Understanding and engineering function in switchable molecular crystals
Lead Research Organisation:
University of Bath
Department Name: Chemistry
Abstract
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Organisations
Publications
Capel Berdiell I
(2021)
Structures and Spin States of Iron(II) Complexes of Isomeric 2,6-Di(1,2,3-triazolyl)pyridine Ligands.
in Inorganic chemistry
Deeth RJ
(2018)
Ab Initio Ligand Field Molecular Mechanics and the Nature of Metal-Ligand p-Bonding in Fe(II) 2,6-di(pyrazol-1-yl)pyridine Spin Crossover Complexes.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Francisco TM
(2017)
Hard X-ray-Induced Valence Tautomeric Interconversion in Cobalt-o-Dioxolene Complexes.
in The journal of physical chemistry letters
Greatorex S
(2020)
Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn-Teller Distortion.
in Inorganic chemistry
Halcrow MA
(2019)
Relationship between the Molecular Structure and Switching Temperature in a Library of Spin-Crossover Molecular Materials.
in Inorganic chemistry
Kulmaczewski R
(2017)
The role of symmetry breaking in the structural trapping of light-induced excited spin states.
in Chemical communications (Cambridge, England)
Kulmaczewski R
(2021)
Structural Transformations and Spin-Crossover in [FeL2 ]2+ Salts (L=4-{tert-Butylsulfanyl}-2,6-di{pyrazol-1-yl}pyridine): The Influence of Bulky Ligand Substituents.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Kulmaczewski R
(2023)
Di-Iron(II) [2+2] Helicates of Bis-(Dipyrazolylpyridine) Ligands: The Influence of the Ligand Linker Group on Spin State Properties.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Kulmaczewski R
(2021)
Influence of ligand substituent conformation on the spin state of an iron(II)/di(pyrazol-1-yl)pyridine complex.
in Dalton transactions (Cambridge, England : 2003)
Leroy L
(2021)
Controlled Light and Temperature Induced Valence Tautomerism in a Cobalt-o-Dioxolene Complex
in Inorganic Chemistry
| Description | The is a second component of the grant with the same title in my portfolio, and is now held in Bath because Professor Robert Deeth, formerly of the University of Warwick, has moved to Bath. He has been undertaking computational studies on spin crossover complexes, and we are using his input to direct and underpin our synthetic studies. We have established control over the temperature related switching properties of new classes of spin crossover materials. |
| Exploitation Route | Other may use the knowledge that we have gained in the control of the spin crossover temperature and the width of the hysterisis loop to design magnetically switching materials. |
| Sectors | Digital/Communication/Information Technologies (including Software),Electronics,Energy |