Macroscopic quantum coherence in non-equilibrium and driven quantum systems

Lead Research Organisation: University of Cambridge
Department Name: Physics

Abstract

My research studies systems in which quantum mechanical effects can beobserved in macroscopic systems. With thousands or millions ofparticles at relatively high temperatures (such as room temperature)most effects of quantum mechanics are washed out. Hence, most thingsin day to day life are entirely classical. There are however largesystems in which quantum mechanical effects can be seen at mediumtemperatures, these can arise when a phase transition to a quantumcondensate occurs. Examples of such condensates includesuperconductivity (where there is flow of current without electricalresistance) and superfluidity of liquid Helium (where there is fluidflow without mechanical resistance). These are striking examples ofhow ``more is different'': In systems of many interacting particles,collective phenomena can arise, where no such effect would be apparentwith only a few particles.Superconductivity and superfluid Helium are however somewhatexceptional as quantum condensates: they are the true equilibriumstates of the given material. The last decade has seen an increasingrange of other quantum condensates in systems which are not in perfectequilibrium. These include cold dilute gases of alkali atoms and veryrecently condensates of quasi-particle excitations in semiconductors,microcavity polaritons. Microcavity polaritons are mixtures ofphotons (quantised particles of light) and excitons (quantisedpolarisation of the semiconductor); this mixing is achieved usingmirrors to build a cavity that confines light, and placing a quantumwell that confines excitons between these mirrors. Microcavitypolaritons can form quantum condensates at much higher temperaturesthan the cold atomic gases, but are further from equilibrium due tothe finite lifetime of the polaritons. While the equilibriumcondensate, and the highly non-equilibrium laser have been extensivelystudied, exploration of systems between these two limits has onlybegun recently. This will be a major area of my research.In addition to allowing the investigation of coherence out ofequilibrium, the new quantum condensates have other differences fromprevious condensates; these include the effect of confining acondensate to two dimensions and the consideration of particles whoseinternal structure is relevant. Combining the effects of reduction totwo dimensions, internal structure, and nonequilibrium behaviour, thedescription of coherence in these systems can differ significantlyfrom previous examples of condensates. An understanding of how andwhen these differences inhibit the formation of quantum condensates isimportant both in terms of producing quantum condensates under easilyattainable conditions (i.e. room temperature), and in extending thevariety of properties that these condensates may have.Another area in which non-equilibrium many-body quantum mechanicalproblems arise is when parameters of the system (e.g. appliedelectric and magnetic fields, applied laser beams) are deliberatelyvaried in time. In many cases it is sufficient to describe suchsystems classically, since systems with many particles often wash outquantum mechanical effects; however there are examples, such asvarying parameters near the transition to a quantum condensate whenquantum effects should be seen. Building on recent examples ofstrongly coupled light-matter systems in which semiclassicaltreatments are inadequate, I will study whether there are cases wherethere can be dramatic signatures of quantum mechanics in such drivensystems.In summary, my work aims to study the conditions under whichmacroscopic physical systems show quantum behaviour, to consider whatuses this behaviour may have, and to understand what is required toextend the range of conditions where such behaviour can be seen.

Publications

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Description The unifying theme of my fellowship has been non-equilibrium quantum systems, including both the dynamics of many body quantum systems and non-equilibrium (non-thermal) steady state condensation. These ideas relate to a range of different experimental systems, from microcavity polaritons (superpositions of photons and bound electron-hole pairs), to superconducing qubits in microwave resonators, to cold atoms. Cold atoms and superconducting qubits play a role as particularly well controlled systems in which one may explore the consequences of non-equilibrium quantum dynamics in straightforward settings. In contrast, polariton condensates show more complex behaviours, due to effects of disorder, decoherence and energy relaxation induced by the solid state environment - they thus require a clear understanding of the influence that these unavoidable effects have on non-equilibrium condensation. During the course of my fellowship, experimental progress in all of these fields has prompted new questions, in addition to those originally anticipated. The Key findings relate to these, but are classified below under the categories identified in the original proposal.Driven quantum condensates: I have calculated the superfluid density of a non-equilibrium polariton condensate, and the results of this have been published in [5]_. I showed that superfluidity can survive despite finite particle lifetime, and proposed how to measure polariton superfluid density; this achieves a major aim of this strand. Building on a microscopic model of non-equilibrium polariton condensation, I have shown the important role of temperature in distinguishing lasing and condensation[6]_. I have collaborated with the experimental group of Y. Yamamoto (Stanford) to interpret their measurements of coherence in a polariton condensate; we have shown that power law decay of coherence (as expected in a 2D system) survives finite particle lifetime, but the power law seen differs significantly from equilibrium[13]. I have also written an invited review on polariton condensation[3]_. During the course of this fellowship, I was awarded an additional "Developing Leaders" grant to work on problems of "Photon Condensation" in dye-filled microcavities[4].This lead to the development of a quantum model, which takes account of the thermalisation as well as the losses in the cavity, published in [14]. Based on this model, we are continuing to explore the conditions under which photon condensation differs from lasing. Other properties of exotic condensates: I have studied how the polarisation degree of freedom affects non-equilibrium pattern formation in a polariton condensate[7,8]_. This work has shown that the polarisation state adopted in a non-equilibrium context can be significantly more complicated than in equilibrium, since pumping may prevent the lowest polarisation states from being achieved. I have also worked on polarisation phenomena in cold exciton gases[1]._ I have also shown that the polarisation dependent interaction between polaritons suggests the existence of an entirely new phase of the polariton system [15]Dynamical many body systems: As originally proposed, I have explored how large quantum corrections exist in the dynamics if starting near unstable classical equilibrium, and how this may be described using the WKB approach[9,10]_. This work lead to productive collaboration with groups in ETH leading to a number of other projects, based on experimental developments occurring during the fellowship. In particular, experiments on collective dynamics showed the first realisation of the superradiance transition of the Dicke model[2]_. In these experiments, atoms were placed in an optical cavity and pumped from the side. Above a critical pump strength a transition to a non-equilibrium self-organised steady state occured. We have shown[11,12]_ how the collective dynamics in this system shows surprisingly long timescales, and how persistent oscillating phases can also be achieved. Recently, we have extended this to see how fermionic atoms lead to a range of exotic critical behaviour [16]. I have also begun to explore how non-equilibrium behaviour affects quantum simulation in coupled qubit-resonator systems[17], involving collaborative work with the world-leading Wallraff group[18].[1] N. Sinclair et al. Phys. Rev. B 83, 245304 (2011).[2] K. Baumann, C. Guerlin, F. Brennecke, and T. Esslinger, Nature 464, 1301-1306 (2010).[3] J. Keeling and N. G. Berloff, Contemporary Physics 52, 131-151 (2011).[4] J. Klaers, J. Schmitt, F. Vewinger, and M. Weitz, Nature 468, 545-548 (2010).[5] J. Keeling, Phys. Rev. Lett. 107, 080402 (2011).[6] J. Keeling, M. H. Szymanska, and P. B Littlewood, in Optical Generation and Control of Quantum Coherence in Semiconductor Nanostructures, edited by G. Slavcheva and P. Roussignol (2010), p. 293.[7] J. Keeling and N. G Berloff, arXiv:1102.5302v2 (2011).[8] M. O. Borgh, J. Keeling, and N. G. Berloff, Phys. Rev. B 81, 235302 (2010).[9] J. Keeling, Phys. Rev. A 79, 053825 (2009).[10] F. Nissen and J. Keeling, Phys. Rev. A 81, 063628 (2010).[11] J. Keeling, M. J. Bhaseen, and B. D. Simons, Phys. Rev. Lett. 105, 043001 (2010).[12] M. J. Bhaseen, J Mayoh, B. D. Simons, and J Keeling, Phys. Rev. A 85, 013817 (2012).[13] G. Roumpos, et al., J. Keeling, et al. Submitted to Proc. Natl. Acad. Sci (2012).[14] P. Kirton and J. Keeling, Phys. Rev. Lett. 111 100404 (2013).[15] F. Marchetti and J. Keeling arXiv:1308.1032[16] J. Keeling, M. J. Bhaseen and B. D. Simons arXiv:1309.2464, Phys. Rev. Lett. In press.[17] F. Nissen, S. Schmidt, M. Biondi, G. Blatter, H. E. Türeci, and J. Keeling, Phys. Rev. Lett. 108 233603 (2012)[18] F. Nissen, J. M. Fink, J. A. Mlynek, A. Wallraff, and J. Keeling, Phys. Rev. Lett. 110 203602 (2013)
Exploitation Route My work on pattern formation in polariton condensates (cited > 100 times since its 2008 publication has led to a widely used approach in modelling polariton physics.

My work of ideal electronic pulses has stimulated continuing work a group in Paris aiming to building devices based on manipulating single electron wavepackets.

My work on superfluidity has inspired significant recent theoretical work, that appears to radically redefine what we understand about superfluid behaviour in open systems

My work on organic polariton and photon condensates provides a basis to ask novel questions about energy transport, energy level engineering and optoelectronic properties of organic materials, which may have implications for light harvesting (i.e. solar cells) or light emission (i.e. LEDs), work is continuing to explore these.
Sectors Electronics,Energy

 
Description My work as a theorist is focussed on understanding underpinning aspects of non-equilibrium quantum behaviour across a range of systems, with possible applications in information processing, optoelectronics and light-harvesting. However, because these are working on areas where there is uncertainty, there is a long period between understanding the physics and producing commercial devices. From repeated conversations with those working in technology transfer, they repeatedly tell me that the time to market for real devices (as opposed to software) is typically 20-40 years. As such, it would be hard for unknown aspects of theory to have already delivered commercial impact within the duration of a five year fellowship.
Sector Electronics,Energy
 
Description DAAD RISE Internship: Roman Mauch
Amount € 1,300 (EUR)
Funding ID GB-PH-2072 
Organisation German Academic Exchange Service (DAAD) 
Sector Academic/University
Country United States
Start 08/2016 
End 09/2016
 
Description Laidlaw Internship: Ryan Moodie
Amount £4,110 (GBP)
Organisation University of St Andrews 
Sector Academic/University
Country United Kingdom
Start 06/2016 
End 08/2016
 
Description Nuffield Undergraduate Research Bursary
Amount £1,440 (GBP)
Funding ID URB/40664 
Organisation Nuffield Foundation 
Sector Charity/Non Profit
Country United Kingdom
Start 05/2012 
End 08/2012
 
Description Talk to University Physics Society 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Undergraduate students
Results and Impact Students asked questions afterwards

Queries from audience members about taking up summer internship programmes, or possible PhD applications
Year(s) Of Engagement Activity 2008,2014