Fuelling The Future : From Materials Science To New Energy Conversion Systems

Lead Research Organisation: University of St Andrews
Department Name: Chemistry

Abstract

The philosophy of this proposal is to bring together careful, focused basic studies with development actions to try to provide stepchange advances in Energy technology that have realistic possibility to be implemented in Industrial Development. The focus has been well informed by involvement in the Strategic Research Agenda of the European Hydrogen and Fuel Cells Platform. Our objective is to provide some of the solutions necessary to bring to fruition a vision of the new energy economy as stated below. We prefer not to follow the nuclear option; however, this only makes sense if renewable and clean energy technologies can demonstrate fairly soon that there does exist a viable non-nuclear solution, as we cannot leave Nuclear Technology on standby for very much longer, lest we lose capability. This is perhaps the gauntlet that the UK government Energy White Paper threw down for our clean Energy Community.By 2050 cheap oil will no longer be available and Europe's internal reserves will be exhausted. An increasing proportion of primary energy production will be from renewables such as solar, wind, tidal and biomass possibly supplemented by nuclear, natural gas and coal. We must rely on new energy carriers such as hydrogen, biogas or synfuels and liquid biofuels. These carriers will complement electricity as energy vectors, enabling some degree of energy efficiency optimisation, both on a local and a larger scale. A decentralised electricity generation infrastructure powered by a broad spectrum of renewable and clean technologies with a strong fuel cell component will have been created. The power network will largely be based upon self-contained nodes, each consisting of renewable and/or fuel cell systems. The advantages of this decentralised system arise from lower transmission losses, higher total energy efficiency and improved energy security. These nodes will be supported by a high value network powered by advanced thermal or nuclear systems, hydropower, buffered wind power and fuel cell systems. Our role is to develop high temperature electrochemical technologies to enable the efficient introduction of this new energy economy. Our early work will seek to optimise current fuel cell technology improving durability and stability and reducing cost of manufacture to enable widespread introduction. We will develop new anode formulations to enable efficient utilisation of more complex fuels, ranging from natural gas and LPG through biogas to liquid biofuels and biomass. Efficient utilisation of biomass is central to the new energy economy and this will be achieved by a range of mechanisms. Fuel cell technology is a particularly important enabler for biomass utilisation offering high efficiencies of conversion in fairly small unit sizes and is essential to the new distributed energy economy.Solid Oxide Fuel Cells seem certain to make a significant contribution to the future energy economy in 5-10 years, if good technological progress can be maintained; however, we only see this as one manifestation of this technology. Future development relates to efficient electrolysis, novel systems and carbon neutral fuel production. Efficient electrolysis to produce clean hydrogen is of key importance to the possibility of utilising renewable energy in transport. Similarly reversible fuel cells with careful thermal management can provide good buffering for intermittent power supplies. Discovery of new materials is important to achieving new more efficient technologies and the development of alternative systems based upon other ceramic electrolytes such as protonic or even hydride ion conductors offer even more exciting advances. The efficient conversion of carbon dioxide or nitrogen to useful carbon-free fuels is perhaps our ultimate goal in this project.
 
Description The Senior Fellowship has greatly advanced my career. My activity has considerably expanded with a research group of 40 being sustained by a structure including 4 Senior Researchers and 2 Technicians. We have set up a well equiped laboratory able to take new materials right from the electron microscope up to stack scale devices, with a high levelof competency at all these stages. We are supported by UK, European and US agences, UK and International companies. During this period I have been awarded the RSC Materials Chemistry and Lee Hsun Awards and led an EU Coal and Steel consortium, the Delivery of Sustainable Hydrogen Supergen consortium and the EPSRC UK/India Biogas SOFC consortium. I have chaired the Scottish Hydrogen and Fuel Cell Association for the last 5 years and am co-director of the Scottish Energy Technology Partnership. I chaired the 2010 European Fuel Cell Forum and have chaired or co-chaired 4 other International Conferences, editing Proceedings Volumes for all 5. I am or have been on the Editorial Board of several journals including Journal of Materials Chemistry and Advanced Energy Materials. Thus through the Felowship I have maintained and strengthened my strong interdisciplinary profile.

There have been several important research achievements and these will continue to have direct impact in the coming year with our ongoing programme building upon these into the future.

As proposed, we have maintained and developed our leading position in alternative anode materials discovery and development. Very significant progress has been made in Impregnated Electrode Structures and in Redox Exsolution Chemistry, controlling location and nanostructure of electroactive sites. Important new activities or major advances have also been as follows:

* Demonstration of High Performance (900mWcm-2) in a Hybrid Direct Carbon Fuel Cell (HDFC).
* Demonstrated Feasibility of Scale up of HDFC.
* Observation of Interstitial Oxide Ions in Apatite Conductors
* Discovery of Red Metallic Photocatalysis.
* Discovery of route to high density proton conducting perovskites.
* Discovery of catalysis of water gas shift by proton conducting oxides
* Use of proton conducting oxides for syngas production from CO2 and H2O
* Low polarisation losses demonstrated at an oxide cathode for CO2 electrolysis.
* Observation of electrolysis of pure steam at titanate electrodes.
* Direct ammonia synthesis at barium cerate type electrolytes
* Discovery and demonstration of High Hydride ion conductivity in saline hydrides
* Elucidation of t" phase in Ln2CuO4 system as a metasatble phase formed on rapid cooling
* Demonstration of very low polarisation resistance Sm2(Ba,Sr)2CoO5 SOFC cathodes
* Discovery of high protonic and oxide ionic conductivity in Si5(PO4)6O and its Ge analogue
* Use of net shape process to form dense two phase electrolyte structure with enhanced conduction and mechanical properties
* Demonstration of use of reversible fuel cell to store electricity at over 70% cycle efficiency in a thermally integrated concept.
Exploitation Route he philosophy of this proposal was to bring together careful, focused basic studies with development actions to provide stepchange advances in Energy technology that have realistic possibility to be implemented in Industrial Development. Our objective is to provide some of the solutions necessary to bring to fruition a vision of the new energy economy as stated below.

By 2050 cheap oil will no longer be available and Europe's internal reserves will be exhausted. An increasing proportion of primary energy production will be from renewables such as solar, wind, tidal and biomass possibly supplemented by nuclear, natural gas and coal. We must rely on new energy carriers such as hydrogen, biogas or synfuels and liquid biofuels. These carriers will complement electricity as energy vectors, enabling some degree of energy efficiency optimisation, both on a local and a larger scale. A decentralised electricity generation infrastructure powered by a broad spectrum of renewable and clean technologies with a strong fuel cell component will have been created. The power network will largely be based upon self-contained nodes, each consisting of renewable and/or fuel cell systems. The advantages of this decentralised system arise from lower transmission losses, higher total energy efficiency and improved energy security. These nodes will be supported by a high value network powered by advanced thermal or nuclear systems, hydropower, buffered wind power and fuel cell systems.

Our role is to develop high temperature electrochemical technologies to enable the efficient introduction of this new energy economy. This involved optimisation of current fuel cell technology improving durability and stability and reducing cost of manufacture to enable widespread introduction. We develop new anode formulations to enable efficient utilisation of more complex fuels, ranging from natural gas and LPG through biogas to liquid biofuels and biomass. Efficient utilisation of biomass is central to the new energy economy and this will be achieved by a range of mechanisms including Direct Carbon Fuel Cells. Fuel cell technology is a particularly important enabler for biomass utilisation offering high efficiencies of conversion in fairly small unit sizes and is essential to the new distributed energy economy.

Solid Oxide Fuel Cells are now satrting to make a significant contribution to the future energy economy; however, we only see this as one manifestation of this technology. Future development relates to efficient electrolysis, novel systems and carbon neutral fuel production. Efficient electrolysis to produce clean hydrogen is of key importance to the possibility of utilising renewable energy in transport. Similarly reversible fuel cells with careful thermal management can provide good buffering for intermittent power supplies. Discovery of new materials is important to achieving new more efficient technologies and the development of alternative systems based upon other ceramic electrolytes such as protonic or even hydride ion conductors offer even more exciting advances. The efficient conversion of carbon dioxide or nitrogen to useful carbon-free fuels is perhaps our ultimate goal in this project.
Sectors Energy,Environment

 
Description The philosophy of this proposal was to bring together careful, focused basic studies with development actions to provide stepchange advances in Energy technology that have realistic possibility to be implemented in Industrial Development. Our objective is to provide some of the solutions necessary to bring to fruition a vision of the new energy economy as stated below. By 2050 cheap oil will no longer be available and Europe's internal reserves will be exhausted. An increasing proportion of primary energy production will be from renewables such as solar, wind, tidal and biomass possibly supplemented by nuclear, natural gas and coal. We must rely on new energy carriers such as hydrogen, biogas or synfuels and liquid biofuels. These carriers will complement electricity as energy vectors, enabling some degree of energy efficiency optimisation, both on a local and a larger scale. A decentralised electricity generation infrastructure powered by a broad spectrum of renewable and clean technologies with a strong fuel cell component will have been created. The power network will largely be based upon self-contained nodes, each consisting of renewable and/or fuel cell systems. The advantages of this decentralised system arise from lower transmission losses, higher total energy efficiency and improved energy security. These nodes will be supported by a high value network powered by advanced thermal or nuclear systems, hydropower, buffered wind power and fuel cell systems. Our role is to develop high temperature electrochemical technologies to enable the efficient introduction of this new energy economy. This involved optimisation of current fuel cell technology improving durability and stability and reducing cost of manufacture to enable widespread introduction. We develop new anode formulations to enable efficient utilisation of more complex fuels, ranging from natural gas and LPG through biogas to liquid biofuels and biomass. Efficient utilisation of biomass is central to the new energy economy and this will be achieved by a range of mechanisms including Direct Carbon Fuel Cells. Fuel cell technology is a particularly important enabler for biomass utilisation offering high efficiencies of conversion in fairly small unit sizes and is essential to the new distributed energy economy. Solid Oxide Fuel Cells are now satrting to make a significant contribution to the future energy economy; however, we only see this as one manifestation of this technology. Future development relates to efficient electrolysis, novel systems and carbon neutral fuel production. Efficient electrolysis to produce clean hydrogen is of key importance to the possibility of utilising renewable energy in transport. Similarly reversible fuel cells with careful thermal management can provide good buffering for intermittent power supplies. Discovery of new materials is important to achieving new more efficient technologies and the development of alternative systems based upon other ceramic electrolytes such as protonic or even hydride ion conductors offer even more exciting advances. The efficient conversion of carbon dioxide or nitrogen to useful carbon-free fuels is perhaps our ultimate goal in this project.
Sector Energy,Environment
 
Description Bloom energy
Amount £270,505 (GBP)
Funding ID be 
Organisation Bloom Energy 
Sector Private
Country United States
Start  
 
Description EPSRC
Amount £142,473 (GBP)
Funding ID EP/F062435/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 04/2008 
End 03/2009
 
Description EPSRC
Amount £528,038 (GBP)
Funding ID EP/E045421/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 04/2007 
End 03/2012
 
Description EPSRC
Amount £859,124 (GBP)
Funding ID EP/G030995/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 09/2009 
End 02/2014
 
Description EPSRC
Amount £432,871 (GBP)
Funding ID EP/H004130/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 11/2009 
End 10/2012
 
Description EPSRC
Amount £1,224,922 (GBP)
Funding ID EP/I037016/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 09/2011 
End 08/2014
 
Description EPSRC
Amount £432,148 (GBP)
Funding ID EP/I022570/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 08/2011 
End 07/2015
 
Description EPSRC
Amount £137,448 (GBP)
Funding ID EP/I038950/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 01/2012 
End 06/2015
 
Description EPSRC
Amount £1,007,937 (GBP)
Funding ID EP/E064248/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 01/2008 
End 12/2012
 
Description EPSRC
Amount £4,913,990 (GBP)
Funding ID EP/G01244X/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 10/2008 
End 09/2012
 
Description EPSRC
Amount £253,420 (GBP)
Funding ID DT/E010113/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 06/2007 
End 05/2010
 
Description EU Research Fund for Coal and Steel
Amount £404,881 (GBP)
Organisation Research Fund for Coal and Steel 
Sector Public
Country Belgium
Start  
 
Description European Commission (EC)
Amount € 213,940 (EUR)
Funding ID FCH-JU-2009-01 
Organisation European Commission 
Sector Public
Country European Union (EU)
Start 10/2010 
End 09/2013
 
Description European Commission (EC)
Amount € 150,089 (EUR)
Funding ID HFC JTU 
Organisation European Commission 
Sector Public
Country European Union (EU)
Start 11/2011 
End 10/2014
 
Description European Commission (EC)
Amount £215,889 (GBP)
Funding ID FP7 
Organisation European Commission 
Sector Public
Country European Union (EU)
Start 10/2008 
End 09/2012
 
Description European Regional Development Fund
Amount £117,071 (GBP)
Funding ID lups 
Organisation European Commission 
Department European Regional Development Fund (ERDF)
Sector Public
Country Belgium
Start 01/2010 
End 03/2013
 
Description International Copper Association Ltd
Amount £56,000 (GBP)
Funding ID UStA 
Organisation International Copper Association Ltd 
Sector Charity/Non Profit
Country United States
Start  
 
Description Office of Naval Research
Amount £108,108 (GBP)
Funding ID UPenn 
Organisation US Navy 
Department US Office of Naval Research Global
Sector Academic/University
Country United States
Start  
 
Description Sasol Technology
Amount £233,727 (GBP)
Funding ID sasol 
Organisation Sasol Technology 
Sector Private
Country South Africa
Start  
 
Description Scottish Enterprise
Amount £151,187 (GBP)
Funding ID POC 
Organisation Scottish Enterprise 
Sector Public
Country United Kingdom
Start 12/2008 
End 01/2011