Diamond for Image Intensifier and Photodetection Applications
Lead Research Organisation:
University College London
Department Name: London Centre for Nanotechnology
Abstract
An image intensifier is a device that intensifies low light-level images to light levels that can be seen with the human eye or can be detected by a camera. An image intensifier consists of a vacuum tube with several conversion and multiplication screens. An incident photon will hit a light sensitive photo-cathode screen. Photons are absorbed in the photocathode and give rise to emission of electrons into the vacuum. These electrons are accelerated by an electric field to increase their energy and focus them on the multi channel plate (MCP).
As a wide band gap (5.5eV) semiconductor diamond offers a range of properties that make its integration into image intensifier devices very promising in terms of enhanced device performance. For example, under appropriate conditions the surface of diamond can display a negative electron affinity (NEA), allowing for high secondary electron yields (SEY) to be achieved, with values greater than 100 being achieved. Diamond, grown by chemical vapour deposition (CVD) methods, can also support very high carrier mobilities and has a high electric field breakdown strength. Given that it takes 13eV to create electron-hole pairs in diamond when irradiated by electrons 'cascade gain' of an electron flux within diamond can be achieved; this can lead to an electron transmission gain of >10 if the transmitted electrons emerge from an NEA diamond surface. Diamond can also be doped p-type by the inclusion of boron.
Existing MCP technology leads to a secondary electron 'gain' of around 1.9 when incoming electrons impact the channel regions of the plate. Whilst cascading results in over-all gains of a few thousand at the exit of the MCP, these large values only arise for the electrons that are effective in the initial stages of secondary generation. As 1.9 is a statistical value some incoming electrons will not result in further cascade and are effectively 'lost' degrading the resultant image. It is thus desirable that gain levels are increased at the entrance to the MCP and for a short distance into the MCP.
Another limitation to the performance of current MCP-based image intensifiers involves the loss of 'focus' caused by the emergence of 'hot' electrons from the exit of the MCP. It is the consideration of these issues, along with the properties of diamond described above that allows for the development of several ideas for considerably enhancing the performance of existing image intensifiers, namely:
[1] A diamond pre-amplifier stage. A thin diamond membrane (displaying transmission electron gain), to pre-amplify the photo-generated electrons prior to their entry into the MCP for image intensifiers.
[2] Diamond coating the MCP for enhanced SEY (displaying reflective gain) for image intensifiers. A thin diamond layer displaying NEA to enhance the SEY for each electron collision within the MCP
In addition the replacement of the MCP within an image intensifier device with a 'stack' of diamond membranes may offer an alternative to Avalanche Photodiodes (APD) for ultra-low light fast photodetection. If each membrane offers a transmission gain of ~10, then a 4-layer stack may offer a gain of some 10,000. This would lead to a completely new generation of photodetectors.
[3] A diamond membrane stack for multi-stage electron amplification (transmission gain) within a low light fast photodetector
As a wide band gap (5.5eV) semiconductor diamond offers a range of properties that make its integration into image intensifier devices very promising in terms of enhanced device performance. For example, under appropriate conditions the surface of diamond can display a negative electron affinity (NEA), allowing for high secondary electron yields (SEY) to be achieved, with values greater than 100 being achieved. Diamond, grown by chemical vapour deposition (CVD) methods, can also support very high carrier mobilities and has a high electric field breakdown strength. Given that it takes 13eV to create electron-hole pairs in diamond when irradiated by electrons 'cascade gain' of an electron flux within diamond can be achieved; this can lead to an electron transmission gain of >10 if the transmitted electrons emerge from an NEA diamond surface. Diamond can also be doped p-type by the inclusion of boron.
Existing MCP technology leads to a secondary electron 'gain' of around 1.9 when incoming electrons impact the channel regions of the plate. Whilst cascading results in over-all gains of a few thousand at the exit of the MCP, these large values only arise for the electrons that are effective in the initial stages of secondary generation. As 1.9 is a statistical value some incoming electrons will not result in further cascade and are effectively 'lost' degrading the resultant image. It is thus desirable that gain levels are increased at the entrance to the MCP and for a short distance into the MCP.
Another limitation to the performance of current MCP-based image intensifiers involves the loss of 'focus' caused by the emergence of 'hot' electrons from the exit of the MCP. It is the consideration of these issues, along with the properties of diamond described above that allows for the development of several ideas for considerably enhancing the performance of existing image intensifiers, namely:
[1] A diamond pre-amplifier stage. A thin diamond membrane (displaying transmission electron gain), to pre-amplify the photo-generated electrons prior to their entry into the MCP for image intensifiers.
[2] Diamond coating the MCP for enhanced SEY (displaying reflective gain) for image intensifiers. A thin diamond layer displaying NEA to enhance the SEY for each electron collision within the MCP
In addition the replacement of the MCP within an image intensifier device with a 'stack' of diamond membranes may offer an alternative to Avalanche Photodiodes (APD) for ultra-low light fast photodetection. If each membrane offers a transmission gain of ~10, then a 4-layer stack may offer a gain of some 10,000. This would lead to a completely new generation of photodetectors.
[3] A diamond membrane stack for multi-stage electron amplification (transmission gain) within a low light fast photodetector
Planned Impact
Low light level photo-detection and imaging is essential in many sectors, ranging from manufacturing, automotive and aerospace, medical and scientific instrumentation, space science and astronomy as well as defence related activities. In the latter case night vision is now an essential aspect of modern warfare, and continual improvements are sought to keep NATO forces a step-ahead within the volatile arenas around the world that they find themselves within. It is also the case that more local terror threats along with civil search and rescue tasks all require the UK to have sophisticated night vision capabilities. The proposed activity will have a very broadly based, very high impact on a number of sectors of high importance to the UK and the EU.
[1] Image Intensifiers for night vision
The manufacture of enhanced image intensfiers. The proposed activity offers the prospect of a generation of image intensifiers that will considerably outperform current devices. As a project partner, the EUs Photonis SAS is well placed to expolit such an acheivement and has indeed expressed a strong interest in expoiting diamond technology within its products. The UKs Photek Ltd also manufacture image intensifiers and can be expected to be able to exploit the outcomes of the project.
Access to the military markets is complex, and Photonis are ideally placed to achieve this, and the UKs Qioptiq Ltd provides night vision systems for the military using image intensifiers therefore also being well placed to exploit the developments achieved.
The UKs BAE Systems plc is the second largest defence sector manufacturer and is well placed to exploit enhanced night vision devices in many areas, including within its aerospace division.
It is anticipated that night vision within the automotive industry will emerge as a multi-billion dollar market (see case in support); 'high end' vehicles (luxury, performance) will be the entry point here and the UK is particularly strong here, with an important industry in parts development and supply. The UK also manufactures large volumes of mainstream cars for export, to which the technology can be expected to trickle-down. Low light level machine vision is also an increasing important use of image intensifiers within, for example, the food industry.
[2] Photodetection
The enhanced MCP-based technology and the completely new type of photodetector (based on stacked diamond membranes) have the potential to make an enormous impact on, again, a very broad range of applications sectors. In addition to the manufacturing capabilities of Photonis and Photek already noted the UK hosts a number of SMEs, with which Jackman already has past/present links, which are well placed to exploit the projects outcomes to develop and manufacture detectors. These include Centronic Ltd, E2V Ltd, Applied Scintillation Technologies Ltd and Micron Semiconductor Ltd; the latter already has an in-house programme developing diamond based radiation detectors.
In terms of application, the UK has a thriving space science and astronomy community for whom these devices would be of considerable interest. A major interest will be in the use of ultra-compact, fast, high gain new generation photodetectors that will emerge for laser range finding. Qioptiq Ltd in the UK will be ideally placed to liaise with Photonis or one of the other manufacturing companies to develop a new generation of, for example, weapons sights using such devices. High-speed low light level detection applications exist in the medical and scientific instrument fields as well as advanced manufacturing environments.
[1] Image Intensifiers for night vision
The manufacture of enhanced image intensfiers. The proposed activity offers the prospect of a generation of image intensifiers that will considerably outperform current devices. As a project partner, the EUs Photonis SAS is well placed to expolit such an acheivement and has indeed expressed a strong interest in expoiting diamond technology within its products. The UKs Photek Ltd also manufacture image intensifiers and can be expected to be able to exploit the outcomes of the project.
Access to the military markets is complex, and Photonis are ideally placed to achieve this, and the UKs Qioptiq Ltd provides night vision systems for the military using image intensifiers therefore also being well placed to exploit the developments achieved.
The UKs BAE Systems plc is the second largest defence sector manufacturer and is well placed to exploit enhanced night vision devices in many areas, including within its aerospace division.
It is anticipated that night vision within the automotive industry will emerge as a multi-billion dollar market (see case in support); 'high end' vehicles (luxury, performance) will be the entry point here and the UK is particularly strong here, with an important industry in parts development and supply. The UK also manufactures large volumes of mainstream cars for export, to which the technology can be expected to trickle-down. Low light level machine vision is also an increasing important use of image intensifiers within, for example, the food industry.
[2] Photodetection
The enhanced MCP-based technology and the completely new type of photodetector (based on stacked diamond membranes) have the potential to make an enormous impact on, again, a very broad range of applications sectors. In addition to the manufacturing capabilities of Photonis and Photek already noted the UK hosts a number of SMEs, with which Jackman already has past/present links, which are well placed to exploit the projects outcomes to develop and manufacture detectors. These include Centronic Ltd, E2V Ltd, Applied Scintillation Technologies Ltd and Micron Semiconductor Ltd; the latter already has an in-house programme developing diamond based radiation detectors.
In terms of application, the UK has a thriving space science and astronomy community for whom these devices would be of considerable interest. A major interest will be in the use of ultra-compact, fast, high gain new generation photodetectors that will emerge for laser range finding. Qioptiq Ltd in the UK will be ideally placed to liaise with Photonis or one of the other manufacturing companies to develop a new generation of, for example, weapons sights using such devices. High-speed low light level detection applications exist in the medical and scientific instrument fields as well as advanced manufacturing environments.
People |
ORCID iD |
Richard Jackman (Principal Investigator) |
Publications
Afandi A
(2018)
Nanodiamonds for device applications: An investigation of the properties of boron-doped detonation nanodiamonds.
in Scientific reports
Canas J
(2021)
Normally-OFF Diamond Reverse Blocking MESFET
in IEEE Transactions on Electron Devices
Dashwood C
(2021)
Probing Electron-Phonon Interactions Away from the Fermi Level with Resonant Inelastic X-Ray Scattering
in Physical Review X
Franchino S
(2016)
Charge transfer properties through graphene for applications in gaseous detectors
in Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment
Loto O
(2018)
Gate Oxide Electrical Stability of p-type Diamond MOS Capacitors
in IEEE Transactions on Electron Devices
Mazzola F
(2018)
Simultaneous Conduction and Valence Band Quantization in Ultrashallow High-Density Doping Profiles in Semiconductors
in Physical Review Letters
McLaughlin MHS
(2021)
A detailed EIS study of boron doped diamond electrodes decorated with gold nanoparticles for high sensitivity mercury detection.
in Scientific reports
Pakpour-Tabrizi A
(2022)
Diamond Nanowire Transistor with High Current Capability
in physica status solidi (a)
Pakpour-Tabrizi AC
(2020)
The occupied electronic structure of ultrathin boron doped diamond.
in Nanoscale advances
Description | On-going, but making significant improvements to the state-of-the art in image intensifiers for night vision applications. Currently exploring the commercial development of the ideas generated. |
Exploitation Route | Further funding being sought for translational research |
Sectors | Aerospace, Defence and Marine |
Description | Patent submission made by UCL. Patent licensed to BAE Systems for exploitation. BAE Systems has awarded 2.1M GBP further research funding to the grants PI at UCL to develop prototype devices. |
First Year Of Impact | 2018 |
Sector | Aerospace, Defence and Marine |
Impact Types | Societal,Economic |
Description | Multfunctional diamond sensors for extreme environments: BoltSens phase 1 |
Amount | £849,000 (GBP) |
Organisation | BAE Systems |
Sector | Academic/University |
Country | United Kingdom |
Start | 12/2018 |
End | 03/2021 |
Description | Multifunctional diamond sensors for extreme environments: BoltSens phase 2 |
Amount | £1,126,000 (GBP) |
Organisation | BAE Systems |
Sector | Academic/University |
Country | United Kingdom |
Start | 01/2022 |
End | 12/2023 |
Description | Q-NEURO: Diamond Quantum Technology for the Investigation of Neurological disease |
Amount | £282,470 (GBP) |
Funding ID | EP/R034699/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 01/2018 |
End | 07/2020 |
Description | BAES diamond devices |
Organisation | BAE Systems |
Department | BAE Systems Submarine Solutions |
Country | United Kingdom |
Sector | Private |
PI Contribution | The design and fabrication of diamond devices for submarine applications |
Collaborator Contribution | Identification of submarine needs; device packaging; in-house test facilities; diamond substrates |
Impact | Diamond devices designed and fabricated by the PIs team are being fitted on HMS Artful, the UKs third nuclear ASTUTE class submarine for safety critical operation. Further to this original application - >4M GBP programme (4 years) is underway (midpoint as of 02/2022) in diamond sensors for the primary water cooling circuit of PWRs that power the UKs nuclear submarine fleet |
Start Year | 2010 |
Description | Collaboration with Yale University |
Organisation | Yale University |
Department | School of Engineering and Applied Science |
Country | United States |
Sector | Academic/University |
PI Contribution | Secondment of UCLs Alex Pakpour-Tabrizi to Yale University for 5 months. Expertise on diamond electronic devices and diamond processing. Funded by a scheme known as the "Yale UCL Collaborative". |
Collaborator Contribution | Received UCLs Alex Pakpour-Tabrizi at Yale for 5 months. Expertise on e-beam lithography, quantum structures and nanowires, device processing. |
Impact | Joint publication of a ground breaking paper on diamond nanowires |
Start Year | 2018 |
Description | Diamond Radiation detectors |
Organisation | BAE Systems |
Department | BAE Systems Maritime – Naval Ships |
Country | United Kingdom |
Sector | Private |
PI Contribution | Idea, research and prototype development. |
Collaborator Contribution | Devices under trial on Astute class submarines. |
Impact | REF Case study used any UCL. Safety feature designed for UKs fleet of nuclear powered submarines |
Start Year | 2015 |
Description | Diamond-based multi-function sensors for extreme environments |
Organisation | BAE Systems |
Department | BAE Systems Maritime – Naval Ships |
Country | United Kingdom |
Sector | Private |
PI Contribution | Design, research, development and prototyping |
Collaborator Contribution | Need, drive and test facilities |
Impact | Currently confidential |
Start Year | 2016 |
Description | Further collaboration with Photonis SAS |
Organisation | Photonis SAS |
Country | France |
Sector | Private |
PI Contribution | We are working with Photonis on diamond-based enhancement to image intensifiers and photodetectors |
Collaborator Contribution | Know how an image intensifier design and operation, as well as the same for photodetectors, access stop materials and devices otherwise not freely available, use of measurement and test facilities at Photonis SAS |
Impact | Early stage to be reported later. Anticipate field trial ahead of potential commercial development. |
Start Year | 2015 |
Description | GreenDiamond |
Organisation | NEEL Institute |
Country | France |
Sector | Public |
PI Contribution | Design, processing and fabrication of diamond devices |
Collaborator Contribution | Design, processing and fabrication of diamond devices |
Impact | An Impact award from the French science ministry. Currently shortlisted for an EU impact prize (value 25k Euro) |
Start Year | 2017 |
Description | GreenDiamond |
Organisation | University of Cadiz |
Country | Spain |
Sector | Academic/University |
PI Contribution | Processing and fabrication for diamond electronics |
Collaborator Contribution | Materials characterisation for diamond electronics |
Impact | GreenDiamond EU Horizon 2020 award |
Start Year | 2018 |
Description | Photonis diamond devices |
Organisation | Photonis SAS |
Country | France |
Sector | Private |
PI Contribution | Deign work; materials science; device fabrication; diamond growth |
Collaborator Contribution | Design work; in-house test facilities; diamond materials and substrates |
Impact | One PhD thesis; two publications; 4 patents |
Start Year | 2011 |
Title | A PHOTO CATHODE FOR USE IN A VACUUM TUBE AS WELL AS SUCH A VACUUM TUBE |
Description | The invention relates to a photo cathode for use in a vacuum tube at least comprising a cathode layer, having an entrance face capable for absorbing photons impinging on said cathode layer, and an exit face for releasing electrons upon impinging of said photons; as well as an electron exit layer, in facing relationship with said exit face of said cathode layer for improving said releasing of said electrons; and a carbon containing layer, positioned between said exit face of said cathode layer and said electron exit layer, for bonding said electron exit layer to said cathode layer. The invention also relates to a vacuum tube using such a photo cathode. |
IP Reference | WO2011112086 |
Protection | Patent granted |
Year Protection Granted | 2011 |
Licensed | Commercial In Confidence |
Impact | commercial development of a diamond based night vision device |
Title | AN ELECTRON MULTIPLYING STRUCTURE FOR USE IN A VACUUM TUBE USING ELECTRON MULTIPLYING AS WELL AS A VACUUM TUBE USING ELECTRON MULTIPLYING PROVIDED WITH SUCH AN ELECTRON MULTIPLYING STRUCTURE |
Description | The invention relates to an electron multiplying structure for use in a vacuum tube using electron multiplying and to an vacuum tube using electron multiplying provided with such an electron multiplying structure. According to the invention an electron multiplying structure is proposed for use in a vacuum tube using electron multiplying, the electron multiplying structure comprising an input face intended to be oriented in a facing relationship with an entrance window of the vacuum tube, an output face intended to be oriented in a facing relationship with a detection surface of the vacuum tube, wherein the electron multiplying structure at least is composed of a semi-conductor material layer adjacent the detection windows. |
IP Reference | WO2011149351 |
Protection | Patent granted |
Year Protection Granted | 2011 |
Licensed | Commercial In Confidence |
Impact | Commercial development of diamond-based electron amplifiers |
Title | DIAMOND-BASED SENSOR DEVICE FOR USE IN HOSTILE ENVIRONMENTS |
Description | A sensor device is provided to sample data from a fluid in a sealed environment. The sensor comprises a housing and a diamond within the housing. The housing is formed such that the device is reversibly insertable into the sealed environment so that the diamond directly interfaces with the sealed environment. |
IP Reference | US2019064099 |
Protection | Patent application published |
Year Protection Granted | 2019 |
Licensed | Yes |
Impact | UCL spin out company |
Title | ELECTRON MULTIPLIER DETECTOR FORMED FROM A HIGHLY DOPED NANODIAMOND LAYER |
Description | The invention relates to a system for detecting electromagnetic radiation or an ion flow, comprising an input device (10) for receiving the electronic radiation or the ion flow and emitting so-called primary electrons in response, a multiplier (20) of electrons in transmission, for receiving the primary electrons and emitting so-called secondary electrons in response, and an output device (30) for receiving the secondary electrons and emitting an output signal in response. Said electron multiplier (20) comprises at least one nanocrystalline diamond layer (21) doped with boron in a concentration of higher than 5.1019cm~3. |
IP Reference | WO2011157810 |
Protection | Patent granted |
Year Protection Granted | 2011 |
Licensed | Commercial In Confidence |
Impact | Commercial development of a diamond-based electron multiplier |
Title | ELECTRON MULTIPLIER DEVICE HAVING A NANODIAMOND LAYER |
Description | The invention relates to an electron multiplier (1) for a system for detecting electromagnetic radiation or an ion flow. The multiplier (1) comprises at least one active structure (2) for receiving a flow of incident electrons and for emitting a flow of so-called secondary electrons in response. Said active structure (2) comprises a substrate (3) on which a thin nanodiamond layer (4) is arranged, wherein said layer consists of diamond particles, the average size of which is no greater than 100 nm. |
IP Reference | WO2012034948 |
Protection | Patent granted |
Year Protection Granted | 2012 |
Licensed | Commercial In Confidence |
Impact | Commercial development of a diamond based electron multiplier device |
Title | ELECTRONIC DEVICE |
Description | An electronic device, and method of producing an electronic device, are disclosed. The electronic device comprises a diamond substrate 10. Within the substrate 10 is an electrode 12, known as a 'buried electrode'. A first surface 14 of the substrate 10 is provided with a conductive contact region 16. The electrode 12 is electrically connected to the contact region 16 by a conductive pillar 18. The electrode, conductive pillar, and contact region comprise modified portions of the diamond substrate, for example comprising at least one of graphitic carbon, amorphous carbon, and a combination of SP2 and SP3 phases of carbon, formed from a portion of diamond substrate. |
IP Reference | WO2021170989 |
Protection | Patent application published |
Year Protection Granted | 2021 |
Licensed | No |
Impact | Highly efficient diamond power devices for the low carbon energy economy |
Company Name | Corite Technology Ltd |
Description | A spin-out from the PIs research team with 4 of the PIs team members to exploit diamond sensor technology |
Year Established | 2017 |
Impact | Start up |