The Strength of the Lower Mantle

Lead Research Organisation: University of Liverpool
Department Name: Earth, Ocean and Ecological Sciences

Abstract

The internal behaviour of the Earth is controlled by convection hence knowledge of mantle viscosity is critical to our understanding. The viscosity of the mantle on large scales has been measured from post-glacial rebound and geoid inversions. These have shown that there is a significant contrast in viscosity between the upper and lower mantles which has been invoked to explain the varied behaviour of subducting slabs at the 660 km discontinuity. The slabs show a range of behaviour from ponding just above the 660 km discontinuity to penetrating the discontinuity and thickening as they enter the lower mantle.
It is apparent therefore that the size and impermeability of the 660 km viscosity contrast affects the style of mantle convection and cooling rates but the resolution of the geophysical observations is not sufficient for a complete understanding of the fate of material around the 660 km discontinuity. Here we propose to measure the rheology of the minerals and assemblages present in the transition-zone and lower-mantle and so provide the constraints needed for a fuller understanding of the viscosity contrast between the upper and lower mantles.

Planned Impact

Academic users: We will integrate our work into the recently established Paris-UCL Research Exchange (PURE) programme which aims to foster collaboration between scientists working on the deep Earth (both mantle and core) at UCL and at the Institut de Physique du Globe de Paris. Broader engagement with material scientists will be made through the UCL Centre for Materials Research, on which Dobson is a board member.

Training: The project will result in the training of one PDRA and the continued training of the Research Co-I Hunt. The PDRA will be trained in high-pressure/high temperature experimental techniques (mostly Liverpool University), measurement of physical properties and diffraction studies, and will also gain experience working at international large-scale facilities (e.g., NSLS); as a result s/he will be in a position to gain employment in a variety of materials science based occupations. As part of their training, both PDRAs will be required to participate in courses, as part of the staff development programmes at their respective universities, which continues the Robert's Agenda in our institutions.

Industry Dobson will continue his work with the fine-arts industry to develop improved paper registration techniques. One day meetings will be held annually to discuss progress and further developments.

Outreach - There is an existing outreach programme run by UCL Earth Sciences to which the investigators from UCL already contribute; the PDRAs working on this project will be expected to participate in this activity. In addition, we shall our research activity, "Diamonds from Dirt", aimed at key-stage 3 students. Diamonds can be readily grown from any source of carbon; we have already grown diamonds from toast with work-experience placements. We believe that growing diamonds from 'snot' will engage with younger students. While this might seem flippant we genuinely believe it is of vital importance to capture the imaginations of students at as young an age as possible and this should appeal broadly, involving a 'girl's best friend' and, possibly, a young boy's best friend. Nasally secreted mucus is a mixture of water and glycosylated peptides: once dried it has a high concentration of carbon (about 30 mole%) and, after reducing pyrolysis, will readily form diamonds via the standard solvent catalysis route. It will not be possible, for health-and-safety reasons, for key-stage 3 students to attend the synthesis experiments so we propose to make a web-cast of the diamond growing process which we will use in conjunction with school visits to discuss the process and present the grown diamonds. These outreach activities will be performed in collaboration with Dr Andrea Sella (UCL Chemistry) who is an EPSRC senior media fellow and has contacts with a network of primary schools in London, including being a governor of Gilmore Primary School and running several science clubs. We also strongly suspect that a webcast about growing diamonds from snot might be picked up by the news media, allowing us to discuss more serious aspects of high-pressure research and public outreach.

Publications

10 25 50
 
Description The rheology of SiO2 minerals is significantly affected by the transformation from quartz to coesite, with a 4-fold increase in strength, to stishovite, with a 6-fold increase in strength. This is interpreted to be due to changes in Si coordination and material's density and has important implications for the viscosity of the lower mantle. If the effect of Si coordination and density can be applied to bridgmanite, then our results might explain the large increase in viscosity around the 660 km discontinuity.
We studied the kinetics of the reaction of majoritic garnet and ferropericlase to ringwoodite at the 660 km discontinuity. Our results show that a fine-grained intergrowth zone of ringwoodite and garnet forms at the contact between reactant phases. This fine-grained zone is likely to facilitate transition to diffusion creep deformation, resulting in transient weakening and lower viscosity in mantle upwellings just above 660 km, which could result in viscous decoupling between the upper and lower mantle.
At further depths in the Earth, postperovskite is abundant just above the core-mantle boundary (D"). Experimental and modelling outcomes from this grant show that the strength contrast between slip systems in analogue postperovskite is lower than expected, and that therefore anisotropy development by dislocation creep at the D" should be slower than previously thought. An alternative outcome is that anisotropic chemical diffusivity in postperovskite may lead to flow by anisotropic diffusion creep, and result in strong fabric development as well as weakening in the D". These outcomes contribute to explaining both the strong seismic anisotropy and rapid lateral changes in seismic velocities detected just above the core-mantle boundary.
All outcomes above are published in peer reviewed journals.
In addition to the above work, some mantle mineral analogues deformed experimentally under mantle conditions flow by dislocation creep. This process results in local crystallographic alignment but overall the rock fabric is random due to the heterogeneity of deformation. This could explain seismic data showing that the lower mantle is mostly isotropic.
However, new results from neighbourite (the best analogue for bridgmanite) experiments show that, with decreasing grain sizes, there is a transition from dislocation creep to a grain-size-sensitive deformation mechanism (diffusion creep, DisGBS) and weakening. Experimental samples still show they maintain and/or further develop significant crystallographic preferred orientation, even during diffusion creep. Therefore, heterogeneity of the deformation might remain the most likely explanation for an isotropic mantle.
This work is currently being written up for submission in a peer-reviewed journal.
Exploitation Route All findings are or will be published in peer-reviewed journals, in the form of high-profile publications.
Such papers serve for pilot ideas for further studies and new projects.
I addition the mechanical properties of perovskite structures such as those forming Earth's mantle might be on interest to chemists, physicists and engineers who study new materials with the same structure for the development of solid oxide fuel cells and PVs for alternative energy resources.
Sectors Energy,Environment,Other

 
Title Creation of analog mineral for experimental testing 
Description Neighborite, NaMgF3, is a lower pressure analog of bridgmanit, (Mg,Fe)SiO3, the most abundant mineral in the lower mantle and in the Earth. Neighborite is not only a perovskite structure, like bridgmanite, but it also shares its symmetry group Pnma and has been shown to deform plastically by developing similar crystallographic preferred orientation when deformed in compression. Our group synthesized pure neighborite 10 grams at a time by sintering. 
Type Of Material Improvements to research infrastructure 
Year Produced 2017 
Provided To Others? No  
Impact Improved efficiency in generating analog mineral neighborite for deformation tests. 
 
Title Creation of code for stress step deformation tests 
Description A python script was created to estimate 3D grain volumes based on observed 2D grain cross-section areas measured by electron backscatter diffraction (EBSD) in a scanning electron microscope (SEM) using the Johnson-Saltykov method and were posted on Github online. Additional Python scripts for processing mechanical deformation data will soon be added to Github. These scripts include: 1) automatically picking out points of strain rate change and fitting strain rates at different strain steps to find strain-rate-stress relationships, and 2) fitting strain-rate-stress data and grain sizes estimated from Johnson-Saltykov method to a flow law. 
Type Of Material Improvements to research infrastructure 
Year Produced 2018 
Provided To Others? Yes  
Impact More accurate and efficient analysis of experimental deformation data for use in deriving a flow law. 
URL https://github.com/pkaercher/Johnson-Saltykov-function
 
Title Development of polishing technique two-phase, hydrophilic samples for detailed microstructural and EBSD analysis 
Description Halite is soft and hydrophilic, while neighborite is harder, making two-phase samples challenging to prepare for EBSD. Polishing was done by hand in mineral oil, first on grit paper of successive grit sizes: P1200, P2400, P4000, followed by 1 µm, then 0.3 µm colloidal silica on a ChemoMet pad. The sample was cleaned with soft tissue and wiped with hexane between each polish. A final polish is done in a Precision Ion Polishing System (PIPS). Halite indexes very well, and neighborite indexes moderately well. Detailed quantified analysis can be done for halite, and general grain shapes of neighborite can be seen. 
Type Of Material Technology assay or reagent 
Provided To Others? No  
Impact We are able to look at the deformation microstructures of lower mantle two-phase analogs to better understand by which mechanisms they deform. 
 
Title Code for analysis of experimental deformation data 
Description A python script was created to estimate 3D grain volumes based on observed 2D grain cross-section areas measured by electron backscatter diffraction (EBSD) in a scanning electron microscope (SEM) using the Johnson-Saltykov method and were posted on Github online. Additional Python scripts for processing mechanical deformation data will soon be added to Github. These scripts include: 1) automatically picking out points of strain rate change and fitting strain rates at different strain steps to find strain-rate-stress relationships, and 2) fitting strain-rate-stress data and grain sizes estimated from Johnson-Saltykov method to a flow law. 
Type Of Material Data analysis technique 
Year Produced 2018 
Provided To Others? Yes  
Impact More accurate and efficient analysis of experimental deformation data for use in deriving a flow law. 
URL https://github.com/pkaercher/Johnson-Saltykov-function
 
Title Deformation results and microstructural analysis from 20 compression experiments and microstructural analysis on bridgmanite analog, neighborite 
Description 20 compression experiments were performed in a Nimonic rig on bridgmanite analog, neighborite, at 200 MPa confining pressure, 500-700 deg C, and 25-175 MPa stress. Strain rates were precisely recorded to quantify the strength of neighborite. In addition microstrucutral data, roughly 100 scans and images, were collected on undeformed and deformed samples using electronic backscatter diffraction (EBSD) in a scanning electron microscope (SEM) in order to understand by which mechanisms neighborite deforms. 
Type Of Material Database/Collection of data 
Year Produced 2017 
Provided To Others? No  
Impact The mechanical and microstructural data described above has been used to derive a flow law for neighborite. Understanding how analogs of bridgmanite (for which precise deformation experiments are nearly impossible given that its stability field lies above 25 GPa and 2000K) such as neighborite deform and knowing their strength at different conditions can provide insight into how bridgmanite itself deforms and thus lead to better estimates of strength in the lower mantle. 
 
Description Attended EBSD conference in 2016 and presented poster 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Attended the EBSD 2016 workshop to learn more about EBSD techniques and presented a poster titled "" to get feedback on research. Here we made contact with another researchers who we collaborated with.
Year(s) Of Engagement Activity 2016
URL https://www.rms.org.uk/discover-engage/event-calendar/ebsd-2016.html
 
Description Presented at AGU Fall Meeting 2015: "Novel Techniques for Examining Detailed Microstructure of Two-phase Lower Mantle Mineral Analogs with SEM and EBSD" 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Presented a poster at the AGU Fall Meeting 2015 titled "Novel Techniques for Examining Detailed Microstructure of Two-phase Lower Mantle Mineral Analogs with SEM and EBSD" to present methods we had developed and exchange ideas with other researchers.
Year(s) Of Engagement Activity 2015
URL https://agu.confex.com/agu/fm15/meetingapp.cgi/Paper/64686
 
Description Presented at AGU Fall Meeting 2016: "Creep of the bridgmanite analog neighborite (NaMgF3) and implications for viscous flow in the lower mantle" 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Attended AGU Fall Meeting 2016 and presented a poster titled "Creep of the bridgmanite analog neighborite (NaMgF3) and implications for viscous flow in the lower mantle" to share preliminary findings and get feedback.
Year(s) Of Engagement Activity 2016
URL https://agu.confex.com/agu/fm16/meetingapp.cgi/Paper/159588
 
Description Presented at EGU General Assembly 2016: "Tackling pseudosymmetry problems in EBSD analyses of perovskite" 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Presented a poster titled "Tackling pseudosymmetry problems in EBSD analyses of perovskite" to exchange ideas with other researchers on best methods.
Year(s) Of Engagement Activity 2016
URL https://meetingorganizer.copernicus.org/EGU2016/session/20583
 
Description Presented poster at EGU General Assembly 2016: "Detailed microstructure of two-phase lower mantle mineral analogs from SEM and EBSD" 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Presented a poster at the EGU General Assemby 2015 titled "Detailed microstructure of two-phase lower mantle mineral analogs from SEM and EBSD" with preliminary results to get feedback.
Year(s) Of Engagement Activity 2016
URL https://meetingorganizer.copernicus.org/EGU2016/session/20583