Self-Tuning Fibre-Reinforced Polymer Adaptive Nanocomposite (STRAINcomp)

Lead Research Organisation: Cranfield University
Department Name: Sch of Aerospace, Transport & Manufact

Abstract

Self-Tuning Fibre-Reinforced Polymer Adaptive Nanocomposite (STRAINcomp) will provide a state-of-the-art, swift, reversible and process-efficient material and technology in response to varying operating loads, an innovative scientific answer to the rate dependence challenge with a novel integrated material development. It proposes one small step towards a giant leap for development of smart critical structures equipped with self-regulate micro-mechanisms.
STRAINcomp is mainly aligned with the EPSRC's Engineering and Manufacturing the Future themes, in the areas of Materials engineering - composites and Manufacturing technologies which have been identified as areas to maintain by the EPSRC as well as including priority areas of Engineering Sciences, Functional Materials and Polymer Science. It is inherently multidisciplinary, and directly targets novel, innovative and disruptive technology of self-tuning high performance composite material for UK and global composites sectors. This will bring a novel material development that will put the UK position ahead of the global pioneering innovations and market.
The UK sectors including aerospace (e.g. fuselage and wing structures), renewable energy (e.g. wind and tidal turbine blades and cowlings), automotive (e.g. composite panels, chassis, bumpers), civil (e.g. bridge beams, lamp-posts, road furniture), rail (e.g. composite carriages), marine (e.g. boat hulls and masts) and high-end sports equipment markets urgently require toughening solutions. There are many established polymer composites businesses and fast growing sectors in UK (e.g. Composite Reinforcements UK, Bombardier, Cambridge Nanosystems, Hexcel, Munro Technology etc.). These companies will directly benefit from the outputs of this project.

Planned Impact

The technology proposed by STRAINcomp will be applicable to a variety of research communities, scientists, educators, students and composite industries from the highly conservative aviation to automotive and renewable energy sectors as well as biomedical sector. STRAINcomp will also have indirect impacts on reductions in energy consumption and greenhouse gas emissions during the manufacturing process through the use of less carbon fibres, or microwave and radio frequency rapid heating technologies. The PI has microwave curing experience with his former projects of Dielectric Activated Resin Cure for Composite Repair (Institutional grant funded at Cranfield) as PI and Fastener-less Joining Technologies for High Performance Hybrid Composites (Science Foundation Ireland funded at Irish Centre for Composites Research) as project manager and research fellow. This experience can take the outcomes of this project further that composites processing will be beneficial from. Developed in-situ measurement and strain sensor technologies via dielectric constant measurements can also be influenced post-project. That can open up opportunities for non-destructive dielectric measurement of defects in structure.

The major impact of this project will be to inform development practice by improving the scientific understanding of micro-toughening mechanism in the presence of nanomaterials so as to provide researchers, designers and manufacturers with the confidence to invest in this multi-disciplinary efficient technology and thereby improve materials and structures sustainability. Dielectric multifunctional composites are multi-purpose materials used in high performacne structures for conductivity (e.g. microelectronics), rapid processing (e.g. microwave curing), electromagnetic shielding (e.g. military aircrafts), energy storage and recently for dissassembly purpose (e.g. fastener-less technology in www.falcom.ie) but there is no robust practical evidence to demonstrate their ability for smart toughening by cost-effective process and property tailoring proposed by STRAINcomp. By providing the evidence base for cost-effective lightweight technologies, STRAINcomp can stretch
further towards low income companies as well as critical highly certification driven sectors such as aerospace and defence, and towards other multifunctional sectors such as biomedical devices, and/or communities will be able to afford to invest in improving their own multifunctional products, and realise the benefits.
These benefits include less time, cost and energy spent. STRAINcomp material can be tailored in such way to process with efficient low-cost processing technique, and provides an acquired-on-demand self-tuning technology which, with lowest interference with the structural integrity maintining nominal properties, significantly reduces the energy required for toughening. Designers can satisfy requirements at both static and dynamic operating conditions with directional properties that STRAINcomp proposes, and hence use less complex geometric features, materials and assembly procedures. Further continuation of STRAINcomp can lead to rapid processing using uniform electromagnetic radiation as dielectric nanomaterials can efficiently absorb radiation which in return heat up their surrounding polymer uniformly. The impact on cost-effectiveness and eco-friendliness will be substantial as the time and energy required for fabrication of STRAINcomp will be significantly reduced. This will ultimately lead to highly sustainable product, process and environements.

It is estimated that due to the multi-disciplinary nature of STRAINcomp the ultimate result is that almost all composite sectors will be benefited. This will make highly competitive composite market and will lead to cheap products so public will directly be benefited, but the impact on the environment and energy consumption will be minimal.

Publications

10 25 50

 
Description The following key developments were achieved through the STRAINcomp:

- Passive mechanical property tailoring of smart nanocomposite materials was enabled.
- A novel characterisation instrument design was proposed and is under development for the first time globally for quantification of electromagnetic radiation induced mechanical strains.
- A petent is under development based on the proposed characterisation method and instrument.
- A number of publications have been published and are under preparation for publication in top rank scientific and engineering journals.
- New collaborations with the UK, US and European academies have been made as result of the research, which will be further accompanied with new UKRI (EPSRC), NSF-EPSRC, SFI-EPSRC and H2020 proposals.
- New interests in high performance composite sector have been raised that will result in further industrial collaborations with pioneering aerospace, transport and energy composite industries.
- A new scientific direction is under development for science and academic communities, to be supported by new publications, which can be implemented as new scientific training materials and also state-of-the-art discoveries.
- Secondments of the STRAINcomp researchers at the newly established partners (e.g. the University of Manchester for 3D X-ray tomography) has been done.
- One website dedicated to STRAINcomp (www.straincomp.com) and another as result of the research activities of the STRAINcomp team relating to multifunctional nanocomposites (www.cranfield.ac.uk/multicomp) has been created.
- Two PhD projects were defined (Ms. Danning Li and Mr. Raghvendra Mishra) who continued the project after its end date, studying the phenomenon and conducting the development of STRAINcomp at two separate scales of molecular and meso-scale:
https://www.cranfield.ac.uk/people/danning-li-19334958
https://www.cranfield.ac.uk/people/raghvndra-kumar-mishra-23556703

Mr. Raghvendra Mishra's PhD is funded by the EPSRC DTP:
https://gtr.ukri.org/projects?ref=studentship-2278684
Exploitation Route STRAINcomp findings will contribute to mechanical engineering, material science, chemistry, polymer sciences, nanotechnology and biomedical disciplines. Therefore, academic beneficiaries can be varied. STRAINcomp will provide knowledge and understanding of the dielectric activated microstructural evolution and its effect on the properties of polymer composites. Mechanical engineers in all industrial sectors related to critical structures (e.g. aerospace) will benefit from STRAINcomp as it offers self-tuning high toughness material. Biomedical scientists will benefit from this project as it will allow new materials for deformable cortical tissue and stent replacements, which are capable of being electrically excited and deformed. Engineers and researchers in chemistry, polymer science and nanotechnology will also benefit as the STRAINcomp will offer efficient nanomaterial embedment in such way to make the material highly sensitive to dielectric field so as to be able to tune properties.
The beneficiaries who will be benefited from the outcomes of the STRAINcomp project are listed below:
- First and foremost, all UK academies, their researchers, staffs and activities involved in polymer chemistry, polymer composite materials and structures (adhesively bonded joints), and multi-functional composites will directly be benefited especially the core UK universities in the THE EPSRC FUTURE COMPOSITES MANUFACTURING RESEARCH HUB including Imperial College London, Universities of Bristol, Manchester, Nottingham, Southampton and Cranfield.
- Indirect beneficiaries will include those departments involved in dielectric nanomaterials and nano-synthesis, and biomedical devices and engineering.

The benefits will be realised through conference presentations, paper writing, seminars, workshops, direct internal/external meetings with the beneficiaries and social media/website updates.

The findings will also be presented to the general public through public engagement activities such as opening days, and science days at Cranfield. During these events a demonstration of STRAINComp and its findings will be given to members of the public by the PI. Additionally we hope to hold an event at the Lates in Science Museum in
London. These events will be advertised on the project's website (www.straincomp.com), Cranfield University website and through social media use as Twitter, LinkedIn, and Research Gate.

Besides the potential material science discovery behind variable fibre-matrix interface, the project is exploring for two separate pieces of intellectual properties (IP).

The outcome of STRAINcomp will directly be open access for all scientific and academic activities in UK and worldwide. The outcomes will be presented in world leading conferences and at JEC Composites in Paris to the pioneering industries and composite markets.
Sectors Aerospace, Defence and Marine,Chemicals,Education,Energy,Healthcare,Manufacturing, including Industrial Biotechology,Security and Diplomacy,Transport

URL http://www.straincomp.com
 
Description Munro Technology Ltd. company sponsored MSc individual projects at the Enhanced Composites and Structures Centre, Cranfield University, under the supervision of Dr. Yazdani Nezhad to develop a unique tailorable multifunctional composite with no interference in structural integrity and no weight penalty, taking outcomes of the STRAINcomp project. The scientific findings of the projects were published in top rank Quartile-1 journals, with open access. The company has now utilised the findings in fast production of structural high performance structures, initially for aircraft's secondary structures as an attempt towards future smart and digitalised aviation. It has led to establishment of a new market for the company. The company has partnered with SAFRAN Seats (formerly Zodiac Aerospace Ltd.) for potential production of new interior components for commercial aircraft. A new idea based on Electromagnetic Volumetric Radiation Driven Microstructural Deformation and Fracture for Self-Tailoring Polymer Nanocomposite Development (EVolMicroSelf) has been developed and submitted to a number of funding organisations. Collaboration with american institutes and industries have been made for such concept/idea.
First Year Of Impact 2018
Sector Aerospace, Defence and Marine,Chemicals,Education,Energy,Environment,Manufacturing, including Industrial Biotechology,Transport
Impact Types Societal,Economic

 
Description EPSRC Doctoral Training Programme
Amount £70,952 (GBP)
Funding ID EPSRC EP/R513027/1 
Organisation Cranfield University 
Sector Academic/University
Country United Kingdom
Start 06/2018 
End 06/2021
 
Description Future Advanced Metrology Hub
Amount £10,456,170 (GBP)
Funding ID EP/P006930/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 03/2017 
End 02/2024
 
Title A Review on Biomedical Application of Polysaccharide-Based Hydrogels with a Focus on Drug Delivery Systems 
Description Underpinning data 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://city.figshare.com/articles/dataset/A_Review_on_Biomedical_Application_of_Polysaccharide-Base...
 
Title A Review on Biomedical Application of Polysaccharide-Based Hydrogels with a Focus on Drug Delivery Systems 
Description Underpinning data 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://city.figshare.com/articles/dataset/A_Review_on_Biomedical_Application_of_Polysaccharide-Base...
 
Title Data supporting "Electromagnetic Field Controlled Domain Wall Displacement for Induced Strain Tailoring in BaTiO3-Epoxy Nanocomposite" 
Description This dataset is comprised of 4 files: 100W_strains, 100W_temperature, 440W_strains, and 440W_temperature.Failure in an epoxy polymer composite material is prone to initiate by the coalescence of microcracks in its polymer matrix. As such, matrix toughening via addition of a second phase as rigid or/and rubber nano/micro-particles is one of the most popular approaches to improve the fracture toughness across multiple scales in a polymer composite, which dissipates fracture energy via deformation mechanisms and microcracks arrest. Few studies have focused on tailorable and variable toughening, so-called 'active toughening', mainly suggesting thermally induced strains which offer slow and irreversible toughening due to polymer's poor thermal conductivity. The research presented in the current article has developed an instantaneous, reversible active toughening composite based upon contact-less introduction of a microscopic compressive extrinsic strain field via remote electromagnetic radiation. Quantification of the extrinsic strain evolving in the composite with the microwave energy has been conducted using in-situ realtime fibre optic sensing. A theoretical constitutive equation correlating the exposure energy to micro-strains has been developed, with its solution validating the experimental data and describing their underlying physics. The research has utilised functionalised dielectric ferroelectric nanomaterials, barium titanate (BaTiO3), as a second phase dispersed in an epoxy matrix, able to introduce microscopic electro-strains to their surrounding rigid epoxy subjected to an external electric field (microwaves, herein), as result of their domain walls dipole displacements. Epoxy Araldite LY1564, a diglycidyl ether of bisphenol A (DGEBA) associated with the curing agent Aradur 3487 were embedded with the BaTiO3 nanoparticles. The silane coupling agent for the nanoparticles' surface functionalisation was 3-glycidoxypropyl trimethoxysilane (3-GPS). Hydrogen peroxide (H2O2, 30%) and acetic acid (C2H4O2, 99.9%) used as functionalisation aids, and the ethanol (C2H6O, 99.9%) used for BaTiO3 dispersion. Firstly, the crystal microstructure of the functionalised nanoparticles and the thermal and dielectric properties of the achieved epoxy composite materials have been characterised. It has been observed that the addition of the dielectric nanoparticles has a slight impact on the curing extent of the epoxy. Secondly, the surface-bonded fibre bragg grating (FBG) sensors have been employed to investigate the real-time variation of strain and temperature in the epoxy composites exposed to microwaves at 2.45 GHz and at different exposure energy. The strains developed due to the in-situ exposure at composite, adhesive and their holding fixture material were evaluated using the FBG. The domain wall induced extrinsic strains were distinguished from the thermally induced strains, and found that the increasing exposure energy has an instantaneously increasing effect on the development of compressive strains. Post-exposure Raman spectra showed no residual field in the composite indicating no remnant strain field examined under microwave powers < 1000 W, thus suggesting a reversible strain introduction mechanism, i.e. the composite retaining its nominal properties post exposure. The dielectric composite development and quantifications presented in this article proposes a novel active toughening technology for high-performance composite applications in numerous sectors. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://cord.cranfield.ac.uk/articles/dataset/Data_supporting_Electromagnetic_Field_Controlled_Domai...
 
Title Data supporting "Electromagnetic Field Controlled Domain Wall Displacement for Induced Strain Tailoring in BaTiO3-Epoxy Nanocomposite" 
Description This dataset is comprised of 4 files: 100W_strains, 100W_temperature, 440W_strains, and 440W_temperature.Failure in an epoxy polymer composite material is prone to initiate by the coalescence of microcracks in its polymer matrix. As such, matrix toughening via addition of a second phase as rigid or/and rubber nano/micro-particles is one of the most popular approaches to improve the fracture toughness across multiple scales in a polymer composite, which dissipates fracture energy via deformation mechanisms and microcracks arrest. Few studies have focused on tailorable and variable toughening, so-called 'active toughening', mainly suggesting thermally induced strains which offer slow and irreversible toughening due to polymer's poor thermal conductivity. The research presented in the current article has developed an instantaneous, reversible active toughening composite based upon contact-less introduction of a microscopic compressive extrinsic strain field via remote electromagnetic radiation. Quantification of the extrinsic strain evolving in the composite with the microwave energy has been conducted using in-situ realtime fibre optic sensing. A theoretical constitutive equation correlating the exposure energy to micro-strains has been developed, with its solution validating the experimental data and describing their underlying physics. The research has utilised functionalised dielectric ferroelectric nanomaterials, barium titanate (BaTiO3), as a second phase dispersed in an epoxy matrix, able to introduce microscopic electro-strains to their surrounding rigid epoxy subjected to an external electric field (microwaves, herein), as result of their domain walls dipole displacements. Epoxy Araldite LY1564, a diglycidyl ether of bisphenol A (DGEBA) associated with the curing agent Aradur 3487 were embedded with the BaTiO3 nanoparticles. The silane coupling agent for the nanoparticles' surface functionalisation was 3-glycidoxypropyl trimethoxysilane (3-GPS). Hydrogen peroxide (H2O2, 30%) and acetic acid (C2H4O2, 99.9%) used as functionalisation aids, and the ethanol (C2H6O, 99.9%) used for BaTiO3 dispersion. Firstly, the crystal microstructure of the functionalised nanoparticles and the thermal and dielectric properties of the achieved epoxy composite materials have been characterised. It has been observed that the addition of the dielectric nanoparticles has a slight impact on the curing extent of the epoxy. Secondly, the surface-bonded fibre bragg grating (FBG) sensors have been employed to investigate the real-time variation of strain and temperature in the epoxy composites exposed to microwaves at 2.45 GHz and at different exposure energy. The strains developed due to the in-situ exposure at composite, adhesive and their holding fixture material were evaluated using the FBG. The domain wall induced extrinsic strains were distinguished from the thermally induced strains, and found that the increasing exposure energy has an instantaneously increasing effect on the development of compressive strains. Post-exposure Raman spectra showed no residual field in the composite indicating no remnant strain field examined under microwave powers < 1000 W, thus suggesting a reversible strain introduction mechanism, i.e. the composite retaining its nominal properties post exposure. The dielectric composite development and quantifications presented in this article proposes a novel active toughening technology for high-performance composite applications in numerous sectors. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://cord.cranfield.ac.uk/articles/dataset/Data_supporting_Electromagnetic_Field_Controlled_Domai...
 
Title Data supporting: 'Electromagnetic Field Controlled Domain Wall Displacement for Induced Strain Tailoring in BaTiO3-Epoxy Nanocomposite' 
Description This dataset is comprised of 4 files: 100W_strains, 100W_temperature, 440W_strains, and 440W_temperature. Failure in an epoxy polymer composite material is prone to initiate by the coalescence of microcracks in its polymer matrix. As such, matrix toughening via addition of a second phase as rigid or/and rubber nano/micro-particles is one of the most popular approaches to improve the fracture toughness across multiple scales in a polymer composite, which dissipates fracture energy via deformation mechanisms and microcracks arrest. Few studies have focused on tailorable and variable toughening, so-called 'active toughening', mainly suggesting thermally induced strains which offer slow and irreversible toughening due to polymer's poor thermal conductivity. The research presented in the current article has developed an instantaneous, reversible active toughening composite based upon contact-less introduction of a microscopic compressive extrinsic strain field via remote electromagnetic radiation. Quantification of the extrinsic strain evolving in the composite with the microwave energy has been conducted using in-situ realtime fibre optic sensing. A theoretical constitutive equation correlating the exposure energy to micro-strains has been developed, with its solution validating the experimental data and describing their underlying physics. The research has utilised functionalised dielectric ferroelectric nanomaterials, barium titanate (BaTiO3), as a second phase dispersed in an epoxy matrix, able to introduce microscopic electro-strains to their surrounding rigid epoxy subjected to an external electric field (microwaves, herein), as result of their domain walls dipole displacements. Epoxy Araldite LY1564, a diglycidyl ether of bisphenol A (DGEBA) associated with the curing agent Aradur 3487 were embedded with the BaTiO3 nanoparticles. The silane coupling agent for the nanoparticles' surface functionalisation was 3-glycidoxypropyl trimethoxysilane (3-GPS). Hydrogen peroxide (H2O2, 30%) and acetic acid (C2H4O2, 99.9%) used as functionalisation aids, and the ethanol (C2H6O, 99.9%) used for BaTiO3 dispersion. Firstly, the crystal microstructure of the functionalised nanoparticles and the thermal and dielectric properties of the achieved epoxy composite materials have been characterised. It has been observed that the addition of the dielectric nanoparticles has a slight impact on the curing extent of the epoxy. Secondly, the surface-bonded fibre bragg grating (FBG) sensors have been employed to investigate the real-time variation of strain and temperature in the epoxy composites exposed to microwaves at 2.45 GHz and at different exposure energy. The strains developed due to the in-situ exposure at composite, adhesive and their holding fixture material were evaluated using the FBG. The domain wall induced extrinsic strains were distinguished from the thermally induced strains, and found that the increasing exposure energy has an instantaneously increasing effect on the development of compressive strains. Post-exposure Raman spectra showed no residual field in the composite indicating no remnant strain field examined under microwave powers < 1000 W, thus suggesting a reversible strain introduction mechanism, i.e. the composite retaining its nominal properties post exposure. The dielectric composite development and quantifications presented in this article proposes a novel active toughening technology for high-performance composite applications in numerous sectors. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://cord.cranfield.ac.uk/articles/dataset/Data_supporting_Electromagnetic_Field_Controlled_Domai...
 
Title Data underpinning the paper: 'Development and testing of carbonaceous tin-based solder achieving unprecedented joint performance Item' 
Description The paper shows that the suitable addition of carbon nanomaterials to a tin-based solder material matrix results in two fold strength of soldered joints. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://cord.cranfield.ac.uk/articles/dataset/Data_underpinning_the_paper_Development_and_testing_of...
 
Title Data underpinning the paper: 'Development and testing of carbonaceous tin-based solder achieving unprecedented joint performance Item' 
Description The paper shows that the suitable addition of carbon nanomaterials to a tin-based solder material matrix results in two fold strength of soldered joints. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
URL https://cord.cranfield.ac.uk/articles/dataset/Data_underpinning_the_paper_Development_and_testing_of...
 
Title Electrical and Magnetic Properties of 3D Printed Integrated Conductive Biodegradable Polymer Nanocomposites for Sustainable Electronics Development 
Description Underpinning data for the journal article on Electrical and Magnetic Properties of 3D Printed Integrated Conductive Biodegradable Polymer Nanocomposites for Sustainable Electronics Development 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://city.figshare.com/articles/dataset/Electrical_and_Magnetic_Properties_of_3D_Printed_Integrat...
 
Title Electrical and Magnetic Properties of 3D Printed Integrated Conductive Biodegradable Polymer Nanocomposites for Sustainable Electronics Development 
Description Underpinning data for the journal article on Electrical and Magnetic Properties of 3D Printed Integrated Conductive Biodegradable Polymer Nanocomposites for Sustainable Electronics Development 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://city.figshare.com/articles/dataset/Electrical_and_Magnetic_Properties_of_3D_Printed_Integrat...
 
Title Shear Driven Deformation and Damage Mechanisms in High-performance Carbon Fibre-reinforced Thermoplastic and Thermoset Composites 
Description The underpinning data related to monolithic and cyclic testing of thermoplastic and thermoset carbon fibre-reinforced polymer composites for description of shear driven deformation and damage mechanisms at micro-scale, related to high-performance aerospace grade structures undergoing high mechanical strains. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://cord.cranfield.ac.uk/articles/dataset/Shear_Driven_Deformation_and_Damage_Mechanisms_in_High...
 
Title Shear Driven Deformation and Damage Mechanisms in High-performance Carbon Fibre-reinforced Thermoplastic and Thermoset Composites 
Description The underpinning data related to monolithic and cyclic testing of thermoplastic and thermoset carbon fibre-reinforced polymer composites for description of shear driven deformation and damage mechanisms at micro-scale, related to high-performance aerospace grade structures undergoing high mechanical strains. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL https://cord.cranfield.ac.uk/articles/dataset/Shear_Driven_Deformation_and_Damage_Mechanisms_in_High...
 
Description University of Manchester 
Organisation University of Manchester
Department Manchester X-ray Imaging Facility
Country United Kingdom 
Sector Academic/University 
PI Contribution We established a collaboration for in-situ X-ray tomography study of dielectric nanocomposites. This is still active and will require several visit to the X-ray facility at Manchester. The outcomes will be published in a number of collaborative journal articles.
Collaborator Contribution The PI was able to create a bi-lateral collaboration with Dr. James Carr and Prof. Phil Withers at the University of Manchester, and successfully secure a beamtime and the Royce Institute grant to use for a week of 3D X-ray computed tomography.
Impact Publication under preparation
Start Year 2018