Diamond for Image Intensifier and Photodetection Applications

Lead Research Organisation: University College London
Department Name: London Centre for Nanotechnology

Abstract

An image intensifier is a device that intensifies low light-level images to light levels that can be seen with the human eye or can be detected by a camera. An image intensifier consists of a vacuum tube with several conversion and multiplication screens. An incident photon will hit a light sensitive photo-cathode screen. Photons are absorbed in the photocathode and give rise to emission of electrons into the vacuum. These electrons are accelerated by an electric field to increase their energy and focus them on the multi channel plate (MCP).

As a wide band gap (5.5eV) semiconductor diamond offers a range of properties that make its integration into image intensifier devices very promising in terms of enhanced device performance. For example, under appropriate conditions the surface of diamond can display a negative electron affinity (NEA), allowing for high secondary electron yields (SEY) to be achieved, with values greater than 100 being achieved. Diamond, grown by chemical vapour deposition (CVD) methods, can also support very high carrier mobilities and has a high electric field breakdown strength. Given that it takes 13eV to create electron-hole pairs in diamond when irradiated by electrons 'cascade gain' of an electron flux within diamond can be achieved; this can lead to an electron transmission gain of >10 if the transmitted electrons emerge from an NEA diamond surface. Diamond can also be doped p-type by the inclusion of boron.

Existing MCP technology leads to a secondary electron 'gain' of around 1.9 when incoming electrons impact the channel regions of the plate. Whilst cascading results in over-all gains of a few thousand at the exit of the MCP, these large values only arise for the electrons that are effective in the initial stages of secondary generation. As 1.9 is a statistical value some incoming electrons will not result in further cascade and are effectively 'lost' degrading the resultant image. It is thus desirable that gain levels are increased at the entrance to the MCP and for a short distance into the MCP.

Another limitation to the performance of current MCP-based image intensifiers involves the loss of 'focus' caused by the emergence of 'hot' electrons from the exit of the MCP. It is the consideration of these issues, along with the properties of diamond described above that allows for the development of several ideas for considerably enhancing the performance of existing image intensifiers, namely:

[1] A diamond pre-amplifier stage. A thin diamond membrane (displaying transmission electron gain), to pre-amplify the photo-generated electrons prior to their entry into the MCP for image intensifiers.
[2] Diamond coating the MCP for enhanced SEY (displaying reflective gain) for image intensifiers. A thin diamond layer displaying NEA to enhance the SEY for each electron collision within the MCP

In addition the replacement of the MCP within an image intensifier device with a 'stack' of diamond membranes may offer an alternative to Avalanche Photodiodes (APD) for ultra-low light fast photodetection. If each membrane offers a transmission gain of ~10, then a 4-layer stack may offer a gain of some 10,000. This would lead to a completely new generation of photodetectors.

[3] A diamond membrane stack for multi-stage electron amplification (transmission gain) within a low light fast photodetector

Planned Impact

Low light level photo-detection and imaging is essential in many sectors, ranging from manufacturing, automotive and aerospace, medical and scientific instrumentation, space science and astronomy as well as defence related activities. In the latter case night vision is now an essential aspect of modern warfare, and continual improvements are sought to keep NATO forces a step-ahead within the volatile arenas around the world that they find themselves within. It is also the case that more local terror threats along with civil search and rescue tasks all require the UK to have sophisticated night vision capabilities. The proposed activity will have a very broadly based, very high impact on a number of sectors of high importance to the UK and the EU.

[1] Image Intensifiers for night vision

The manufacture of enhanced image intensfiers. The proposed activity offers the prospect of a generation of image intensifiers that will considerably outperform current devices. As a project partner, the EUs Photonis SAS is well placed to expolit such an acheivement and has indeed expressed a strong interest in expoiting diamond technology within its products. The UKs Photek Ltd also manufacture image intensifiers and can be expected to be able to exploit the outcomes of the project.

Access to the military markets is complex, and Photonis are ideally placed to achieve this, and the UKs Qioptiq Ltd provides night vision systems for the military using image intensifiers therefore also being well placed to exploit the developments achieved.

The UKs BAE Systems plc is the second largest defence sector manufacturer and is well placed to exploit enhanced night vision devices in many areas, including within its aerospace division.

It is anticipated that night vision within the automotive industry will emerge as a multi-billion dollar market (see case in support); 'high end' vehicles (luxury, performance) will be the entry point here and the UK is particularly strong here, with an important industry in parts development and supply. The UK also manufactures large volumes of mainstream cars for export, to which the technology can be expected to trickle-down. Low light level machine vision is also an increasing important use of image intensifiers within, for example, the food industry.

[2] Photodetection

The enhanced MCP-based technology and the completely new type of photodetector (based on stacked diamond membranes) have the potential to make an enormous impact on, again, a very broad range of applications sectors. In addition to the manufacturing capabilities of Photonis and Photek already noted the UK hosts a number of SMEs, with which Jackman already has past/present links, which are well placed to exploit the projects outcomes to develop and manufacture detectors. These include Centronic Ltd, E2V Ltd, Applied Scintillation Technologies Ltd and Micron Semiconductor Ltd; the latter already has an in-house programme developing diamond based radiation detectors.

In terms of application, the UK has a thriving space science and astronomy community for whom these devices would be of considerable interest. A major interest will be in the use of ultra-compact, fast, high gain new generation photodetectors that will emerge for laser range finding. Qioptiq Ltd in the UK will be ideally placed to liaise with Photonis or one of the other manufacturing companies to develop a new generation of, for example, weapons sights using such devices. High-speed low light level detection applications exist in the medical and scientific instrument fields as well as advanced manufacturing environments.

Publications

10 25 50
 
Description On-going, but making significant improvements to the state-of-the art in image intensifiers for night vision applications. Currently exploring the commercial development of the ideas generated.
Exploitation Route Further funding being sought for translational research
Sectors Aerospace, Defence and Marine

 
Description Patent submission made by UCL. Patent licensed to BAE Systems for exploitation. BAE Systems has awarded 2.1M GBP further research funding to the grants PI at UCL to develop prototype devices.
First Year Of Impact 2018
Sector Aerospace, Defence and Marine
Impact Types Societal,Economic

 
Description Multfunctional diamond sensors for extreme environments: BoltSens phase 1
Amount £849,000 (GBP)
Organisation BAE Systems 
Sector Academic/University
Country United Kingdom
Start 12/2018 
End 03/2021
 
Description Multifunctional diamond sensors for extreme environments: BoltSens phase 2
Amount £1,126,000 (GBP)
Organisation BAE Systems 
Sector Academic/University
Country United Kingdom
Start 01/2022 
End 12/2023
 
Description Q-NEURO: Diamond Quantum Technology for the Investigation of Neurological disease
Amount £282,470 (GBP)
Funding ID EP/R034699/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 01/2018 
End 07/2020
 
Description BAES diamond devices 
Organisation BAE Systems
Department BAE Systems Submarine Solutions
Country United Kingdom 
Sector Private 
PI Contribution The design and fabrication of diamond devices for submarine applications
Collaborator Contribution Identification of submarine needs; device packaging; in-house test facilities; diamond substrates
Impact Diamond devices designed and fabricated by the PIs team are being fitted on HMS Artful, the UKs third nuclear ASTUTE class submarine for safety critical operation. Further to this original application - >4M GBP programme (4 years) is underway (midpoint as of 02/2022) in diamond sensors for the primary water cooling circuit of PWRs that power the UKs nuclear submarine fleet
Start Year 2010
 
Description Collaboration with Yale University 
Organisation Yale University
Department School of Engineering and Applied Science
Country United States 
Sector Academic/University 
PI Contribution Secondment of UCLs Alex Pakpour-Tabrizi to Yale University for 5 months. Expertise on diamond electronic devices and diamond processing. Funded by a scheme known as the "Yale UCL Collaborative".
Collaborator Contribution Received UCLs Alex Pakpour-Tabrizi at Yale for 5 months. Expertise on e-beam lithography, quantum structures and nanowires, device processing.
Impact Joint publication of a ground breaking paper on diamond nanowires
Start Year 2018
 
Description Diamond Radiation detectors 
Organisation BAE Systems
Department BAE Systems Maritime – Naval Ships
Country United Kingdom 
Sector Private 
PI Contribution Idea, research and prototype development.
Collaborator Contribution Devices under trial on Astute class submarines.
Impact REF Case study used any UCL. Safety feature designed for UKs fleet of nuclear powered submarines
Start Year 2015
 
Description Diamond-based multi-function sensors for extreme environments 
Organisation BAE Systems
Department BAE Systems Maritime – Naval Ships
Country United Kingdom 
Sector Private 
PI Contribution Design, research, development and prototyping
Collaborator Contribution Need, drive and test facilities
Impact Currently confidential
Start Year 2016
 
Description Further collaboration with Photonis SAS 
Organisation Photonis SAS
Country France 
Sector Private 
PI Contribution We are working with Photonis on diamond-based enhancement to image intensifiers and photodetectors
Collaborator Contribution Know how an image intensifier design and operation, as well as the same for photodetectors, access stop materials and devices otherwise not freely available, use of measurement and test facilities at Photonis SAS
Impact Early stage to be reported later. Anticipate field trial ahead of potential commercial development.
Start Year 2015
 
Description GreenDiamond 
Organisation NEEL Institute
Country France 
Sector Public 
PI Contribution Design, processing and fabrication of diamond devices
Collaborator Contribution Design, processing and fabrication of diamond devices
Impact An Impact award from the French science ministry. Currently shortlisted for an EU impact prize (value 25k Euro)
Start Year 2017
 
Description GreenDiamond 
Organisation University of Cadiz
Country Spain 
Sector Academic/University 
PI Contribution Processing and fabrication for diamond electronics
Collaborator Contribution Materials characterisation for diamond electronics
Impact GreenDiamond EU Horizon 2020 award
Start Year 2018
 
Description Photonis diamond devices 
Organisation Photonis SAS
Country France 
Sector Private 
PI Contribution Deign work; materials science; device fabrication; diamond growth
Collaborator Contribution Design work; in-house test facilities; diamond materials and substrates
Impact One PhD thesis; two publications; 4 patents
Start Year 2011
 
Title A PHOTO CATHODE FOR USE IN A VACUUM TUBE AS WELL AS SUCH A VACUUM TUBE 
Description The invention relates to a photo cathode for use in a vacuum tube at least comprising a cathode layer, having an entrance face capable for absorbing photons impinging on said cathode layer, and an exit face for releasing electrons upon impinging of said photons; as well as an electron exit layer, in facing relationship with said exit face of said cathode layer for improving said releasing of said electrons; and a carbon containing layer, positioned between said exit face of said cathode layer and said electron exit layer, for bonding said electron exit layer to said cathode layer. The invention also relates to a vacuum tube using such a photo cathode. 
IP Reference WO2011112086 
Protection Patent granted
Year Protection Granted 2011
Licensed Commercial In Confidence
Impact commercial development of a diamond based night vision device
 
Title AN ELECTRON MULTIPLYING STRUCTURE FOR USE IN A VACUUM TUBE USING ELECTRON MULTIPLYING AS WELL AS A VACUUM TUBE USING ELECTRON MULTIPLYING PROVIDED WITH SUCH AN ELECTRON MULTIPLYING STRUCTURE 
Description The invention relates to an electron multiplying structure for use in a vacuum tube using electron multiplying and to an vacuum tube using electron multiplying provided with such an electron multiplying structure. According to the invention an electron multiplying structure is proposed for use in a vacuum tube using electron multiplying, the electron multiplying structure comprising an input face intended to be oriented in a facing relationship with an entrance window of the vacuum tube, an output face intended to be oriented in a facing relationship with a detection surface of the vacuum tube, wherein the electron multiplying structure at least is composed of a semi-conductor material layer adjacent the detection windows. 
IP Reference WO2011149351 
Protection Patent granted
Year Protection Granted 2011
Licensed Commercial In Confidence
Impact Commercial development of diamond-based electron amplifiers
 
Title DIAMOND-BASED SENSOR DEVICE FOR USE IN HOSTILE ENVIRONMENTS 
Description A sensor device is provided to sample data from a fluid in a sealed environment. The sensor comprises a housing and a diamond within the housing. The housing is formed such that the device is reversibly insertable into the sealed environment so that the diamond directly interfaces with the sealed environment. 
IP Reference US2019064099 
Protection Patent application published
Year Protection Granted 2019
Licensed Yes
Impact UCL spin out company
 
Title ELECTRON MULTIPLIER DETECTOR FORMED FROM A HIGHLY DOPED NANODIAMOND LAYER 
Description The invention relates to a system for detecting electromagnetic radiation or an ion flow, comprising an input device (10) for receiving the electronic radiation or the ion flow and emitting so-called primary electrons in response, a multiplier (20) of electrons in transmission, for receiving the primary electrons and emitting so-called secondary electrons in response, and an output device (30) for receiving the secondary electrons and emitting an output signal in response. Said electron multiplier (20) comprises at least one nanocrystalline diamond layer (21) doped with boron in a concentration of higher than 5.1019cm~3. 
IP Reference WO2011157810 
Protection Patent granted
Year Protection Granted 2011
Licensed Commercial In Confidence
Impact Commercial development of a diamond-based electron multiplier
 
Title ELECTRON MULTIPLIER DEVICE HAVING A NANODIAMOND LAYER 
Description The invention relates to an electron multiplier (1) for a system for detecting electromagnetic radiation or an ion flow. The multiplier (1) comprises at least one active structure (2) for receiving a flow of incident electrons and for emitting a flow of so-called secondary electrons in response. Said active structure (2) comprises a substrate (3) on which a thin nanodiamond layer (4) is arranged, wherein said layer consists of diamond particles, the average size of which is no greater than 100 nm. 
IP Reference WO2012034948 
Protection Patent granted
Year Protection Granted 2012
Licensed Commercial In Confidence
Impact Commercial development of a diamond based electron multiplier device
 
Title ELECTRONIC DEVICE 
Description An electronic device, and method of producing an electronic device, are disclosed. The electronic device comprises a diamond substrate 10. Within the substrate 10 is an electrode 12, known as a 'buried electrode'. A first surface 14 of the substrate 10 is provided with a conductive contact region 16. The electrode 12 is electrically connected to the contact region 16 by a conductive pillar 18. The electrode, conductive pillar, and contact region comprise modified portions of the diamond substrate, for example comprising at least one of graphitic carbon, amorphous carbon, and a combination of SP2 and SP3 phases of carbon, formed from a portion of diamond substrate. 
IP Reference WO2021170989 
Protection Patent application published
Year Protection Granted 2021
Licensed No
Impact Highly efficient diamond power devices for the low carbon energy economy
 
Company Name Corite Technology Ltd 
Description A spin-out from the PIs research team with 4 of the PIs team members to exploit diamond sensor technology 
Year Established 2017 
Impact Start up