Fate and Management of Emerging Contaminants (FAME)

Lead Research Organisation: University of Exeter
Department Name: Engineering

Abstract

Owing to on-going demographic shifts, urbanisation and changing life styles supported by rapid industrialisation, pollution by so-called emerging contaminants (ECs) is an emerging environmental and public health concern in India, the UK and globally. Pharmaceuticals, personal-care products, pesticides & industrial compounds, are collectively known as ECs. They lead to, among other effects, increasing antibiotic resistance and endocrine disruption in aquatic animals and possibly humans. Conventional wastewater treatment plants (WTPs) have a mixed performance in dealing with such contaminants and might even be adversely affected by the ECs in treating more conventional pollutants. There is also evidence that WTPs can act as reservoirs of antibiotic resistant pathogenic bacteria. Due to limited availability of data, the fate of ECs in the environment and wastewater treatment remains under-investigated, limiting our ability to provide targeted cost effective treatment.

The research aims to study the sources and fate of ECs and their interactions in receiving waters and WTPs and develop novel and sustainable management strategies to improve water quality. In the project, two rivers will be monitored: the Yamuna in the north (in the most polluted stretch, contributing to 70% of Delhi's water supply needs) & the Cauvery in the south (the most abstracted river in India). Investigations will also be made on the fate of ECs during wastewater and sludge treatment line at 10 WTPs in India and compared with selected plants in the UK. Investigations will also include, the fate of ECs during the treatment and use of bio-solids. The work will help to develop evidence based wastewater discharge standards and guidance for safe use of contaminated sludge. We will also look to develop novel, cost effective and fit for purpose solutions for the treatment of ECs in urban and rural communities. Several approaches will be investigated including zero/limited energy consuming natural treatment systems configurations; and space saving systems based on the development and novel application of a new generation of adsorbents; energy efficient membranes and chemicals free treatment. The work will help the development of design and operation guidance for optimal treatment systems requiring limited input from O&M staff. Finally, we intend to develop a novel decision support system to automatically generate and identify sustainable treatment strategies as a function of user defined constraints and contexts. This will serve as a negotiation tool to visualise the impact of different stakeholders objectives and preferences. The tool will be trialled with a range of end users in India and UK.

Planned Impact

The targeted groups are end user communities (e.g. water/wastewater technology developer and operators, environmental regulators, public) and scientific communities (researchers and academics). While initial impact generation focuses on India and the UK, FAME has enormous potential for global impact. Specific impacts include.

Economic: FAME will support anticipated industrial growth without compromising environmental/water quality regulations. The Indian and global market for products responsible for ECs emission and associated water pollution continues to grow enormously. For example, India loses INR 366 billion per year due to water pollution triggered health issues. FAME treatment solutions will support the wastewater industry and government to minimise this ever increasing economic loss. Effective policy making requires consultation with various stakeholders and consensus building. With our open access DSS application in the 29 Indian states and union territories via CPCB, the identification of context-specific sustainable solutions and technology investment/financing decisions will become faster. This will support the treatment of currently untreated effluents (>40 million m3/day). Innovations in advanced oxidation process through chemical free pulsed power technology (AOP-PPT) could result in user friendly plant operation by a less skilled labour force (a desirable feature in India) and could lead to several industrial applications. AOP-PPT can support this level of economic activity without compromising water quality regulations. Novel graphene based adsorbents, able to reduce post treatment infrastructure construction and operation and maintenance costs, will offer considerable potential for water production for potable and industrial applications. It can support the adsorbent manufacturers and suppliers markets globally.

Environmental and societal: Through monitoring the Yamuna River and the Cauvery River and wastewater treatment plants, FAME's evidence base will directly influence the development and updating of regulators' standards, thus contributing to the protection of the aquatic environment and improved human wellbeing. India will have 7 megacities by 2030, meaning further densification of heavily congested urban areas and need for decentralised systems. The novel compact solutions can support sustainable locally and facilitate community scale greywater reuse. Graphene based adsorbents could be used for cost-effective removal of other pollutants (e.g. arsenic, fluoride and nitrates), frequently detected in groundwater in India, Bangladesh, China, the USA (i.e. globally), from drinking water in an energy efficient manner. FAME specifically targets sustainable development and poverty alleviation as project goals. The nature of issues for many ODA List developing countries is similar to the challenges in India. Research outputs will support international development policies (e.g. UK Aid Strategy and UN Sustainable Development Goals - Target 6 and its sub targets).

People: The junior members of the FAME team (i.e. 5 PhD students and 6 PDRAs) will develop important research skills for advanced water quality analysis techniques, multi-objective optimisation, new materials synthesis, technology miniaturisation and community engagement, building research capability and the workforce within the UK and India. The 16 project partners will have opportunities to exchange, access, influence, implement and co-create knowledge and cross fertilise new ideas.

Publications

10 25 50

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Delhiraja K (2020) Characterization of segregated greywater from Indian households-part B: emerging contaminants. in Environmental monitoring and assessment

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Dubey M (2021) Occurrence, fate, and persistence of emerging micropollutants in sewage sludge treatment. in Environmental pollution (Barking, Essex : 1987)

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Manthiram Karthik R (2021) Sorption of pharmaceutical compounds and nutrients by various porous low cost adsorbents in Journal of Environmental Chemical Engineering

 
Description 1. Successful synthesis of graphene based materials and lab investigations indicated that porous graphene offers a good potential to treat selected emerging contaminants. This is leading towards further exploration of green synthesis routes for graphene based materials for compact tertiary treatments development for the removal of complex emerging contaminants. The developed solutions can act as potential decentralised treatment solutions for densely populated urban India and similar contexts in developing countries. A pilot treatment system has been provided by Exeter University to IIT Madras for future research and education activities and further testing.

2. The water quality analysis of the two major rivers in India and sewage treatment plants near Delhi is helping to consolidate an evidence base that can potentially inform / influence water quality standards formulation for Central Pollution Control Board in India.

3. The decision support tool has been completed and has been embedded with an improved enumeration algorithm to facilitate efficient treatment solutions automated search in response to a range of developing countries contexts including India. The uptake of the developed tool by a range of stakeholders can facilitate dialogue and view trade off to optimise sustainability indicators and treatment technology selection. The tool has been upgraded based on stakeholders feedback from India and now is available on: https://fame-dst.com/
Exploitation Route The research has produced critical science for the development of treatment solutions for emerging contaminants. The critical know how is published via +17 open access publications. Additionally, a decision support tool has been developed together with its user manual. Pilot scale systems for lab and field based explorations are now available to pursue further research and are available as example demonstrations for enhanced user uptake.
Sectors Chemicals,Education,Environment,Pharmaceuticals and Medical Biotechnology

 
Description The evidence base developed on water quality monitoring of the two major rivers in India (Yamuna and Cauvery) and the unit process level treatment performance of the 10 sewage treatment works, near Delhi, is informing the deliberations of the pollution control committees for setting up discharge consents for EC thresholds in India.
First Year Of Impact 2021
Sector Chemicals,Environment
Impact Types Policy & public services

 
Description Evidence base on the prevalence of Emerging contaminants in Indian waters, conventional and innovative treatment solutions and formulation of national/regional water quality standards for India
Geographic Reach Asia 
Policy Influence Type Participation in a guidance/advisory committee
Impact One of the core research team members, i.e. Prof Ligy Philip from IIT- Madras, sits on a national water quality standards and pollution mitigation committee in India. Via Ligy the project developed knowledge base and generated data is fed into committee deliberations and in the long run leading towards new water quality standards on contaminants (i.e. improved regulatory environment) and the project developed treatment solutions will contribute towards improved wastewater treatment for pharmaceutical industries and therefore improved environmental sustainability...all leading towards improved health and enhanced productivity delivering economic impacts. The evidence can be tracked in the publications section.
 
Title Decision support tool for the optimal selection of wastewater treatment technologies for Indian context 
Description A novel decision support tool with flexible architecture to accommodate contexts of DAC list (developing countries) has been developed for the optioneering of wastewater treatment solutions to short list potential solutions and negotiate sustainability trade-offs and conflicting goals of different stakeholders. The tool can help to identify potential solutions keeping in view developing countries contexts and constraints ( e.g. limited availability resources, skilled labour, land, continuous supply of energy, input water quality and required water quality standards). An end user manual has also been developed. The tool has benefitted from the end user feedback from a range of stakeholders in India. This feedback has been incorporated in the tool. The tool is available as an open access tool on: https://fame-dst.com/ 
Type Of Material Improvements to research infrastructure 
Year Produced 2022 
Provided To Others? Yes  
Impact Further tool testing is being pursued with Indian collaborators. The tool application will help achieve water quality improvements supporting cleaner environment and associated health and economic benefits in India and countries with similar context. We plan to track the tool uptake. 
URL http://www.fame-dst.com/
 
Title Decision support tool for the optimal selection of wastewater treatment solutions 
Description As described in the tools section. 
Type Of Material Computer model/algorithm 
Year Produced 2020 
Provided To Others? Yes  
Impact please see the section on tools. 
 
Title Performance evaluation of porous graphene as filter media for the removal of pharmaceutical/emerging contaminants from water and wastewater 
Description Supplementary file for an article submitted to MDPI Nanomaterials. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
Impact Leads to the development of a packaged tertiary treatment for trials in India. 
URL https://zenodo.org/record/4386515
 
Description Research Collaboration on Water Quality Management for India 
Organisation Central Pollution Control Board
Department Delhi Pollution Control Committee (DPCC)
Country India 
Sector Public 
PI Contribution University of Exeter - Overall lead plus development of compact graphene based material treatment solutions for emerging contaminants + development of a decision support tool for the selection of optimal wastewater treatment technology for urban and rural India.
Collaborator Contribution 1. IIT - Madras (India) - Emerging contaminants (EC) monitoring for Cauvery River (South India) and development of green/extensive and compact wastewater treatments for rural and urban India. 2. IIT - Roorkee (India) - EC monitoring for Yamuna River (North India), and an assessment of 10 sewage treatment works near New Delhi and investigation of sludge treatment options for the management of ECs plus investigations on ECs prevalence in groundwater. 3. UCL (UK) - Dissemination and end user engagement 4. South West Water - Providing access to CIP (Contaminants Investigation Programme) Data and its treatment facilities operation data 5. ELIQUO HYDROK - Providing access to its HYSAF decentralised treatment facility in India. 6. Delhi and Central Pollution Control Boards (India) - India Environmental regulators providing access to 10 sewage treatment plants for ECs monitoring and facilitation with fieldwork.
Impact + 17 papers have been published by the academic partners and details are in the publications section. Pilot scale graphene based treatment system supplied to India for trial and further research purpose to IIT Madras by Exeter University. A novel decision support too has been made available, by Exeter University, as an online open access tool for the selection of sustainable treatment solutions. The tool is available here: https://fame-dst.com/ IIT-Madras also developed novel compact treatment reactor plus green solutions for ECs removal.
Start Year 2018
 
Description Research Collaboration on Water Quality Management for India 
Organisation Central Pollution Control Board
Country India 
Sector Public 
PI Contribution University of Exeter - Overall lead plus development of compact graphene based material treatment solutions for emerging contaminants + development of a decision support tool for the selection of optimal wastewater treatment technology for urban and rural India.
Collaborator Contribution 1. IIT - Madras (India) - Emerging contaminants (EC) monitoring for Cauvery River (South India) and development of green/extensive and compact wastewater treatments for rural and urban India. 2. IIT - Roorkee (India) - EC monitoring for Yamuna River (North India), and an assessment of 10 sewage treatment works near New Delhi and investigation of sludge treatment options for the management of ECs plus investigations on ECs prevalence in groundwater. 3. UCL (UK) - Dissemination and end user engagement 4. South West Water - Providing access to CIP (Contaminants Investigation Programme) Data and its treatment facilities operation data 5. ELIQUO HYDROK - Providing access to its HYSAF decentralised treatment facility in India. 6. Delhi and Central Pollution Control Boards (India) - India Environmental regulators providing access to 10 sewage treatment plants for ECs monitoring and facilitation with fieldwork.
Impact + 17 papers have been published by the academic partners and details are in the publications section. Pilot scale graphene based treatment system supplied to India for trial and further research purpose to IIT Madras by Exeter University. A novel decision support too has been made available, by Exeter University, as an online open access tool for the selection of sustainable treatment solutions. The tool is available here: https://fame-dst.com/ IIT-Madras also developed novel compact treatment reactor plus green solutions for ECs removal.
Start Year 2018
 
Description Research Collaboration on Water Quality Management for India 
Organisation ELIQUO HYDROK
Country United Kingdom 
Sector Private 
PI Contribution University of Exeter - Overall lead plus development of compact graphene based material treatment solutions for emerging contaminants + development of a decision support tool for the selection of optimal wastewater treatment technology for urban and rural India.
Collaborator Contribution 1. IIT - Madras (India) - Emerging contaminants (EC) monitoring for Cauvery River (South India) and development of green/extensive and compact wastewater treatments for rural and urban India. 2. IIT - Roorkee (India) - EC monitoring for Yamuna River (North India), and an assessment of 10 sewage treatment works near New Delhi and investigation of sludge treatment options for the management of ECs plus investigations on ECs prevalence in groundwater. 3. UCL (UK) - Dissemination and end user engagement 4. South West Water - Providing access to CIP (Contaminants Investigation Programme) Data and its treatment facilities operation data 5. ELIQUO HYDROK - Providing access to its HYSAF decentralised treatment facility in India. 6. Delhi and Central Pollution Control Boards (India) - India Environmental regulators providing access to 10 sewage treatment plants for ECs monitoring and facilitation with fieldwork.
Impact + 17 papers have been published by the academic partners and details are in the publications section. Pilot scale graphene based treatment system supplied to India for trial and further research purpose to IIT Madras by Exeter University. A novel decision support too has been made available, by Exeter University, as an online open access tool for the selection of sustainable treatment solutions. The tool is available here: https://fame-dst.com/ IIT-Madras also developed novel compact treatment reactor plus green solutions for ECs removal.
Start Year 2018
 
Description Research Collaboration on Water Quality Management for India 
Organisation Indian Institute of Technology Madras
Country India 
Sector Academic/University 
PI Contribution University of Exeter - Overall lead plus development of compact graphene based material treatment solutions for emerging contaminants + development of a decision support tool for the selection of optimal wastewater treatment technology for urban and rural India.
Collaborator Contribution 1. IIT - Madras (India) - Emerging contaminants (EC) monitoring for Cauvery River (South India) and development of green/extensive and compact wastewater treatments for rural and urban India. 2. IIT - Roorkee (India) - EC monitoring for Yamuna River (North India), and an assessment of 10 sewage treatment works near New Delhi and investigation of sludge treatment options for the management of ECs plus investigations on ECs prevalence in groundwater. 3. UCL (UK) - Dissemination and end user engagement 4. South West Water - Providing access to CIP (Contaminants Investigation Programme) Data and its treatment facilities operation data 5. ELIQUO HYDROK - Providing access to its HYSAF decentralised treatment facility in India. 6. Delhi and Central Pollution Control Boards (India) - India Environmental regulators providing access to 10 sewage treatment plants for ECs monitoring and facilitation with fieldwork.
Impact + 17 papers have been published by the academic partners and details are in the publications section. Pilot scale graphene based treatment system supplied to India for trial and further research purpose to IIT Madras by Exeter University. A novel decision support too has been made available, by Exeter University, as an online open access tool for the selection of sustainable treatment solutions. The tool is available here: https://fame-dst.com/ IIT-Madras also developed novel compact treatment reactor plus green solutions for ECs removal.
Start Year 2018
 
Description Research Collaboration on Water Quality Management for India 
Organisation Indian Institute of Technology Roorkee
Country India 
Sector Academic/University 
PI Contribution University of Exeter - Overall lead plus development of compact graphene based material treatment solutions for emerging contaminants + development of a decision support tool for the selection of optimal wastewater treatment technology for urban and rural India.
Collaborator Contribution 1. IIT - Madras (India) - Emerging contaminants (EC) monitoring for Cauvery River (South India) and development of green/extensive and compact wastewater treatments for rural and urban India. 2. IIT - Roorkee (India) - EC monitoring for Yamuna River (North India), and an assessment of 10 sewage treatment works near New Delhi and investigation of sludge treatment options for the management of ECs plus investigations on ECs prevalence in groundwater. 3. UCL (UK) - Dissemination and end user engagement 4. South West Water - Providing access to CIP (Contaminants Investigation Programme) Data and its treatment facilities operation data 5. ELIQUO HYDROK - Providing access to its HYSAF decentralised treatment facility in India. 6. Delhi and Central Pollution Control Boards (India) - India Environmental regulators providing access to 10 sewage treatment plants for ECs monitoring and facilitation with fieldwork.
Impact + 17 papers have been published by the academic partners and details are in the publications section. Pilot scale graphene based treatment system supplied to India for trial and further research purpose to IIT Madras by Exeter University. A novel decision support too has been made available, by Exeter University, as an online open access tool for the selection of sustainable treatment solutions. The tool is available here: https://fame-dst.com/ IIT-Madras also developed novel compact treatment reactor plus green solutions for ECs removal.
Start Year 2018
 
Description Research Collaboration on Water Quality Management for India 
Organisation South West Water Ltd
Country United Kingdom 
Sector Private 
PI Contribution University of Exeter - Overall lead plus development of compact graphene based material treatment solutions for emerging contaminants + development of a decision support tool for the selection of optimal wastewater treatment technology for urban and rural India.
Collaborator Contribution 1. IIT - Madras (India) - Emerging contaminants (EC) monitoring for Cauvery River (South India) and development of green/extensive and compact wastewater treatments for rural and urban India. 2. IIT - Roorkee (India) - EC monitoring for Yamuna River (North India), and an assessment of 10 sewage treatment works near New Delhi and investigation of sludge treatment options for the management of ECs plus investigations on ECs prevalence in groundwater. 3. UCL (UK) - Dissemination and end user engagement 4. South West Water - Providing access to CIP (Contaminants Investigation Programme) Data and its treatment facilities operation data 5. ELIQUO HYDROK - Providing access to its HYSAF decentralised treatment facility in India. 6. Delhi and Central Pollution Control Boards (India) - India Environmental regulators providing access to 10 sewage treatment plants for ECs monitoring and facilitation with fieldwork.
Impact + 17 papers have been published by the academic partners and details are in the publications section. Pilot scale graphene based treatment system supplied to India for trial and further research purpose to IIT Madras by Exeter University. A novel decision support too has been made available, by Exeter University, as an online open access tool for the selection of sustainable treatment solutions. The tool is available here: https://fame-dst.com/ IIT-Madras also developed novel compact treatment reactor plus green solutions for ECs removal.
Start Year 2018
 
Description Research Collaboration on Water Quality Management for India 
Organisation University College London
Department Department of Civil, Environmental and Geomatic Engineering
Country United Kingdom 
Sector Academic/University 
PI Contribution University of Exeter - Overall lead plus development of compact graphene based material treatment solutions for emerging contaminants + development of a decision support tool for the selection of optimal wastewater treatment technology for urban and rural India.
Collaborator Contribution 1. IIT - Madras (India) - Emerging contaminants (EC) monitoring for Cauvery River (South India) and development of green/extensive and compact wastewater treatments for rural and urban India. 2. IIT - Roorkee (India) - EC monitoring for Yamuna River (North India), and an assessment of 10 sewage treatment works near New Delhi and investigation of sludge treatment options for the management of ECs plus investigations on ECs prevalence in groundwater. 3. UCL (UK) - Dissemination and end user engagement 4. South West Water - Providing access to CIP (Contaminants Investigation Programme) Data and its treatment facilities operation data 5. ELIQUO HYDROK - Providing access to its HYSAF decentralised treatment facility in India. 6. Delhi and Central Pollution Control Boards (India) - India Environmental regulators providing access to 10 sewage treatment plants for ECs monitoring and facilitation with fieldwork.
Impact + 17 papers have been published by the academic partners and details are in the publications section. Pilot scale graphene based treatment system supplied to India for trial and further research purpose to IIT Madras by Exeter University. A novel decision support too has been made available, by Exeter University, as an online open access tool for the selection of sustainable treatment solutions. The tool is available here: https://fame-dst.com/ IIT-Madras also developed novel compact treatment reactor plus green solutions for ECs removal.
Start Year 2018
 
Description Workshops for end user engagement 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact 1. We organised two workshops in India with key stakeholders in India. These were held at IIT Madras where delegates included key water pollution control regulators, wastewater treatment technology developers and suppliers and researchers. These were held to enhance end-user engagement in India and contribute towards ODA compliance to address water quality improvements resulting in impacts such as environmental pollution control and poverty alleviation through improved health. The research findings at the completion of the project are anticipated to provide an evidence base to influence the formulation of water quality standards on emerging contaminants.

2. Additionally, in the UK we organised two industry steering broad meetings under the chairmanship of the former CEO of UKWIR where we presented the research out puts so far and opportunities for their enhanced uptake by the industry in the UK, India and beyond.

3. We have been invited to deliver a project talk at New Jersey Institute of Technology in the USA.

4. The project is also organising a virtual international conference (AQUA360) in September 2021 where delegates from DAC List/developing countries will be able to participate without any registration fees. the conference will have specific themes on emerging contaminants and water management in developing countries.
Year(s) Of Engagement Activity 2018,2019,2020,2021
URL http://www.fame-indouk.com/other-activities-iit-madras.html