INFUSE: Interface with the Future - Underpinning Science to Support the Energy transition

Lead Research Organisation: Imperial College London
Department Name: Materials

Abstract

Climate Change is the single biggest threat to present and future generations: to meet the ambitious targets for net zero CO2 set out by the UK government and in line with Paris Climate Agreement requires technological mobilization on an unprecedented scale - with action required in rapid development and deployment of new approaches. A paradigm shift in the UK's research and development capabilities is needed to reduce time to market for novel and sustainable solutions for energy production and consumption. Successful rapid translation requires partnership between academia and industry, with a shared vision and commitment.

Proposed technological strategies for CO2 reduction - either at source (you don't produce it) or post combustion mitigation (you capture and use it) - have limitations in efficiency, stability or lifetime associated with the behaviour of material interfaces in the systems, and how these interfaces change with time in the operating environments. Examples of such dynamic systems range from geological carbon capture and storage, to interfaces in new electric vehicles, to nanoscale materials for catalysts or energy harvesting. If we were able to understand and control such interfaces it would provide a transformation in our ability to create, optimize and deploy radical technological solutions to both combat climate change and create clean energy systems.

In this joint programme between Shell, Imperial College London and the UK National Synchrotron Facility - Diamond Light Source - we aim to develop entirely new capabilities to study the behaviour of interfaces under complex real world conditions - such as high temperature, flow, stress, electric fields etc. and to be able to correlate the measurements in time and across length-scales so that we build up a complete picture of interface properties and how they change. We will combine these experiments with state-of-the-art computational techniques to provide new insights into interfacial behaviour. This mechanistic platform represents the foundation that will underpin the rational design of new materials and processes with reduced energy demand, better lifetime or more robust integrity.

Publications

10 25 50
publication icon
Ayestarán Latorre C (2021) Mechanochemistry of phosphate esters confined between sliding iron surfaces. in Communications chemistry

publication icon
Zhang X (2022) Quantifying Wetting Dynamics with Triboelectrification. in Advanced science (Weinheim, Baden-Wurttemberg, Germany)

publication icon
Zhang Y (2022) Nonlinear multiphase flow in hydrophobic porous media in Journal of Fluid Mechanics

 
Description EPSRC iCASE 2022 training grant - iCASE studentship with Shell (voucher number 220145)
Amount £135,000 (GBP)
Funding ID 220145 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 11/2022 
End 11/2026
 
Description Flexoelectricity for green energy batteries
Amount £204,031 (GBP)
Funding ID EP/X026582/1 
Organisation Marie Sklodowska-Curie Actions 
Sector Charity/Non Profit
Country Global
Start 07/2023 
End 07/2025
 
Description High Voltage Ceramic Heating (ETC-2022-5818)
Amount £477,000 (GBP)
Organisation Shell Global Solutions International BV 
Sector Private
Country Netherlands
Start 01/2023 
End 01/2025
 
Description Imperial-Shell UTC for Fuels and Lubricants (renewal 2021-2026) - Prof. Dini co-director
Amount £2,167,700 (GBP)
Organisation Shell Global Solutions International BV 
Sector Private
Country Netherlands
Start 10/2021 
End 03/2026
 
Description RAEng/Shell Research Chair in Complex Engineering Interfaces
Amount £1,202,967 (GBP)
Funding ID RCSRF2122-14-143 
Organisation Royal Academy of Engineering 
Sector Charity/Non Profit
Country United Kingdom
Start 03/2022 
End 03/2027
 
Description Researcher Development Grant
Amount £500 (GBP)
Funding ID D22-0562069656 
Organisation Royal Society of Chemistry 
Sector Charity/Non Profit
Country United Kingdom
Start 06/2022 
End 07/2022
 
Description Diamond/Imperial/Universitat Autònoma de Barcelona 
Organisation Autonomous University of Barcelona (UAB)
Country Spain 
Sector Academic/University 
PI Contribution Thokozile Kathyola and Sofia Diaz-Moreno will develop novel in situ/operando experimental set-ups for the characterisation of adsorbents using correlative synchrotron X-ray techniques, plan and execute beamtime experiments, and provide data analysis expertise. Ronny Pini, Camille Petit, and Killian Gymrek will provide samples, offer expertise on adsorption processes, and provide information on complementary lab-based experiments.
Collaborator Contribution Roberto Boada Romero will provide expertise on the analysis of zeolitic imidazolate frameworks using X-ray absorption spectroscopy.
Impact Beamtime Experiments: Diamond Light Source (Beamline I18; December 2022) - Elucidation of Adsorption-Induced Structural Transitions in Zeolitic Imidazolate Frameworks at High Pressures
Start Year 2022
 
Description Diamond/University of St Andrews 
Organisation University of St Andrews
Department School of Chemistry St Andrews
Country United Kingdom 
Sector Academic/University 
PI Contribution Thokozile Kathyola, Sofia Diaz-Moreno and Anna Korner will develop novel in situ/operando experimental set-ups for the characterisation of catalysts using correlative synchrotron X-ray techniques, plan and execute beamtime experiments, and provide data analysis expertise.
Collaborator Contribution Paul Webb will provide samples, offer expertise on catalytic reactions, and provide information on complementary lab-based and synchrotron experiments.
Impact Beamtime Experiments: Diamond Light Source (Beamline I18; April 2023) - Operando High-Pressure Studies of CO2 Co-feeding in the Fischer-Tropsch Reaction Using Combined X-ray Spectroscopy, Scattering, and Imaging The European Synchrotron Radiation Facility (Beamline ID31; July 2023) - Operando High-Pressure Studies of CO2 Co-feeding in the Fischer-Tropsch Reaction Using Combined X-ray Scattering and Imaging Conference Contributions: Operendo VII Conference (Poster; May 2023) - Operando Studies of High-Temperature Fischer-Tropsch Synthesis Using Combined X-ray Spectroscopy, Scattering, and Imaging
Start Year 2022
 
Description 18th International Conference on X-Ray Absorption and Fine Structure (XAFS 2022) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Thokozile Kathyola gave an oral presentation at the 18th International Conference on X-ray Absorption Fine Structure in Sydney, Australia on the 11th of July 2022. The title of the presentation was, "X-ray absorption spectroscopy study of the effects of temperature, pressure, and shear on the local structure of vanadium-based oil lubricant additives". She was also a contributor to another talk on "Self-Absorption Effects in Ambient Pressure Total Electron Yield X-ray Absorption Spectra: The Crucial Role of Fluorescence-Induced Gas Ionization". Notably, she applied for and received extra funding to attend this conference from the Royal Society of Chemistry (RSC) Researcher Development Grant. Thokozile was able to guage the importance of her work, establish new collaborations, and expand her network of contacts in the X-ray spectroscopy community.
Year(s) Of Engagement Activity 2022
 
Description 9th UK Catalysis Conference 2023 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Thokozile Kathyola attended the 9th UK Catalysis Conference 2023 in Loughborough, UK from the 4th to 6th January 2023. She established new collaborations and expanded her network of contacts in the catalysis community.
Year(s) Of Engagement Activity 2023
 
Description Exhibition at the New Scientist Live, London October 2022 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Our group routinely has an exhibition stand (E22 in 2022) at the New Scientist Live, where we explain the wonder of friction and interfaces to the general public.
Year(s) Of Engagement Activity 2018,2019,2022
URL https://live.newscientist.com/partners-exhibitors