Transition Metal Alkane Sigma Complexes by Solid-State Synthesis Routes: Defining and Exploiting a New Area of Organometallic Chemistry.
Lead Research Organisation:
Heriot-Watt University
Department Name: Sch of Engineering and Physical Science
Abstract
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Organisations
Publications
Bukvic AJ
(2021)
A Series of Crystallographically Characterized Linear and Branched s-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane.
in Journal of the American Chemical Society
Doyle LR
(2022)
Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane s-Alkane Complex.
in Organometallics
Krämer T
(2023)
Solid-State Confinement Effects in Selective exo -H/D Exchange in the Rhodium s-Norbornane Complex [(Cy 2 PCH 2 CH 2 PCy 2 )Rh(? 2 :? 2 -C 7 H 12 )][BAr F 4 ]
in Helvetica Chimica Acta
Krämer T
(2023)
Stability and C-H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism.
in Journal of the American Chemical Society
Pike S
(2015)
Stoichiometric and Catalytic Solid-Gas Reactivity of Rhodium Bis-phosphine Complexes
in Organometallics
Pike SD
(2015)
Solid-state synthesis and characterization of s-alkane complexes, [Rh(L2)(?(2),?(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine).
in Journal of the American Chemical Society
| Description | Information on reaction mechanisms relevant for catalysis |
| Exploitation Route | in the design of more robust catalysts |
| Sectors | Chemicals |