Light-controlled manufacturing of semiconductor structures: a platform for next generation processing of photonic devices

Lead Research Organisation: University of Glasgow
Department Name: School of Chemistry

Abstract

This Platform Grant (PG) will apply our internationally-leading expertise in structured illumination and hybrid inorganic/organic semiconductor optoelectronic devices to create new opportunities in the rapidly developing field of light-controlled manufacturing. Structured illumination fields can in principle be obtained from both inorganic (GaN) and organic LEDs, implemented on a macroscale via relay optics, or demagnified to a microscale. Novel manufacturing with photopolymerisable materials can firstly involve use of structured illumination as a novel means to control motorised stages. This technique can be combined with pattern-programmable UV excitation for mask-free photolithographic patterning, continuous photo-curing over larger fields, localised photochemical deposition, or other forms of photo-labile assembly. Process variants can also be envisaged in which arbitrarily positioned fluorescent objects or markers are 'hunted', and then subject to beam excitation for photocuring or targeted photoexcitation. This method could be used, for example, to immobilise individual colloidal quantum dots for use as emitters in quantum technology applications. Multifunctional devices with sensing ability, such as organic lasers for explosives detection, represent another excellent example of automated devices operating under remote conditions. Further examples of the envisaged uses of this technology include:

[1] LED microdisplay asset tags for management of high-value objects (artworks, nuclear fuel containers).
[2] Passive asset tags containing unique micro-patterns of fluorescent objects (eg. colloidal quantum dots, organic macromolecules) for higher-volume, anti-counterfeiting applications.
[3] Customisable continuous-flow micro-reactors for fine chemical manufacturing.
[4] Energy harvesting micro-modules to power other autonomous microsystems, where we will focus on organic PV and ambient-radiation (RF) approaches.

Planned Impact

Our work centres on an exciting new approach to the manufacturing of photonic devices that will impact academic and commercial beneficiaries and the public sector. The approach uses arrays of electronically-interfaced light-emitting devices (gallium nitride and organic LEDs, plus hybrids) to generate patterned illumination for a range of coordinated manufacturing functions. These devices provide precision tooling down to the sub-micron level to locate, write on and develop photoresist layers and photosensitive nanocomposites in a directed and spatially localised manner, whilst also controlling mechanically activated multi-step assembly and facilitating process monitoring. Such structured and targeted light is ideal for spatially localised excitation to enable the targeted photo-setting of light-sensitive materials but the same source can also map and identify the area to be illuminated and control the assembly process. This approach does not require a precision mask for patterning of the device and is therefore a highly convenient, low-cost and flexible method for producing a range of differently patterned devices with features down to the micro and nanoscale.

The types of applications we will target range from automated, self-locating systems to hybrid semiconductor devices for visible light communications. The latter includes light fidelity or LiFi, a powerful technology to complement WiFi, which is reaching its limit in terms of data transfer rates with rapidly increasing user demand. Our work will therefore be highly beneficial to the manufacturing sector, end-users in a wide range of businesses (e.g. warehouses, smart lighting for offices and meeting rooms), and the information and communications technology sector. Potential collaborators and beneficiaries include: printing companies that could adopt our manufacturing techniques (Nano Products Ltd., Printed Electronics Ltd., both UK; XCeleprint, Ireland); mask-less lithographic companies (Heidelberg Instruments, Germany); manufacturers of chemical micro-reactors (Little Things Factory, Germany); suppliers of GaN-on-Si LED wafers (Plessey Semiconductors, UK); EPSRC Centre for Innovative Manufacturing in Large Area Electronics, Catapult Centre in High Value Manufacturing.

Publications

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Amano H (2020) The 2020 UV emitter roadmap in Journal of Physics D: Applied Physics

 
Description Single molecule conductors with light-emitting properties have been discovered and proven to have the highest current modulation recorded in single molecule devices.
Emissive materials have been developed that can be used in hybrid LED devices as frequency downconverters to produce specific colour outputs or white light.
Exploitation Route For the downconverters, the materials are being developed through an IAA project since they have commercial value in micro LEDs.
Sectors Chemicals,Electronics,Manufacturing, including Industrial Biotechology

 
Description An IAA award was granted to work with Plessey on the supply of new materials for device applications. This has expanded to an ongoing collaboration with Plessey Semiconductors with the potential for exploitation of IP. The above developed has led to a joint-funded PhD student who started in October 2021.
First Year Of Impact 2021
Sector Chemicals,Electronics,Energy,Manufacturing, including Industrial Biotechology
 
Description 'Hetero-print': A holistic approach to transfer-printing for heterogeneous integration in manufacturing
Amount £5,541,652 (GBP)
Funding ID EP/R03480X/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 06/2018 
End 05/2024
 
Description IAA - Synthesis of organic materials for downconverters
Amount £49,999 (GBP)
Funding ID 319082/0 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 08/2022 
End 07/2023
 
Description Structured illumination and digital lighting at the few-photon level
Amount £476,159 (GBP)
Funding ID EP/S001751/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 06/2018 
End 06/2022
 
Title Micromanipulators for nanoprobing 
Description Two nanoprobes, mounted on micromanipulators, have been installed within a scanning electron microscope allowing measurements of mechanical (e.g. stress, force) and electrical (e.g. IV, EBIC) on a local scale. 
Type Of Material Improvements to research infrastructure 
Year Produced 2020 
Provided To Others? Yes  
Impact Results starting to be reported in journal publications 
 
Title A Study on Varying the Number of Fluorene Units in 2, 1, 3-Benzothiadiazole-Containing Oligomers and the Effect on OLED Performance and Stability 
Description This dataset contains raw data for the above titled article, published in the journal ChemPhotoChem. The data includes synthesis characterisation data for new compounds and characterisation of the physical properties of the target compounds including absorption and emission spectra, thermal characterisation, cyclic voltammetry. Data from organic light-emitting diode devices is also included and characterisation of these devices such as lifetime measurements, electroluminescence and atomic force microscopy topography measurements. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL http://researchdata.gla.ac.uk/id/eprint/1372
 
Title Amino Acid Functionalised Perylene Bisimides for Aqueous Solution-deposited Electron Transporting Interlayers in Organic Photovoltaic Devices 
Description Consists of current voltage plots, external quantum efficiency graphs, atomic force microscopy images, UV/Vis absorption spectra 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL http://researchdata.gla.ac.uk/id/eprint/1186
 
Title Deposited data presented in BICOP2018 paper 'Digital illumination in micro-scale direct-writing photolithography....', M Stonehouse et al 
Description Experimental data presented in figures in the above manuscript, to be published in IEEE Explore 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
Impact None to date 
 
Title Deposited data presented in BICOP2018 paper 'Water resistant caesium lead bromide crystal composites' P Alves et al 
Description Experimental data used in figures in the above paper, to be published in IEEE Explore 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
Impact None to date 
 
Title Effect of end group functionalisation of small molecules featuring the fluorene-thiophene-benzothiadiazole motif as emitters in solution-processed red and orange organic light-emitting diodes 
Description A series of red fluorescent materials (compounds 1-4), which each contain the symmetric fluorene-thiophene-BT-thiophene-fluorene core, is presented along with their performance in solution-processed OLED devices. Extending the molecular conjugation through end-capping with additional fluorene units (compound 2), or through incorporation of donor functionalities (compounds 3 and 4) improves OLED performance relative to the parent compound 1. Notably, incorporating triphenylamine donor groups in compound 3 led to solution-processed OLED devices operating with a peak luminance of 2888 cd m-2 and a low turn-on voltage (3.6 V). 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Highly Nonlinear Transport Across Single-Molecule Junctions via Destructive Quantum Interference 
Description Please note that the data files associated with this record are embargoed until the associated research article is published. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL http://researchdata.gla.ac.uk/id/eprint/1062
 
Title Implementing fluorescent MOFs as down-converting layers in hybrid light-emitting diodes 
Description  
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Title Supporting data for 'Suspension and transfer printing of ZnCdMgSe membranes from an InP substrate'. Optical Materials Express, 10, 3328 (2020) 
Description Data etc. used to produce figures in the published paper 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
Impact Expected commercial impact in 3-5 years. 
URL http://doi.org/10.15129/b3974689-3d7c-49d0-ab7a-c7fd7c1f1382
 
Title Supporting data for IPC conference paper on micro-scale automated alignment and spatial tracking 
Description Numerical data and explanatory text used to make figures in published version of output. 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
Impact These data will allow others to critically assess the accuracy of the automated alignment. 
 
Title Supporting data for Optical Materials Express journal article on lead halide perovskite dots-in-crystal color converer 
Description Files of numerical data and explanatory text used to make figures in journal article 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? No  
Impact This is likely to of use in applying this material in practical visible light communiction. 
 
Title Tetrathiafulvalene-oligofluorene star-shaped systems: new semiconductor materials for fluorescent moisture indicators 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Description Single molecule conductance 
Organisation Columbia University
Country United States 
Sector Academic/University 
PI Contribution A new conjugated molecule has been synthesised and is being studied for its single molecule conductance using the break-junction method.
Collaborator Contribution The collaboration is with Prof Latha Venkataraman from Columbia University, USA. The partners are experts in studying single molecule conductance using the break-junction method. They are carrying out such measurements on two new materials made from the Skabara group. This method is an alternative way of characterising the conductance of target molecules, compared to the methods applied by our co-investigators in Oxford.
Impact We have discovered a new chemical design principle for exploiting destructive quantum interference. The approach has provided a six-nanometer single-molecule switch where the on-state current is more than 10,000 times greater than the off-state current - the largest change in current achieved for a single-molecule circuit to date. The work is multi-disciplinary and involves chemistry (Glasgow) and applied physics (Columbia). The work has been published in Nature Nanotechnology and has received significant coverage in the scientific press (Physicsworld, Science Bulletin, EurekAlert!, ScienMag, Science Daily, Brinkwire, sciencenewsnet.in, Nanowerk, Newswise, Phys.org, Scitech Daily, Bioengineer.com).
Start Year 2018
 
Description International Conference on the Science and Technology of Synthetic Metals (ICSM) Virtual Conference 2021 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact 410 delegates attended a virtual meeting organised by Professors PJ Skabara and I Samuel on 16-17 June 2021. ICSM is the largest conference devoted to the field of organic electronics and has showcased many of the most important developments in the field over the last 40 years. It is a biennial meeting and the free virtual event was organised as a stop-gap between the last (2018) and next (2022) in-person ICSM meetings, since the 2020 meeting was postponed due to the pandemic.
Year(s) Of Engagement Activity 2021
URL https://icsm2022.com/icsm2021-virtual/
 
Description Organisation of the International Conference on the Science and Technology of Synthetic Metals (ICSM). 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact The conference took place at the University of Glasgow from 17-22 July 2022 and was Chaired by Prof PJ Skabara (University of Glasgow) with Prof I Samuel (St Andrews) as Deputy Chair. Over 600 participants attended the meeting. ICSM is the largest conference devoted to the field of organic electronics and has showcased many of the most important developments in the field over the last 40 years.
Year(s) Of Engagement Activity 2022
URL https://icsm2022.com/
 
Description Paul Drude Institute and Technical University Berlin visits, April 2018 by Dr Jochen Bruckbauer, Dr Paul Edwards and Prof Rob Martin, each presenting at both institutes 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Other audiences
Results and Impact Academic presentations to like minded scientific researchers and university staff.
Year(s) Of Engagement Activity 2018
 
Description Plessey Semiconductors Ltd visit 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact An industry visit to dissemante mini-projects and discuss new metrology with potential applications in manufacturing. Interest has been generate in a novel imaging system and discussions on how to progress begun
Year(s) Of Engagement Activity 2019
 
Description PragmatIC Ltd visit 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact Visit to PragmatIC Ltd to discuss smart pick and place manufacturing for continuous batch assembly, and the opportunity to explore future collaboration ideas.
Year(s) Of Engagement Activity 2019
 
Description Prof Rob Martin, Lancaster University Dec 2018 to present a colloquium 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Study participants or study members
Results and Impact academic seminar
Year(s) Of Engagement Activity 2018
 
Description School visit (Aberdeen) to run a workshop on the science of light 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Schools
Results and Impact Approximately 70 final year primary school children attended a workshop on the science of light, conducted by Prof P Skabara and Dr A Klimash. The workshop was hands-on and included demonstrations of technologies not yet on the market (flexible organic optoelectronic devices).
Year(s) Of Engagement Activity 2022
 
Description Supporting Ukrainian researchers and students in a live Q&A session with President Zelensky 
Form Of Engagement Activity A broadcast e.g. TV/radio/film/podcast (other than news/press)
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Media (as a channel to the public)
Results and Impact Channel 4 and 10 UK universities took part in a videoconference with the President of Ukraine in June 2022, including the University of Glasgow, LSE, University of Birmingham, University of Cambridge, University of London, Coventry University, King's College, University of Manchester, University of Oxford and UCL. The Ambassador of Ukraine to the UK Vadym Prystaiko was also present. The videoconference was organised in support of Ukrainian researchers and students in the UK over the invasion of Ukraine by Russia. Professor PJ Skabara addressed President Zelensky and introduced questions from the Glasgow University Ukrainian Society. The event gave outstanding morale support for Ukrainian academics and students across the UK, including three Ukrainian postdoctoral researchers from Professor Skabara's group who are employed on EPSRC projects.
Year(s) Of Engagement Activity 2022
URL https://www.youtube.com/watch?v=2Jylna8P7Tw
 
Description Visit CPI Sedgefield 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact visit to discuss collaborative opportunities, exchange visits and to update on the progress to date. Planned visit to Glasgow agreed
Year(s) Of Engagement Activity 2019
 
Description meeting with the local MP Carol Monaghan 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Policymakers/politicians
Results and Impact A 1 hour meeting with Carol Monaghan, MP for Glasgow North West. To raise the profile of the reserach work being conducted and the potential impact for the local and Scottish economy.
Year(s) Of Engagement Activity 2019