Low cost high energy density anode for stationary energy storage

Lead Research Organisation: University College London
Department Name: Chemistry

Abstract

This project is to investigate the feasibility of bulk synthesis of a low cost high energy density anode for sodium ion batteries (NIB). Specifically, the research will involve synthesis of nanoparticle materials (at UCL) which will then be made into small rechargeable sodium ion batteries and tested in SHARP uk labs. The project will then involve scale-up of the highest performing materials and they will be made into larger cells which will validate the materials on scale-up.
Until recently, NIB technology had been neglected and work focussed on Li ion based systems. Developments in materials chemistry and electrode fabrication are necessary to ensure NIB is a commercially viable alternative to Li ion batteries (LIB). The invention of new materials for use as anodes in these batteries is an important step in preparing the technology for market. We have identified a range of materials which we believe are suitable for use as high energy density anodes. We propose to synthesise a number of these materials, using state of the art synthesis facilities, and subject the new materials to extensive testing and optimise the most suitable materials for use in an energy storage device. As well as developing an optimised anode material for NIB (as well as validate new manufacturing facilities up to pilot plant scale) we anticipate that the materials developed as part of this project are likely to find uses in other technologies, both new and existing, e.g. LIB and supercapacitors.

Planned Impact

The use of rechargeable domestic energy storage devices will have an impact on the Uk with benefits to consumers, energy suppliers and industry in the UK, spanning all three elements of the trilemma.
Impact on Consumers: Peaks in domestic electricity demand do not coincide with peak solar generation. PV consumers export during the day and buy electricity from the grid during the evening. Storage is a clear partner and is often seen as being essential to the mass uptake of renewables. Installation of a storage system which charges during peak generation and discharges during the evening could reduce the consumer's electricity bill by 15-20% and ensure a continuous supply - greater self-sufficiency with some households being almost "off-grid". If electricity suppliers were to charge a premium for periods of peak demand the savings made by installing a storage system would be greater. The use of renewable in this way will reduce the possibility of blackouts and not only gives consumers confidence in the security of their supply but also encourages individuals to take more responsibility for their own carbon footprint. If individual systems are connected, savings for consumers could be even greater. Access to cheaper electricity in this way may also result in an increase in the number of electric vehicles on the road - reducing the number of petrol and diesel vehicles.
Impact on energy suppliers: Such systems could also be utilised by energy suppliers as part of the distribution network to smooth demand. The ability to store electricity in homes also offers the possibility of the UK being more resistant to adverse weather conditions which can sometimes lead to power shortages due to part of the grid being damaged. Of course these technologies would be even more important in remote parts of the UK or the world which are off grid, significantly improving quality of life.
Impact on Uk industry: here are also financial benefits for UK industry as high electricity costs result in some manufacturers stopping production for periods during the winter. Storage systems could be used to spread the demand more evenly, e.g. charging during the weekend when many factories are closed. Continuous manufacture in this way will result in greater productivity and efficiencies for UK industry. Installation of energy storage in homes and workplaces will mean that electricity is used nearer to where it is generated and also that peak demand will be lower. Energy storage which is distributed in this way will significantly reduce the cost of upgrading the transmission network. Another benefit of local consumption is a reduction in the losses during transmission (typically 10%) - a financial and environmental benefit.
Government / Public Sector:Emissions from fossil fuel burning plants are associated with a number of adverse health effects and enabling a switch to renewables will lead to a reduction in airborne pollution, in addition to combatting climate change. With legislation to guarantee a cascade of international agreements to reduce CO2, vehicles emissions and other greenhouse gases to acceptable levels, battery technologies for domestic storage are of prime importance to policy makers and legislators. The relevant applications include developing an uninterrupted power supplies (useful during brownouts), microgeneration and storage of energy (or to feed into the grid) which could include that generated from renewables such as solar energy.

Publications

10 25 50
 
Description we have discovered that we can make less than 50 nm sn particles which are stable to be cycled as na ion batteries
we have discovered that the electrode structure and conductivity needs improvement to give higher capacity
we have discovered we can scale up without adverse effect on the performance
Exploitation Route It could be taken forward as follows
the sn oxides could be developed further as transparent conducting oxides
or if we can do more work to develop the carbons matrix we can improve the capacity even further for na ion batteries. i am now confident that these ideas and the coating appraoch can be used on some of the Faraday FAST START projects for cathode materials to protect them for example from degradation. [ new grant ESPRC Faraday Fast Start project "Towards a Comprehensive Understanding of Degradation Processes in EV Batteries" Grant ref: FIRG001 (consortium agreement being signed, PI Clare Grey, Cambridge)]
Sectors Energy,Environment

 
Description The research from this award has forged the foundations for UCL to approach various industrial partners and push the Na-ion technology investigated to market. This will allow for future development and availability of products, specialised jobs and green technology for use within the UK, and internationally. The dissemination of the results from this award will also aid other researchers to forward their understanding of Na-ion technology, and further boost their industrial outputs. The continuous and green method of the process used to produce our materials has also been showcased on an international level. This will allow industrial partners with interest in other potential materials to approach the team at UCL, providing opportunities for further industrial outputs. UCL has now been invited to be a partner on the Fraday HQ bid and three academics including me were invited to be coinvestgiators. So this research and our expertise has been recognised. We have also won further funding in energy storage which will cover Na ion technologies [ grant ESPRC grant; ISCF Wave 1: The JUICED Hub [Joint University Industry Consortium for Energy (Materials) and Devices Hub (EP/R023662/1)]
First Year Of Impact 2017
Sector Chemicals,Energy
 
Description sharp work on sn anodes for na ion 
Organisation Sharp Laboratories of Europe Ltd
Country United Kingdom 
Sector Private 
PI Contribution we manurafactured new anode nanomaterials and tested them with SHARP for na ion batteries we looked at the advantages of different carbons in the cells we have provided Sn and SnO2 NANOPARTICLES to the partner company and showed that these materials are very stable to cycling in na-ion batteries we have allowed them to test a larger scale up cell for nanomaterials in Na ion batteries. they have begun to understand the key factors that affect stability in such Na ion batteries we will now publish the data and work on the exploitation plan when the project ends.
Collaborator Contribution This was an innovate Uk project and we have received a large amount of know how and support and also equipment and chemcials to allow us to learn how to manufacture sodium ion batteries safely. This has included 1:1 training out UCL pdras in the labs in oxford as well as masters students. UCL is now one of the few labs in the Uk universities that have a capability to make and test sodium ion batteries. the company tested the nanomaterials in cells and shared findings with us the company made larger scale cells to validate scaleup
Impact knowhow on how to make na ion batteries (multidisciplinary) training for researchers at ucl on how to make na ion batteries (multidisciplinary) a thriving masters and phd research programme now on na ion batteries which will continue input to masters projects (multidisciplinary)
Start Year 2016
 
Title Co-current mixer and method for precipitating nanoparticles 
Description this is a confined jet mixer that allow mixing of supercritical water and metal salts at room temperature in water. This prevents bloacking and is a major development that is highly scalable and still makes very good quality nanoceramics 
IP Reference EP2576036 
Protection Patent granted
Year Protection Granted 2013
Licensed No
Impact its allowed me to develop the process so well that we have continued to get industry and academic funding to carry out nanomaterials research and develop new research areas