ECCS - EPSRC Development of uniform, low power, high density resistive memory by vertical interface and defect design

Lead Research Organisation: University of Cambridge
Department Name: Materials Science & Metallurgy

Abstract

The future of energy-efficient computing will increasingly move from being compute-centric to being memory-centric. There is a huge-energy cost of storing and moving data, which is much higher than computing it. Indeed, memory dominates compute energy (>4X) in data-intensive applications. New ultralow power non-volatile memory (NVM) is central to all aspects of computing, from stand-alone, storage class memory (SCM) for use in data centres, to embedded non-volatile memory (e-NVM) for IoT, the automotive industry, etc, to new forms of computing. The area is growing hugely, along with the associated energy consumption, e.g. data centers will use >10% of global electricity by 2030 with a market growing ~10% per year, to >$150 billion by 2023. Such efficiency cannot come from processing as Moore's law reaches an end and new processor technologies are not yet established. The biggest performance and energy saving gains will be in memory. The replacement of standard memory with high performance memory NVM could reduce power usage by more than 60%.

Of the many candidate NVM forms under intense investigation, oxide resistive RAM (RRAM) has the greatest potential in terms of cost, density, simplicity and potential for 3D integration. However, several challenges currently exist, notably the need for a forming voltage, poor uniformity, scaling, and endurance. The aim of this project is to overcome these challenges. It will be done by adopting our ground-breaking results from an ideal system to an industry platform. So far, in the ideal system, we have demonstrated that a) precise and non-random conducting channels can be engineered into films to eliminate the need for a high voltage forming process; b) high and controlled oxygen vacancy concentrations lead to highly and reproducible on-off ratios; c) eliminating use of transition metals produces low leakage and strongly reduces variabilities from film to film. The industry platform we will explore in this project is doped HfO2, grown by sputtering and atomic layer deposition.

An internationally leading team with more than 15 years of very strong collaboration in the area of the proposal will undertake the work. First, growth of VAN films using pulsed laser deposition (PLD) will be undertaken at Purdue University. PLD is the simplest way to make the most perfect metal oxide films in a rapid way. These will enable us to understand the RS processes more fully and will provide information on how to grow the films by the industrially scaleable processes. Both Purdue and Cambridge will be involved in the HfO2 nanostructure film design for PLD. The knowledge from the PLD growth will then be translated to the sputtering and ALD approaches undertaken at the University of Cambridge. The effort at the University at Buffalo will focus on the fabrication and testing of prototype memristors and RRAMs using the RS films deposited by Purdue University and University of Cambridge. State-of-the art (some in-operando) characterisation tools will also be central to materials understanding and device optimisation and these will be used at Purdue and Cambridge. A very strong interaction between the groups, with regular sample and knowledge transfer will take place. Our ultimate goal is a forming free device, with on/off ratio~104, endurance >1012, <10pJ per switch, uniformity of few %, scaled to 20 nm.

In terms of training, we will educate graduates in materials sciences and electronic engineering. We will train more than 3 early career researchers in world-leading research environments in the US and UK, with several companies involved (small to large), including the Cambridge company ARM who are very active, both in the UK and US, in the memory area.

Planned Impact

New high performance NVM is critical to many technology sectors, i.e. in transport, medicine, communications, and IoT. The total market for all these areas is huge, i.e. $ Trillions. Industry adoption of high performance advanced NVM memory would have a huge impact on all these technologies. If our proposed solutions for oxide RRAM are successfully translated to an industry platform then we will have achieved a game-changing NVM technology and it will have a huge impact on future technologies. This will lead both to the creation of many new high tech jobs and to an improvement in quality of life by reducing CO2 emissions. Hence, there is the potential for strong societal impact.

In terms of academic impact, the strong global competition for skilled personnel and the increasing international competition in new technologies, particularly in advanced materials, means that training of a number of high quality engineers and scientists is crucial. The broader training we will provide the team in advanced memory technology will feed not just into the academic community but also into high tech industries. Such industries all report difficulties in finding skilled people, including the companies we will collaborate with in this project.

Strong industrial manufacturing bases in high technology areas to enhance the knowledge economy are very important in both the UK and US for high value-added job creation, and these are current priorities of both governments. Indeed, the advanced NVM topic lies at the heart of a number of UKRI priority areas related to both economic impact and improved quality of life: Advanced materials for NVM aligns with the Government's 2017 industrial strategy white paper. The first grand challenge is, 'put the UK at the forefront of the artificial intelligence and data revolution', mentioning ARM's microchips as being a great underpinning technology. NVM technologies are also key to advances in cognitive computing, boosting the development of artificial intelligence. A second UK grand challenge is 'Clean Growth', with 'development, manufacture and use of low carbon technologies'. The need for NVM in electric vehicles and a very wide range of other green technologies, ideally places NVM development under this second challenge area. NVM development aligns also with UKRI priorities under the following themes: 'manufacturing the future', 'the digital economy', and 'ICT'. NVM also fits under the Eight Great Technologies areas of 'Advanced Materials' and 'Big data and energy efficient computing'.

The development of advanced memristors and NVM is also of great interest to the US private sectors and US government, in all the same areas as listed above for UK government priorities. Currently, exascale computing systems have been planned for 2020 through 2022 in US. Other priorities in the US are improving security circuits for the IoT and AI chips, and computer-in-memory for deep neural networks. NVM is a key technology for these areas.

Publications

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Dou H (2022) Optical dielectric properties of HfO2-based films in Journal of Vacuum Science & Technology A

 
Title Research data supporting "Real-Time In-Situ Optical Tracking of Oxygen Vacancy Migration in Memristors" 
Description  
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://www.repository.cam.ac.uk/handle/1810/311290
 
Description Purdue Univ. 
Organisation Purdue University
Country United States 
Sector Academic/University 
PI Contribution TEM done on our materials.
Collaborator Contribution Lots of TEM
Impact Many papers. Further EPSRC funding.
Start Year 2017
 
Description memory collaboration with Prof. Quanxi Jia 
Organisation University at Buffalo
Country United States 
Sector Academic/University 
PI Contribution biweekly meetings, provision of films for electrical measurements, general discussions
Collaborator Contribution biweekly meetings, electrical measurements, general discussions
Impact it is very multidisciplinary. There are a lot of other grants associated with it. We are doing a lot of outreach things associated with it, via Royal Academy of Engineering web events, fellows day, and via the cambridge science festival.
 
Title RESISTIVE SWITCHING DEVICES AND METHODS FOR THEIR MANUFACTURE AND OPERATION 
Description The present invention relates to resistive switching devices and methods for the manufacture of resistive 5 switching devices and to methods for the operation of resistive switching devices. Such devices are of particular, although not necessarily exclusive, interest as non-volatile memory devices. 
IP Reference 008149451 
Protection Patent application published
Year Protection Granted 2022
Licensed No
Impact The application has just been filed.
 
Description Leverhulme research centre Liverpool, invited talk, 9/22 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact talk on the work related to this grant
Year(s) Of Engagement Activity 2022
 
Description MRS India meeting in Jodphur, Dec. 2022. GAve a prize lecture 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact MRS I International prize lecture. Talked on the memristor work funded by this grant.
Year(s) Of Engagement Activity 2022
 
Description Resisistive switching 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact i am organising this meeting on memory. We will all present many poster presentations at it.

https://horizons.aip.org/materials-challenges/
Year(s) Of Engagement Activity 2021
URL https://horizons.aip.org/materials-challenges/
 
Description cambridge memristor workshop, 7/9/22, which I organised 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Professional Practitioners
Results and Impact Talks at the meeting, aimed at understanding the mechanisms of our research
Year(s) Of Engagement Activity 2022
 
Description talk at IWAM 2023 conference 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Talks to researchers and school kids at IWAM 2023
Year(s) Of Engagement Activity 2023
 
Description talk at The Green Scene Webinar Series 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact prestigious international meeting. Keynote talk.
Hosted by Institute of Materials Research & Engineering (IMRE), A*STAR
Year(s) Of Engagement Activity 2013,2020
URL https://www.a-star.edu.sg/imre/events/the-green-scene-webinar-series