Achieving higher solar cell performance through international collaboration
Lead Research Organisation:
Northumbria University
Department Name: Fac of Engineering and Environment
Abstract
I have recently developed two new solar cells based on semiconductor nanotechnologies that offer the potential for higher efficiency and lower cost. In order to progress these technologies, specialist facilities are now required to gain a deeper scientific understanding of their advantages and to develop new implementations which will make renewable energy generation more competitive.
In this Overseas Travel Grant, I will access the required specialist facilities and related expertise by taking my solar cells to laboratories in Singapore (Nanyang Technical University) and Germany (Fraunhofer Institute for Solar Energy) and performing three novel experiments. These experiments involve state-of-the-art equipment which are not readily available in the UK for example, at Nanyang Technical University, I will study the current pathways in my solar cells at the atomic scale as well as combining them with other solar cell technology to assess the potential for new low-cost, high efficiency solar cells that can be scaled up sustainably. Similarly, at the Fraunhofer Institute for Solar Energy, I will expose my solar cells to high optical concentration (more than 500 times the power of the sun at the Earth's surface) to maximise the contribution from nanometre sized quantum dots which capture more of the incident sunlight.
Importantly, this research programme will also enable me to initiate new collaborations with world-leading experts. Through the exchange of knowledge and skills, it offers a unique professional development opportunity that I will exploit to benefit scientific research and innovation in the UK. This will be achieved by generating essential feasibility data for a deeper major programme of collaborative research that will involve industrial partners. The programme also contains several important opportunities for dissemination with the wider energy materials scientific community but also with young people and school teachers that are engaged with science, technology, engineering and mathematics subjects.
In this Overseas Travel Grant, I will access the required specialist facilities and related expertise by taking my solar cells to laboratories in Singapore (Nanyang Technical University) and Germany (Fraunhofer Institute for Solar Energy) and performing three novel experiments. These experiments involve state-of-the-art equipment which are not readily available in the UK for example, at Nanyang Technical University, I will study the current pathways in my solar cells at the atomic scale as well as combining them with other solar cell technology to assess the potential for new low-cost, high efficiency solar cells that can be scaled up sustainably. Similarly, at the Fraunhofer Institute for Solar Energy, I will expose my solar cells to high optical concentration (more than 500 times the power of the sun at the Earth's surface) to maximise the contribution from nanometre sized quantum dots which capture more of the incident sunlight.
Importantly, this research programme will also enable me to initiate new collaborations with world-leading experts. Through the exchange of knowledge and skills, it offers a unique professional development opportunity that I will exploit to benefit scientific research and innovation in the UK. This will be achieved by generating essential feasibility data for a deeper major programme of collaborative research that will involve industrial partners. The programme also contains several important opportunities for dissemination with the wider energy materials scientific community but also with young people and school teachers that are engaged with science, technology, engineering and mathematics subjects.
Planned Impact
The programme has two major areas of impact: academic and societal.
Academic impact includes the achievement of transformative device results which will be communicated through prestigious scientific journals and attendance at a major international conference. By addressing key issues in solar energy materials research (such as efficiency and cost), the programme will benefit researchers worldwide and naturally attract industrial attention. The programme is a critical element in the development of my research activities as it will enable me to increase my international profile; identify new areas of energy materials research; establish and join international research efforts; and transfer new techniques to my home institution. Furthermore the programme will result in scientific discoveries which will form the basis of broader and deeper programmes of research. These programmes will benefit UK research and innovation through the potential creation of intellectual property and training of PhD students and post-doctoral research associates.
Societal impact includes the development of renewable energy technology that will reduce carbon emissions and potentially help contribute to the UK's ambitious 2050 targets. In addition, the programme will engage directly with young people and school teachers through two workshops aimed at increasing engagement with science, technology, engineering and mathematics subjects. These workshops will draw on content derived from experiments performed in the programme using state-of-the-art experimental equipment to obtain fundamental scientific insight into renewable energy and nanotechnologies.
Academic impact includes the achievement of transformative device results which will be communicated through prestigious scientific journals and attendance at a major international conference. By addressing key issues in solar energy materials research (such as efficiency and cost), the programme will benefit researchers worldwide and naturally attract industrial attention. The programme is a critical element in the development of my research activities as it will enable me to increase my international profile; identify new areas of energy materials research; establish and join international research efforts; and transfer new techniques to my home institution. Furthermore the programme will result in scientific discoveries which will form the basis of broader and deeper programmes of research. These programmes will benefit UK research and innovation through the potential creation of intellectual property and training of PhD students and post-doctoral research associates.
Societal impact includes the development of renewable energy technology that will reduce carbon emissions and potentially help contribute to the UK's ambitious 2050 targets. In addition, the programme will engage directly with young people and school teachers through two workshops aimed at increasing engagement with science, technology, engineering and mathematics subjects. These workshops will draw on content derived from experiments performed in the programme using state-of-the-art experimental equipment to obtain fundamental scientific insight into renewable energy and nanotechnologies.
Organisations
People |
ORCID iD |
Neil Beattie (Principal Investigator) |
Publications
Campbell S
(2022)
Recovery mechanisms in aged kesterite solar cells
in ACS Applied Energy Materials
Qu Y
(2019)
Real-Time Electron Nanoscopy of Photovoltaic Absorber Formation from Kesterite Nanoparticles
in ACS Applied Energy Materials
Description | In May 2018, a PDRA from my team visited NTU Singapore to perform state-of-the-art in situ transmission electron microscopy on Cu2ZnSnS4 (CZTS) nanoparticle inks. The objective of this experiment was to investigate, at the nanometre scale, a sulphur-selenium exchange process that occurs during the fabrication of Earth-abundant thin film solar cells. This experiment was highly novel and has never been done before. The main findings were that the chalcogen atom exchange process in the quaternary compound CZTS is distinct and independent of grain growth. This insight has allowed us to uncover new understanding about the disorder in kesterite solar cells and has been leveraged to make more efficient solar cells. The work was done in collaboration with world-leading TEM experts at both NTU and NUS, Singapore. The main collaborator at NTU is Dr Martial Duchamp. |
Exploitation Route | These findings are highly novel and a manuscript is in preparation for submission to Nature Materials. Once published, the findings will enable the field of researchers working globally on CZTS solar cells to potentially make more efficient devices. In turn, this has the potential to accelerate the commercialisation of a sustainable thin film photovoltaic technology that has can help to meet our increasing demand for electricity. |
Sectors | Aerospace, Defence and Marine,Construction,Electronics,Energy,Healthcare,Leisure Activities, including Sports, Recreation and Tourism,Manufacturing, including Industrial Biotechology,Transport |
Description | This award was an overseas travel grant which created a fruitful collaboration with Dr Martial Duchamp at Nanyang Technological University in Singapore in the specific area of real-time in situ transmission electron microscopy (TEM). In addition to two publications in ACS Applied Energy Materials (the earliest of which has received 1151 article views source: ACS website), collaboration with NTU established through this programme has created wider impact. During the programme, the PI visited (for the first time) the Energy Research Institute at NTU which consequently became a formal partner in the ESPRC Centre for Doctoral Training in Renewable Energy Northeast Universities (EP/S023836/1) which is led by the PI. Subsequent to this award, Dr Duchamp was also a keynote speaker at the EPSRC-ISCF North East Centre for Energy Materials (EP/R021503/1) International Conference for Energy Materials and Interfaces. Following the programme, Dr Yongtao Qu, an early career researchers from Northumbria University visited NTU to perform in situ TEM measurements. |
First Year Of Impact | 2019 |
Sector | Energy |
Impact Types | Cultural,Economic |
Description | Photovoltaic Paint |
Amount | £237,837 (GBP) |
Funding ID | EP/T005491/1 |
Organisation | Northumbria University |
Sector | Academic/University |
Country | United Kingdom |
Start | 07/2019 |
End | 06/2021 |
Description | Cavendish Laboratory, University of Cambridge |
Organisation | University of Cambridge |
Department | Department of Physics |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | Provided solar cell device design. |
Collaborator Contribution | 1. Molecular beam epitaxial growth of III-V semiconductor wafers for solar cells 2. Use of cleanroom facilities, materials and semiconductor processing expertise to process wafers into solar cell devices |
Impact | Provision of letter of support to support ESPRC CDT bid resulting in University of Cambridge becoming formal partner via £60,000 in kind support and access to Cavendish III PUBLICATIONS: Quantum engineering of InAs/GaAs quantum dot based intermediate band solar cells NS Beattie, P See, G Zoppi, PM Ushasree, M Duchamp, I Farrer, ... ACS Photonics 4 (11), 2745-2750 Analysis of InAs/GaAs quantum dot solar cells using Suns-Voc measurements NS Beattie, G Zoppi, P See, I Farrer, M Duchamp, DJ Morrison, RW Miles, ... Solar energy materials and solar cells 130, 241-245 |
Start Year | 2014 |
Description | Collaboration with Dr Martial Duchamp, in situ TEM, NTU Singapore |
Organisation | Nanyang Technological University |
Country | Singapore |
Sector | Academic/University |
PI Contribution | We have made two visits to NTU in the last 2 years (one within the grant period) and on each visit provided samples of inorganic semiconductors used to make photovoltaic devices. The most promising work relates to providing our CZTS nanoparticle ink which was studied in a unique in situ experiment in the TEM. |
Collaborator Contribution | Dr Duchamp performed the microscopy and facilitated access to additional unique microscopy facilities at NUS Singapore. Dr Duchamp provided the data and helped with the analysis. |
Impact | Journal article output in preparation for submission to Nature Materials Conference abstract describing the work submitted to ICMAT 2019, Singapore |
Start Year | 2017 |
Description | Collaboration with Dr Sukhdeep Dhillon, Ecole Normale Superieure, Paris |
Organisation | École Normale Supérieure, Paris |
Country | France |
Sector | Academic/University |
PI Contribution | Provide samples to Dr Dhillon's team in Paris and helped with optical measurements |
Collaborator Contribution | Dr Dhillon's team performed specialist THz spectroscopy measurements on novel inorganic semiconductor samples made from Cu2ZnSnS4 and helped with data analysis. |
Impact | None |
Start Year | 2018 |
Description | Continued academic collaboration with NTU, Singapore |
Organisation | Nanyang Technological University |
Country | Singapore |
Sector | Academic/University |
PI Contribution | Provided CZTS nanoparticle ink samples for unique in situ annealing experiments in a transmission electron microscope. NB (Necem CI) and YQ (Necem PDRA) travelled to NTU in Dec 17 and May 18 respectively to perform these experiments in collaboration with partners. |
Collaborator Contribution | Partners provided the microscopy and specialist facilities. |
Impact | The collaboration involves, physics, chemistry, engineering and has a published output: Quantum engineering of InAs/GaAs quantum dot based intermediate band solar cells NS Beattie, et al, ACS Photonics 4 (11), 2745-2750 (2017). The partnership was also leveraged together with Prof. Stimming's (NECEM PI) collaboration with the Energy Research Institute at NTU (ERI@N) to secure a letter of support for a CDT grant application (EP/S023836/1). |
Start Year | 2016 |
Description | Energy Research Institute @ NTU |
Organisation | Nanyang Technological University |
Country | Singapore |
Sector | Academic/University |
PI Contribution | As a result of the award, the PI expanded the relationship with NTU, Singapore, resulting in the Energy Research Institute (ERI@N) becoming a formal partner on the £5.4M EPSRC Centre for Doctoral Training in Renewable Energy Northeast Universities (ReNU, EPS023836/1). |
Collaborator Contribution | ERI@N provided a letter of support to the CDT signed by the Co-director, Professor Chan Siew Hwa with a value of £60,000 in in-kind support. As a result of this partnership ERI@N will host ReNU students during the lifetime of the CDT for short placements. |
Impact | EPSRC Centre for Doctoral Training in Renewable Energy Northeast Universities (ReNU, EPS023836/1). This programme will train 65 doctoral candidates in the Northeast of England between 2019 and 2027. |
Start Year | 2019 |
Description | Visit to Fraunhofer Institute for Solar Energy |
Organisation | Fraunhofer Society |
Department | Fraunhofer Institute for Solar Energy Research |
Country | Germany |
Sector | Charity/Non Profit |
PI Contribution | Provided III-V quantum dot solar cells for measurement under specialist concentration facilities at FISE, Germany within the team of Dr Gerald Siefer. |
Collaborator Contribution | Dr Siefer's team measured the solar cells under concentrated sunlight. |
Impact | None |
Start Year | 2018 |
Description | 10th International Conference on Materials for Advanced Technologies |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Oral presentation of in situ transmission electron microscopy results on Cu2ZnSnS4 nanoparticle ink solar cells in Symposium A "Investigation of Materials at the Nanoscale using Electrons and X-rays". This conference was part of the prestigious Materials Research Society and took place in the Marina Bay Sands Hotel, Singapore. |
Year(s) Of Engagement Activity | 2019 |
URL | http://icmat2019.mrs.org.sg/symp-list/symp-a/ |
Description | EMRS Poster Presentation, Strasbourg |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Postgraduate students |
Results and Impact | Attendance and presentation of a poster detailing experimental results at the European Materials Research Society conference in Strasbourg. |
Year(s) Of Engagement Activity | 2018 |
URL | https://www.european-mrs.com/meetings/2018-spring-meeting |
Description | NECEM International Conference on Energy Materials |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Oral presentation at the NECEM International Conference on Energy Materials details in situ transmission electron microscope experiments performed on Cu2ZnSnS4 nanoparticle inks. |
Year(s) Of Engagement Activity | 2019 |
Description | Neil Beattie Talk at Ecole Normale Superieure |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Postgraduate students |
Results and Impact | This talk involved presenting research findings at one of the most prestigious institutions globally. |
Year(s) Of Engagement Activity | 2018 |
Description | PDRA research talk at School of MSE, NTU, Singapore |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Postgraduate students |
Results and Impact | During their visit to NTU to perform in situ TEM measurements, the PDRA gave a research seminar to the group at the School of MSE. |
Year(s) Of Engagement Activity | 2018 |