop predictive capability for molten salt behaviour.
Impact Collaboration is multidisciplinary across chemistry and chemical engineering, and across experimental and computational activities. The collaboration has only recently commenced within a NEUP project so there are no outputs or outcomes at this stage.
Start Year 2023
 
Description Ulsan - Dawnmantle 
Organisation Ulsan National Institute of Science and Technology
Country Korea, Republic of 
Sector Academic/University 
PI Contribution Studies on the contamination processes of stainless steel in molten salt process operations. Particle irradiation of stainless steel materials to mimic likely the likely radiation exposure of such materials in various nuclear operations. Preparation of materials to be used to decontamination testing.
Collaborator Contribution Preparation of steel materials to mimic exposure in reactor operations.
Impact Multidisciplinary - Chemistry, Materials, Chemical Engineering
Start Year 2019
 
Description WSU - molten salts 
Organisation Washington State University
Department Washington State University Spokane
Country United States 
Sector Academic/University 
PI Contribution Part of the UK-US recently established relationships from the Nuclear Energy Universities Programme jointly supported by EPSRC in exploring high temperature molten salt behaviour to support developments in the pyroprocessing of spent nuclear fuel and molten salt reactors. Our contribution in this relationship is to provide experimental support to the programme especially where the MSNTL can provide capabilities for the study of fluoride melts.
Collaborator Contribution WSU will predominantly offer computational support in developing capabilities for predicting molten salt behaviour and performance.
Impact This collaboration is multidisciplinary across chemistry and chemical engineering, while also covering experimental and computational activities. This collaboration has only recently commenced with a NEUP project so there are no outputs or outcomes at this stage.
Start Year 2023
 
Title GRAPHITE DECONTAMINATION 
Description The present invention relates to methods of decontaminating irradiated nuclear graphite. The method comprises immersing the irradiated nuclear graphite in a molten salt electrolyte, and subjecting the irradiated nuclear graphite to an electrochemical treatment. 
IP Reference WO2021250413 
Protection Patent granted
Year Protection Granted 2021
Licensed No
Impact -
 
Description EAFORM 2022 - Jeju Island 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Invited talk including an opening address by Clint Sharrad at EAFORM 2022 (The 7th East Asia Forum on Radwaste Management) held at Jeju Island, South Korea. Numerous requests and discussions were had from various people across mulitple nations on possible collaborative opportunities.
Year(s) Of Engagement Activity 2022
 
Description International Molten Salt workshop - Seoul National University 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Invited talks delivered by Clint Sharrad and Tatiana Grebennikova from the Dawnmantle consortium and MSNTL at the International Workshop of Molten Salts Chemistry and Technologies for Nuclear Applications held at Seoul National University. The workshop had expert speakers in the molten salts area from multiple nations across both academia and industry with an audience of ~ 50 people mainly consisting of postgraduate researchers and academics across South Korea.
Year(s) Of Engagement Activity 2022
 
Description Molten Salts in Nuclear Technology Laboratory 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Study participants or study members
Results and Impact Promotion of the Molten Salts in Nuclear Technology Laboratory National Nuclear User Facility to the molten salt user community represented by the Royal Society of Chemistry Molten Salts and Ionic Liquids Discussion Group.
Year(s) Of Engagement Activity 2019
 
Description OECD/NEA Expert Group on Innovative Structural Materials - High entropy alloys for advanced nuclear applications Workshop 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact The NEA Expert Group on Innovative Structural Materials (EGISM) organised a workshop together with the Spanish Center for Energy, Environmental and Technological Research (CIEMAT) on the development, potential uses, opportunities and limitations of high entropy alloys for nuclear applications. Held virtually on 19-21 October 2021, the event attracted 120 participants from 11 countries who exchanged the latest developments and innovations in the field of high entropy materials and complex concentrated alloys. The workshop opened with an overview on research and development initiatives in this field with perspectives from the People's Republic of China, the European Union and the United States. The discussions then addressed numerical design and computational approaches to develop high entropy alloys, as well as fabrication and manufacturing and microstructures and mechanical properties of high entropy alloys. Irradiation resistance of high entropy alloys and their compatibility with corrosive environments were also explored. Participants agreed on the importance of collaboration at the international level to support the acceleration of high entropy materials development for use in the nuclear industry. A broad consensus was also expressed on the need to accumulate both theoretical and experimental data on the behaviour of these materials in conditions that simulate nuclear reactor conditions. Considering the broad variety of systems included in this class of materials, efforts will be also needed to collect and systematise data in a consistent way as they are produced - especially considering the fact that research in this field heavily involves the use of machine learning techniques for both material design and material modelling purposes.
Year(s) Of Engagement Activity 2021
URL https://www.oecd-nea.org/jcms/pl_61782/high-entropy-alloys-for-advanced-nuclear-applications