Catalytic Functionalisation of Aromatic Fluorocarbons
Lead Research Organisation:
Heriot-Watt University
Department Name: Sch of Engineering and Physical Science
Abstract
Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.
Organisations
People |
ORCID iD |
| Stuart Macgregor (Principal Investigator) |
Publications
Cybulski MK
(2017)
Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans-[Ru(NHC)4 H2 ] through a Concerted Nucleophilic Ru-H Attack Pathway.
in Angewandte Chemie (International ed. in English)
Häller LJ
(2017)
Computation provides chemical insight into the diverse hydride NMR chemical shifts of [Ru(NHC)4(L)H]0/+ species (NHC = N-heterocyclic carbene; L = vacant, H2, N2, CO, MeCN, O2, P4, SO2, H-, F- and Cl-) and their [Ru(R2PCH2CH2PR2)2(L)H]+ congeners.
in Dalton transactions (Cambridge, England : 2003)
Macgregor SA
(2013)
Computational study of the hydrodefluorination of fluoroarenes at [Ru(NHC)(PR3)2(CO)(H)2]: predicted scope and regioselectivities.
in Dalton transactions (Cambridge, England : 2003)
Miloserdov FM
(2015)
Exceedingly Facile Ph-X Activation (X = Cl, Br, I) with Ruthenium(II): Arresting Kinetics, Autocatalysis, and Mechanisms.
in Angewandte Chemie (International ed. in English)
Perrin L
(2016)
Computational Studies in Organometallic Chemistry
Riddlestone I
(2016)
Isolation of [Ru(IPr) 2 (CO)H] + (IPr = 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and Reactivity toward E-H (E = H, B) Bonds
in Organometallics
Riddlestone IM
(2018)
Well-Defined Heterobimetallic Reactivity at Unsupported Ruthenium-Indium Bonds.
in Chemistry (Weinheim an der Bergstrasse, Germany)
| Description | Understanding mechanisms of C-F activation at transition metal catalysts |
| Exploitation Route | In designing more efficient catalysts |
| Sectors | Chemicals |