Catalytic Ambiphilic C-H Activation: Mechanism and Exploitation
Lead Research Organisation:
Heriot-Watt University
Department Name: Sch of Engineering and Physical Science
Abstract
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Organisations
People |
ORCID iD |
| Stuart Macgregor (Principal Investigator) |
Publications
Alharis RA
(2019)
Understanding electronic effects on carboxylate-assisted C-H activation at ruthenium: the importance of kinetic and thermodynamic control.
in Faraday discussions
Alharis RA
(2019)
The Importance of Kinetic and Thermodynamic Control when Assessing Mechanisms of Carboxylate-Assisted C-H Activation.
in Journal of the American Chemical Society
Carr K
(2016)
C-H Bond Activation and Catalytic Functionalization I
Davies DL
(2017)
Computational Studies of Carboxylate-Assisted C-H Activation and Functionalization at Group 8-10 Transition Metal Centers.
in Chemical reviews
Perrin L
(2016)
Computational Studies in Organometallic Chemistry
| Description | Insight into the action of transition metal catalysts |
| Exploitation Route | In the design of more effective catalysts. For a series of related substrates the selectivity can change dependent on the reaction conditions. Hence, assigning a reaction mechanism to these types of reaction based on a single set of conditions can lead to erroneous conclusions. |
| Sectors | Chemicals |
| Description | For a series of related substrates the selectivity can change dependent on the reaction conditions. Hence, assigning a reaction mechanism to these types of reaction based on a single set of conditions can lead to erroneous conclusions. |
| First Year Of Impact | 2019 |
| Sector | Chemicals |