From arc magmas to ores (FAMOS): A mineral systems approach
Lead Research Organisation:
University of Bristol
Department Name: Earth Sciences
Abstract
Society is dependent on a reliable supply of metals and minerals for economic growth, improved standards of living, and development of infrastructure. Population growth means that even with increased recycling and resource efficiency, new mineral deposits still need to be discovered. The efficient exploration for, and discovery of, new resources requires new concepts and new tools.
The Mineral Systems approach to exploration considers ore deposits on a lithospheric scale, in terms of the "ingredients", processes and environments that favour their formation. This approach amounts to a "source-pathway-trap" model, with an increased emphasis on predictive capacity, rather than just feature recognition. Historically, much research has focused on the trap, and characterisation of the ore deposits themselves; here we aim to focus deeper in the system by integrating ore deposit formation with concepts of magmatism that arise from igneous petrology and volcanology. Therein lies a challenge because extant models for porphyry systems are increasingly at odds with magmatic models for crustal construction and arc volcanism. Rather than seeing magmatic systems in terms of large, liquid-rich magma chambers, emerging petrological models for crustal magmatism are turning instead to crystal-dominated, volatile-bearing "mushy" systems that traverse most or all of the crust. The dynamics of such systems have important consequences not just for arc magmatism, but also for the chemistry of the volatiles that are exsolved. These same volatiles fuel mineralisation and this is the synergy that we aim to exploit by assembling a multidisciplinary team of researchers from economic geology, igneous and metamorphic petrology, volcanology, geochemistry, numerical modelling and fluid dynamics. Our team embraces almost everyone currently engaged in porphyry mineralisation research in the UK and capitalises on strong existing links between UK ROs and the mining industry, many of who are Project Partners.
The research will involve analysis of minerals from a wide variety of mineralised and barren settings using a wealth of modern analytical tools that enable determination of an extensive suite of trace elements and isotope tracers. As each trace element responds to magmatic processes in subtly different ways due to the affinity of different elements for different phases (minerals, melts and fluids), so the multi-element approach affords many advantages over conventional proxies in which the full potential of the Periodic Table is not exploited. The analysis of natural systems will be underpinned by high pressure and temperature experiments to establish the phase relationships of ascending arc magmas and the partition coefficients that capture the affinities of elements for certain phases. As fluid accumulation and migration is an essential, but poorly understood, final step in ore deposit formation, we will develop, in tandem with the geochemistry, numerical models for fluid-bearing mushy systems. Finally, consideration will be given to critical metals that are passengers through the main ore-forming processes, but constitute important, often under-explored, by-products of porphyry mineralisation.
The research proposed has a strong element of blue skies investigation, but a particular focus on outcomes that will benefit industry through improved exploration tools. Thus the project bridges the divide between academic and applied research in a way that is not normally possible through industry-funded projects. This bridging activity lies at the heart of the Highlight Topic call, specifically through the integration of new advances in the study of mineral systems, igneous petrology and geochemistry, with a view to identifying conditions that can act as pathfinders for new targets. A key outcome will be a range of trace element proxies that will enable the mining industry to establish the potential fertility of a magmatic arc on local to regional scales.
The Mineral Systems approach to exploration considers ore deposits on a lithospheric scale, in terms of the "ingredients", processes and environments that favour their formation. This approach amounts to a "source-pathway-trap" model, with an increased emphasis on predictive capacity, rather than just feature recognition. Historically, much research has focused on the trap, and characterisation of the ore deposits themselves; here we aim to focus deeper in the system by integrating ore deposit formation with concepts of magmatism that arise from igneous petrology and volcanology. Therein lies a challenge because extant models for porphyry systems are increasingly at odds with magmatic models for crustal construction and arc volcanism. Rather than seeing magmatic systems in terms of large, liquid-rich magma chambers, emerging petrological models for crustal magmatism are turning instead to crystal-dominated, volatile-bearing "mushy" systems that traverse most or all of the crust. The dynamics of such systems have important consequences not just for arc magmatism, but also for the chemistry of the volatiles that are exsolved. These same volatiles fuel mineralisation and this is the synergy that we aim to exploit by assembling a multidisciplinary team of researchers from economic geology, igneous and metamorphic petrology, volcanology, geochemistry, numerical modelling and fluid dynamics. Our team embraces almost everyone currently engaged in porphyry mineralisation research in the UK and capitalises on strong existing links between UK ROs and the mining industry, many of who are Project Partners.
The research will involve analysis of minerals from a wide variety of mineralised and barren settings using a wealth of modern analytical tools that enable determination of an extensive suite of trace elements and isotope tracers. As each trace element responds to magmatic processes in subtly different ways due to the affinity of different elements for different phases (minerals, melts and fluids), so the multi-element approach affords many advantages over conventional proxies in which the full potential of the Periodic Table is not exploited. The analysis of natural systems will be underpinned by high pressure and temperature experiments to establish the phase relationships of ascending arc magmas and the partition coefficients that capture the affinities of elements for certain phases. As fluid accumulation and migration is an essential, but poorly understood, final step in ore deposit formation, we will develop, in tandem with the geochemistry, numerical models for fluid-bearing mushy systems. Finally, consideration will be given to critical metals that are passengers through the main ore-forming processes, but constitute important, often under-explored, by-products of porphyry mineralisation.
The research proposed has a strong element of blue skies investigation, but a particular focus on outcomes that will benefit industry through improved exploration tools. Thus the project bridges the divide between academic and applied research in a way that is not normally possible through industry-funded projects. This bridging activity lies at the heart of the Highlight Topic call, specifically through the integration of new advances in the study of mineral systems, igneous petrology and geochemistry, with a view to identifying conditions that can act as pathfinders for new targets. A key outcome will be a range of trace element proxies that will enable the mining industry to establish the potential fertility of a magmatic arc on local to regional scales.
Planned Impact
We have taken an "embedded impact" approach with FAMOS. Stakeholders and beneficiaries have been involved with the development of the project from its initiation (including the initial Highlight Topic suggestion). The scientific content of the proposal was developed in discussion with representatives from industry, and the final consortium has assembled an Advisory Board that includes industry representatives so as to maintain two-way knowledge exchange and ensure development of impact. We have also engaged an international set of project partners (PP) who will extend the reach of our impact (see letters of support). The embedded impact will be delivered through various activities to support outreach, engagement and dissemination.
The key impact goal for FAMOS is to improve discovery rates of porphyry deposits by aiding exploration under cover, influencing decision making in the exploration process, reducing exploration risk and reducing the environmental impacts of drilling and associated disruptive fieldwork through more efficient prospectivity assessment.
There are four impact objectives within FAMOS:
1) A revised Mineral Systems model of porphyry deposit formation. This will lead to improved targeting at regional and igneous complex scales and better inputs to national strategies on mineral resources. Beneficiaries include PRIVATE SECTOR COMPANIES involved in mining, exploration and consultancy (e.g. PPs Anglo American, Rio Tinto, BHPBilliton, Freeport McMoRan), and NATIONAL AGENCIES charged with encouraging exploration and developing strategic resources (e.g. BGS and PP USGS).
2) New proxies for porphyry fertility. This will provide low-cost tools and approaches that will support improved decision-making during exploration. By using multiple proxies within a single sample, more data-rich exploration is possible, and in turn less sampling is required and less environmental impact is caused. Beneficiaries will include PRIVATE SECTOR COMPANIES involved in exploration, consultancy, and the provision of data and analytical equipment to industry (i.e. service companies, e.g. see PPs Olympus, Zeiss and SRK ES letters of support).
3) E-tech elements in porphyries. We will generate vital data for better global and national e-tech resource estimation. This facilitates improved targeting for specific e-techs during exploration, and improved metallurgical characterisation of them. Beneficiaries will be GOVERNMENT AGENCIES who advise on resource strategy (e.g. BGS, PP USGS), and POLICY MAKERS IN GOVERNMENT planning future clean energy strategies. PRIVATE SECTOR COMPANIES exploring for resources (see PP Anglo American letter of support) and end-users of e-techs will benefit through improved strategic knowledge of future supplies and the WIDER PUBLIC will gain through support of sustainable environmental technologies for a low-carbon society.
4) Outreach, education and training. We have planned activities to increase public understanding of resource issues (discovery, depletion, environmental and social impacts, the 'e-tech' concept), particularly through NHM outreach, and activities to encourage the uptake of the new model and proxies with professional geoscientists through training workshops, short courses and engagement at high profile conferences. Beneficiaries include the WIDER PUBLIC, PRIVATE SECTOR COMPANIES as publicly traded bodies and employers of skilled professionals and PROFESSIONAL BODIES such as the IOM3 and Mineral Deposits Studies Group (see letter of support) who support training and professional development for their members.
The key impact goal for FAMOS is to improve discovery rates of porphyry deposits by aiding exploration under cover, influencing decision making in the exploration process, reducing exploration risk and reducing the environmental impacts of drilling and associated disruptive fieldwork through more efficient prospectivity assessment.
There are four impact objectives within FAMOS:
1) A revised Mineral Systems model of porphyry deposit formation. This will lead to improved targeting at regional and igneous complex scales and better inputs to national strategies on mineral resources. Beneficiaries include PRIVATE SECTOR COMPANIES involved in mining, exploration and consultancy (e.g. PPs Anglo American, Rio Tinto, BHPBilliton, Freeport McMoRan), and NATIONAL AGENCIES charged with encouraging exploration and developing strategic resources (e.g. BGS and PP USGS).
2) New proxies for porphyry fertility. This will provide low-cost tools and approaches that will support improved decision-making during exploration. By using multiple proxies within a single sample, more data-rich exploration is possible, and in turn less sampling is required and less environmental impact is caused. Beneficiaries will include PRIVATE SECTOR COMPANIES involved in exploration, consultancy, and the provision of data and analytical equipment to industry (i.e. service companies, e.g. see PPs Olympus, Zeiss and SRK ES letters of support).
3) E-tech elements in porphyries. We will generate vital data for better global and national e-tech resource estimation. This facilitates improved targeting for specific e-techs during exploration, and improved metallurgical characterisation of them. Beneficiaries will be GOVERNMENT AGENCIES who advise on resource strategy (e.g. BGS, PP USGS), and POLICY MAKERS IN GOVERNMENT planning future clean energy strategies. PRIVATE SECTOR COMPANIES exploring for resources (see PP Anglo American letter of support) and end-users of e-techs will benefit through improved strategic knowledge of future supplies and the WIDER PUBLIC will gain through support of sustainable environmental technologies for a low-carbon society.
4) Outreach, education and training. We have planned activities to increase public understanding of resource issues (discovery, depletion, environmental and social impacts, the 'e-tech' concept), particularly through NHM outreach, and activities to encourage the uptake of the new model and proxies with professional geoscientists through training workshops, short courses and engagement at high profile conferences. Beneficiaries include the WIDER PUBLIC, PRIVATE SECTOR COMPANIES as publicly traded bodies and employers of skilled professionals and PROFESSIONAL BODIES such as the IOM3 and Mineral Deposits Studies Group (see letter of support) who support training and professional development for their members.
Organisations
Publications

Afanasyev A
(2018)
Formation of magmatic brine lenses via focussed fluid-flow beneath volcanoes
in Earth and Planetary Science Letters

Blundy J
(2020)
Effect of redox on Fe-Mg-Mn exchange between olivine and melt and an oxybarometer for basalts
in Contributions to Mineralogy and Petrology


Carter L
(2022)
Textural indicators of mineralisation potential in porphyry magmatic systems - A framework from the archetypal Yerington district, Nevada
in Ore Geology Reviews

Carter L
(2022)
A rapid change in magma plumbing taps porphyry copper deposit-forming magmas
in Scientific Reports

Carter L
(2021)
Crystal mush dykes as conduits for mineralising fluids in the Yerington porphyry copper district, Nevada
in Communications Earth & Environment

Hogg O
(2023)
Water-rich magmas optimise volcanic chalcophile element outgassing fluxes
in Earth and Planetary Science Letters

Hutchinson M
(2023)
Trace element partitioning between anhydrite, sulfate melt, and silicate melt
in American Mineralogist

Leuthold J
(2023)
Trace element partitioning in basaltic systems as a function of oxygen fugacity
in Contributions to Mineralogy and Petrology

McCarthy A
(2020)
Taking the pulse of volcanic eruptions using plagioclase glomerocrysts
in Earth and Planetary Science Letters
Title | Megalith |
Description | We worked with Bristol-based theatre-maker Tom Bailey and his company Mechanimal to create a piece of theatre around humankind's complex and longstanding relationship with mining, specifically copper. The resulting piece of theatre, Megalith, was completed in 2022 and played to audiences at the Edinburgh Fringe Festival, Oxford Ideas Festival and international festivals in Montenegro and Slovenia. |
Type Of Art | Performance (Music, Dance, Drama, etc) |
Year Produced | 2022 |
Impact | Brought awareness of the importance and copper mining to audiences not usually exposed to the related issues. |
Description | A case study of the Yerinton (USA) magmatic-porphyry ore system showed that the magmas in the upper parts of the system (< 8 km) underwent a major and rapid change in chemistry over a period of < 200 kyrs that is coincident with the initiation of ore formation. This shift is linked to extraction of magma from mid-crustal reservoirs to extraction from greater (~ 30 km) depths. Detailed studies of field relations and mineral thermometry show that textures such as massive silica bodies, pegmatitic (very coarse-grained) pods, cavities and quartiz veins can record the timing and location of the magmatic-hydrothermal transition and ore-formation. This research provides a textural framework for exploration geologists to assess the likely spatial and temporal architecture of porphyry mineralisation at the district-prospect scale before employing more invasive and expensive techniques. We have explored the phase relationships of water-saturated high-alumina basalt of the type commonly assumed to drive the formation of porphyry-forming systems in the deep crust. This conclusion is based on the trace element signature of the porphyry-forming magmas, notably elevated Sr/Y ratio, which is considered indicative of plagioclase suppression. We find that, even under water-saturation, plagioclase is present at low melt fractions required to generate silicic porphyry dykes. Thus, elevated Sr/Y cannot be ascribed solely to the very wet magmas. Instead, we propose that percolative reactions in the deep crustal mush play an important role in generating the observed signatures. Percolating hydrous melts will dissolve plagioclase and precipitate amphibole thereby generating the observed signatures. Percolative reactive flow is an important process in numerical models of deep hot zone processes. Chloride is the most important ligand species in natural hydrous fluids and so is key to understanding how metals are transported and concentrated into porphyry ore deposits. We have used novel experimental techniques to study chlorine solubility in melt at pressures of 0.5 to 2 GPa and variable redox state to explore controls on incorporation of chlorine into silicate melts. We have shown that chlorine in the gas (Cl2) dissolves as two singly-charged Cl anions replacing oxygen in the melt. The solubility is sensitive to melt composition and, at constant chlorine fugacity, decreases with increasing silica content. We have developed an online calculator for chlorine solubility as a function of pressure, temperature, redox state and melt composition. This model can be used to determine the Cl content of fluids exsolved from magmas with implications for metal transport. Numerical simulations based on three-dimensional X-ray images of natural samples show that how readily silicate melt and fluids percolate through networks of crystals depends on the abundance and size of the crystals, with relatively little effect from the crystal shape. Analogue laboratory experiments show that the strength of crystals frameworks affects how readily volatile phases migrate through crystal mushes and the extent to which bubble growth aids segregation of melt-rich layers. Other laboratory experiments studying larger-scale processes show that stability of melt-rich lenses in hot zones depend strongly on the width of the lens and the viscosity of the overlying mush. All of these results inform large-scale numerical models such as that developed at Imperial College as part of FAMOS. Despite showing favourable geology, there are no known porphyry-type ore deposits in Japan. It therefore provides an ideal porphyry-"barren" case area on which to test a new discriminator for porphyry-"fertile" calc-alkaline systems based on the mineral plagioglase. Of the relevant convergent margin data in the existing GEOROC database, 91% of the Japan data fall in the "barren" field, compared to 73% for equivalent data worldwide. "Fertile" signatures in parts of Kyushu and central Honshu should be further investigated, as well as areas where there are systems with elevated whole-rock Sr/Y compositions but for which there are little or no plagioclase data. The anomalously poor potential for porphyry deposits in Japan is uncertain but could relate to tectonic factors or the nature of the magmatic source or because melt water content in many of the magmatic systems was too low, as suggested from low average excess Al in plagioclase. |
Exploitation Route | Our findings form the basis for refined ore exploration tools |
Sectors | Chemicals |
Description | The improved understanding of the magmatic architecture of ore-forming systems associated with subduction zones is being used by mining companies to refine their exploration strategy |
First Year Of Impact | 2018 |
Sector | Chemicals |
Impact Types | Economic |
Description | 1. Hotter and deeper geothermal - a novel strategy for Net Zero |
Amount | $135,894 (NZD) |
Funding ID | 2023-2025 ILF-GNS2201 |
Organisation | Royal Society of New Zealand |
Sector | Charity/Non Profit |
Country | New Zealand |
Start |
Description | Enabling the energy transition on the island of Montserrat and the wider Caribbean |
Amount | £252,431 (GBP) |
Funding ID | KCD00150 - DG01 |
Organisation | Official Development Assistance |
Sector | Public |
Country | United Kingdom |
Start |
Description | Recovery of metals from geothermal brines |
Amount | £934,132 (GBP) |
Funding ID | EP/Y009568/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 04/2024 |
End | 04/2028 |
Description | Reframing Metal Mining for a Sustainable Energy Transition |
Amount | £999,963 (GBP) |
Organisation | University of Oxford |
Department | Oxford Martin School |
Sector | Academic/University |
Country | United Kingdom |
Start |