Nanoengineered Materials for Clean Catalytic Technologies
Lead Research Organisation:
CARDIFF UNIVERSITY
Department Name: Chemistry
Abstract
Catalysis lies at the heart of life on earth, powers our homes and puts food on our tables. However to a large degree our ability to transform individual atoms and molecules into new pharmaceutical medicines, fuels, and fertilisers has depended upon an equal combination of brilliant science and serendipitous discoveries. This reflects the complex interactions between reacting molecules and products, their surrounding environment, and of course the catalyst itself, which ideally remains unchanged over thousands of reaction cycles. Recent advances in chemical synthesis and analysis now offer an unprecedented opportunity to sculpt the atomic structure of solid catalysts and to peer inside their microscopic workings.Over the next five years, I propose to integrate these new experimental and theoretical breakthroughs with my own expertise in catalyst design and testing, to develop a new generation of nanoengineered materials for the clean production of valuable chemical feedstocks and sustainable biofuels. New collaborations, forged with world leaders in the areas of inorganic solid-state chemistry, nanoscale imaging and computer modelling, will help me to develop the multidisciplinary skillsets needed to achieve my vision of solid catalysts, tailored 'on demand', for efficient clean technologies that will benefit society over the coming decade.
Organisations
- CARDIFF UNIVERSITY (Lead Research Organisation)
- Syngenta International AG (Collaboration)
- Elettra Sincrotrone Trieste (Collaboration)
- University of York (Project Partner)
- BP (International) (Project Partner)
- Syngenta (Project Partner)
- DSM Research (The Netherlands) (Project Partner)
- BP (International) (Project Partner)
- European Synchrotron Radiation Facility (ESRF) (Project Partner)
Publications
Lee A
(2015)
Recent developments in heterogeneous catalysis for the sustainable production of biodiesel
in Catalysis Today
Lee A
(2011)
In-situ X-ray Studies of Clean Catalytic Technologies
in MRS Proceedings
Lee A
(2010)
In situ studies of titania-supported Au shell-Pd core nanoparticles for the selective aerobic oxidation of crotyl alcohol
in Catalysis Today
Lee A.F.
(2011)
Nanoengineering the active site in heterogeneous catalysis
in ACS National Meeting Book of Abstracts
Lee A.F.
(2011)
Nanoengineering the active site in heterogeneous catalysis
in ACS National Meeting Book of Abstracts
Lee AF
(2010)
Surface catalysed Suzuki-Miyaura cross-coupling by Pd nanoparticles: an operando XAS study.
in Dalton transactions (Cambridge, England : 2003)
Lee AF
(2011)
Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd.
in Journal of the American Chemical Society
Lee AF
(2010)
Surface X-ray studies of catalytic clean technologies.
in Chemical communications (Cambridge, England)
Lee, A.F.
(2010)
Evidence for the surface catalysed Suzuki-Miyaura reaction over Pd nanocatalysts: An operando XAS study
in ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
Liu D
(2012)
On the impact of Cu dispersion on CO2 photoreduction over Cu/TiO2
in Catalysis Communications
Related Projects
| Project Reference | Relationship | Related To | Start | End | Award Value |
|---|---|---|---|---|---|
| EP/G007594/1 | 01/03/2009 | 30/07/2009 | £1,351,103 | ||
| EP/G007594/2 | Transfer | EP/G007594/1 | 31/07/2009 | 30/07/2013 | £251,849 |
| EP/G007594/3 | Transfer | EP/G007594/2 | 31/07/2013 | 13/02/2014 | £257,739 |
| EP/G007594/4 | Transfer | EP/G007594/3 | 14/02/2014 | 12/04/2015 | £57,237 |
| Description | Selective catalytic transformations for agrochemicals |
| Organisation | Syngenta International AG |
| Country | Switzerland |
| Sector | Private |
| PI Contribution | Two part-sponsored PhD studentships have undertake fundamental research into the mechanism of palladium catalysed transformations and identified key factors controlling the catalytic performance and stability of nanoparticles. |
| Collaborator Contribution | Access to laboratories, intellectual guidance, provision of catalysts |
| Impact | One PhD graduated to date, and 2 peer-reviewed publications. |
| Start Year | 2009 |
| Description | Synchtrotron studies of nanostructured materials |
| Organisation | Elettra Sincrotrone Trieste |
| Country | Italy |
| Sector | Academic/University |
| PI Contribution | New research areas in catalysis and materials science developed resulting in numerous jointly authored publications over 17 years. |
| Collaborator Contribution | Access to synchtrotron facilities and training of 8 PhD students and PDRAs |
| Impact | Joint publications, contributions to annual highlights, invited seminar and Fonda-Fasella 2004 award |
