EPSRC-Royal Society fellowship engagement (2013): Giant mechanocaloric effects in ferroelectrics and elastomers

Lead Research Organisation: University of Cambridge
Department Name: Materials Science & Metallurgy

Abstract

Please refer to attached Royal Society application.

Planned Impact

Please refer to attached Royal Society application.
 
Description I discovered giant mechanocaloric effects in powdered salts of the ferrielectric ammonium sulphate, which is made from cheap abundant elements and is commercially available. I found giant reversible mechanocaloric effects that outperform those observed in the best mechanocaloric magnetic materials, and those predicted in inferior mechanocaloric ferroelectric oxides.
Exploitation Route We are currently exploring ways to improve the mechanocaloric response of ferroelectric materials in order to match the demanding requirements set by industrial and household cooling applications.
Sectors Energy,Environment

 
Description My discovery of giant mechanocaloric effects in a material that is cheap and made of abundant elements has attracted the interest of Daikin Industries, one of the world's largest multinational air conditioner manufacturing companies, and Beko Ltd, the best-selling white-goods brand in the UK. The interest from Beko materialised in an Early Stage Innovate UK research grant to develop a mechanocaloric cooler, which started in April 2017. More recently, this discovery has attracted interest of several other companies, and this has led to the successful award of an EPSRC Impact Acceleration Account Follow-On Fund to design and build a mechanocaloric cooler based on my material. This latter work led to further engagement with industry, which ultimately culminated in the creation of a start-up company (Barocal Ltd).
First Year Of Impact 2017
Sector Agriculture, Food and Drink,Energy,Environment
Impact Types Societal,Economic

 
Description Feasability of using barocaloric cooling for energy efficiency gains and zero greenhouse warming impact in commercial food and drink refrigeration
Amount £98,500 (GBP)
Funding ID 105512 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 11/2019 
End 10/2020
 
Description Impact Acceleration Account Follow-On Fund
Amount £60,000 (GBP)
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 04/2018 
End 09/2018
 
Description Investigating the spin-out potential for novel barocaloric cooling materials
Amount £12,000 (GBP)
Funding ID RG90413 
Organisation ESRC Impact Acceleration Account Cambridge 
Sector Academic/University
Country United Kingdom
Start 03/2019 
End 06/2019
 
Description Research Fellows Enhancement Award 2017
Amount £110,000 (GBP)
Funding ID RGF\EA\180293 
Organisation The Royal Society 
Sector Charity/Non Profit
Country United Kingdom
Start 12/2017 
End 11/2021
 
Description Research Fellows Enhancement Awards 2018
Amount £199,906 (GBP)
Funding ID RGF\EA\181017 
Organisation University of Cambridge 
Sector Academic/University
Country United Kingdom
Start 10/2018 
End 03/2021
 
Description Starting Grant
Amount € 1,500,000 (EUR)
Funding ID 680032 
Organisation European Research Council (ERC) 
Sector Public
Country Belgium
Start 04/2016 
End 03/2021
 
Description Technology Strategy Board: Energy Catalyst - Early Stage - Round 4
Amount £240,000 (GBP)
Funding ID 132481 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 04/2017 
End 03/2018
 
Description Mechanocaloric Mn-based antiperovksites 
Organisation Imperial College London
Department Department of Physics
Country United Kingdom 
Sector Academic/University 
PI Contribution My team started studying mechanocaloric properties of Mn-based antiperovskites samples that were prepared by our collaborators at Imperial College. These materials undergo magnetovolume phase transitions near room temperature that exhibit large values of latent heat, and therefore are promising for solid-state cooling applications.
Collaborator Contribution Our collaborators prepared a series of Mn-based antiperovskite samples, with transition temperatures spanning a wide temperature range near room temperature that matches applications.
Impact This collaboration is new and the work has just started. The collaboration is multi-disciplinary and involves Materials Science and Physics.
Start Year 2017
 
Description Mechanocaloric VO2 oxides 
Organisation Murata Manufacturing
Country Japan 
Sector Public 
PI Contribution My team studied mechanocaloric properties of VO2 oxide samples that were prepared by our collaborators in Murata Manufacturing. These oxides undergo metal-insulator phase transitions near room temperature that exhibit large values of latent heat, and therefore are promising for solid-state cooling applications.
Collaborator Contribution Our collaborators prepared a series of doped VO2 samples, with transition temperatures spanning a wide temperature range near room temperature that matches applications.
Impact We expanded the list of materials to investigate, based on our studies.
Start Year 2015
 
Description Mechanocaloric superionic conductors 
Organisation University of New South Wales
Country Australia 
Sector Academic/University 
PI Contribution My team started studying mechanocaloric properties of superionic conductors that were sent by our collaborators at the University of New South Wales. These materials undergo superionic phase transitions near room temperature that exhibit large values of latent heat, and therefore are promising for solid-state cooling applications.
Collaborator Contribution Our collaborators sent a number of superionic samples, with transition temperatures spanning a wide temperature range near room temperature that matches applications. They also predicted mechanocaloric properties of some of the materials using first-principles calculations.
Impact This collaboration has already led to the observation of giant mechanocaloric effects in AgI superionic conductors, which has been recently published in Nature Communications, DOI: 10.1038/s41467-017-01898-2.
Start Year 2017
 
Description Blog entry for the Society of Spanish Researchers in the United Kingdom 
Form Of Engagement Activity Engagement focused website, blog or social media channel
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact I was invited by the Society of Spanish Researchers in the United Kingdom to write an entry for their blog about my research on mechanocaloric cooling. This entry led to an invitation to give a lecture the Vicente Cañada Blanch Spanish Secondary School in London.
Year(s) Of Engagement Activity 2017
URL https://blogsruk.wordpress.com/
 
Description Cambridge Science Festival 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Schools
Results and Impact Organisation of the hands-on activity "Cool balloons" to demonstrate caloric materials using balloons and infra-red cameras.
Year(s) Of Engagement Activity 2018
 
Description Chesterton Community College after-school science club 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Schools
Results and Impact Presentation and hands-on activity to demonstrate how solids can be exploited for environmentally friendly cooling applications.
Year(s) Of Engagement Activity 2015,2016
 
Description Enabling Innovation Exhibition 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact I was sponsored by Magna, the leading global automotive supplier, to display a stand to present barocaloric cooling technology at the Enabling Innovation Exhibition, Advanced Engineering 2017 at NEC, Birmingham. This presentation led to offers of industrial collaboration and funding by one automotive company and one aerospace company.
Year(s) Of Engagement Activity 2017
 
Description Interview for AZoNetwork 
Form Of Engagement Activity A press release, press conference or response to a media enquiry/interview
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Interview for AZoNetwork, the leading online publisher producing multimedia content for audiences in Materials, Healthcare, Life Sciences, Sensors, Medical and Nanotechnology.
Year(s) Of Engagement Activity 2017
URL https://www.azom.com/article.aspx?ArticleID=13453
 
Description Interview for Horizon, the European Union science, research and innovation magazine 
Form Of Engagement Activity A press release, press conference or response to a media enquiry/interview
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Media (as a channel to the public)
Results and Impact Interview about my recent work on mechanocaloric materials. This interview led to a recent invitation for an interview by AZoNetwork
Year(s) Of Engagement Activity 2016
URL https://horizon-magazine.eu/article/fridges-without-hum-alloys-and-salts-offer-liquid-free-cooling_e...
 
Description Interview for the Spanish newspaper La Vanguardia 
Form Of Engagement Activity A press release, press conference or response to a media enquiry/interview
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Interview about my research for one of the newspapers with the highest circulation in Spain, La Vanguardia, with 600000 daily readers. This interview led to another interview for another Spanish newspaper, and an invitation to deliver a talk at the Spanish Royal Society of Physics in Madrid.
Year(s) Of Engagement Activity 2017
URL http://www.lavanguardia.com/ciencia/20171218/433651486934/xavier-moya-premio-talento-emergente-2017-...
 
Description Intreview for BBC One, broadcast on BBC Breakfast, BBC Weekend News and BBC World News 
Form Of Engagement Activity A press release, press conference or response to a media enquiry/interview
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Media (as a channel to the public)
Results and Impact I was interviewed by BBC about my work on mechanocaloric materials and devices. The purpose was to disseminate my work. After seeing the interview, a number of academics and industrialists approached me in order to discuss collaboration, thus stimulating increased interest and activity in this area of research. Separately, a number of other media outlets (BBC Radio Wales, Discovery Channel, Al Jazeera) contacted me in order to perform similar pieces for them.
Year(s) Of Engagement Activity 2019
URL https://www.youtube.com/watch?v=M0kMN_t-Dz4
 
Description Science Museum Lates 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact Organisation of "Keep cool and carry on" hands-on outreach activity at the Science Museum London, to demonstrate how solids can be exploited for environmentally friendly mechanocaloric cooling. The activity sparked questions and discussion afterwards, and a school teacher who attended the activity expressed his interest in hosting a similar activity in his school.
Year(s) Of Engagement Activity 2015
 
Description Talk at Pint of Knowledge 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact Presentation and hands-on activity to demonstrate how solids can be exploited for environmentally friendly cooling applications. The presentation led to an invitation to contribute a post for a popular science blog.
Year(s) Of Engagement Activity 2016