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2-Dimensional Materials for Novel Battery Electrodes

Lead Research Organisation: Queen Mary University of London
Department Name: School of Engineering & Materials Scienc

Abstract

There is an urgent need for the development and manufacture of advanced batteries for the electrification of vehicles in order to enable long, energy efficient trips on a single, fast charge with minimal loss of capacity and exceptionally high safety standards. Critical to achieving this aim is improving the capability of battery technology. The UK requires a home-built industry in lithium ion batteries. To achieve this objective, the UK government has initiated the Faraday Challenge (£246M over 5 years) and Faraday Institution, which have highlighted materials innovation as an essential ingredient for realising batteries of the future.

During my career to date, I have developed a transformative new technology which allows for the scalable production of novel layered compounds from undamaged liquids containing undamaged, individualised 2-dimensional (2D) materials that can act as building blocks to achieve engineered battery electrodes with significantly improved capacity, durability and power to enable the widespread electrification of vehicles. Importantly, and in contrast to most competing methods, the process of fabricating the single layered materials is truly scalable. Part of the innovation process of this project will be to accelerate commercialisation of these 2D materials through creation of a UCL spin-out company to manufacture 2D materials on a large scale.

The Advanced Propulsion Centre (APC) has set targets for electrical energy storage, to increase energy and power density whilst reducing price. Novel Lithium-ion and sodium-ion electrodes with increased capacity and kinetics that are cost efficient can contribute to this goal. In this project, working in the Department of Chemical Engineering, UCL, I will create new layered material constructs for battery electrodes, which will be tuned to the needs of the electric vehicle manufacturers. These novel layered material electrodes will be developed from lab scale to pilot scale in collaboration with Warwick Manufacturing Group (WMG). Novel in-situ characterisation techniques will be developed for advanced characterisation of battery materials. Thomas Swan Ltd. will assist with knowledge in the scale-up of solutions of 2D materials, and provide commercial materials. IP will be developed in both the synthesis of the novel layered materials and the scaled-up processing steps required for optimised electrode performance in a car battery.

Planned Impact

This fellowship will produce next-generation electrode materials for Li/Na-ion batteries which will deliver on cheap, energy and power dense electrode materials geared towards 'the development and manufacture of batteries for the electrification of vehicles'. By doing so, this fellowship will build upon the UK central government's commitment to capitalise on the expanding battery technology landscape. The green paper 'Building our Industrial strategy' published in 2017 highlights this- 'Given the UK's underlying strengths in science and energy technology, we want to be a global leader in battery technology'. This has been followed by the government's creation of the Faraday Challenge (£246M over five years).
To ensure the UK Government's recent decision to ban the sale of petrol and diesel cars from 2040 is achieved, advanced batteries for the electrification of vehicles is required. In this fellowship I will develop and scale-up advanced electrode materials to increase energy and power density of batteries, whilst reducing price, in line with the needs of electric car manufacturers. This will have key benefits in decarbonisation and air quality improvements. The general public will be benefit through improved quality of life with environmental improvements, better consumer products and electric vehicles.
Being able to produce and scale-up truly novel battery materials in a short amount of time will go a long way towards meeting many of the targets outlined in the Faraday Challenge, and I believe that this technology represents a route to short and medium term economic growth in the sector of energy storage. During this fellowship, a spin-out company will be formed to scale-up and commercialise the production of 2D material solutions. The development of IP and a spin-out company in a completely new area of energy storage materials will have wide ranging economic benefit in the high tech manufacturing of cutting edge materials in a burgeoning sector.
By working with industry leaders such as WMG, who will provide expertise in the scale up to pouch cell manufacture and Thomas Swan Ltd. who will provide commercial commercially available materials for comparison to the NLMs and expertise in nanomaterial production scale-up, this project will be positioned to be commercially relevant. Working with these partners and expanding upon existing networks will enable this project to deliver prototype batteries catered to electric vehicle manufacturers in the UK. This will facilitate the primary aim of this fellowship: to synthesise and optimise novel electrodes for the development and manufacture of batteries for the electrification of vehicles.

Work carried out during this fellowship, and training for the PDRA, the PhD student and I will add to UK's skill base in battery development. In-situ techniques will be developed to boost the UK's capabilities in the area of developing novel electrodes for batteries (and other areas). By developing UCell (https://www.ucl.ac.uk/ucell), a current Electrochmical Innovation Lab (EIL) outreach initiative, to incorporate novel battery electrodes, I have a vehicle for engaging the public. The Hydrogen fuel cell system with battery bank will be used as a platform to talk about the development of novel battery electrodes, powering events around the UK with accompanying workshops for the general public and schools.
This Fellowship will stimulate the economy, drive battery development for the electrification of vehicles, and educate the community on why investment in these technologies is vital.

Publications

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Greaves F (2025) Hydrogen Induced Phase Transition in TiZrNbHfV 1- x Ta x High Entropy Alloys in The Journal of Physical Chemistry C

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Leach AS (2021) A novel fuel cell design foroperandoenergy-dispersive x-ray absorption measurements. in Journal of physics. Condensed matter : an Institute of Physics journal

Related Projects

Project Reference Relationship Related To Start End Award Value
EP/S001298/1 01/06/2018 05/01/2020 £612,657
EP/S001298/2 Transfer EP/S001298/1 04/04/2020 01/01/2023 £418,627
 
Description So far I have developed a way of looking at batteries whilst in operation with neutrons. This will allow us to understand the behaviour materials inside batteries whilst they operate better, with a veiw to improving battery performance in the future. The development of this particular cell has gone though a few iterations now and I hope that after this year we will get some results that show the value of the combination of this cell with total neutron scattering.


Over the last year I have also published papers on: electrospun lignin derived carbons as electrodes for redox-flow batteries and a novel Pt/graphene material for hydrogen fuel cells that vastly outlasts commercial fuel cell catalysts (patent published recently).

In lieu of labwork during covid two review type papers were published - one on neutrons for Na-ion batteries, and one on the potential use of cannabis in electrochemistry.

A paper was also publish on the design and comissioning of an operando fuel cell for EXAFS measurements
Exploitation Route The equipment I have designed and built will be available to other users who was to look at any material under potential with neutrons. The materials and methods to make these materials will also be useful in a variety of applications. I hope to further develop the Pt/graphene material so that we can scalably produce the material to test in large full PEM fuel cells - this work is currently ongoing. There has been progress in 2D materials for battery electrodes, but that is as yet unpublished.
Sectors Chemicals

Electronics

Energy

Transport

URL https://phys.org/news/2020-07-scientists-material-longer-lasting-fuel-cells.html
 
Description Ex-situ Li-ion battery experiment on NIMROD
Amount £50,000 (GBP)
Organisation ISIS Neutron Source Facility 
Sector Learned Society
Country United Kingdom
Start 03/2022 
End 03/2022
 
Title Electrochemical cell for total neutron scattering 
Description In a multi disciplinary collaboration between Neutron scientists at ISIS and myself and a PhD student, bringing battery expertise. In order to understand the behaviour of materials inside a battery, studies have to be done in-situ. By using the NIMROD instrument we can uniquely look at the structural changes within battery materials over a large legthscale. In order to facilitate this we have designed and manufactured an in-situ cell. This in-situ cell is a small battery itself, the casing of which allows neutrons to pass through in a way that the effect of the casing on the scattering of the neutrons can be completely removed. The current status is that we have designed manufactured and tested this cell, and are now on our 2nd iteration of the cell, to be used in April/May 2021 in the neutron beamline. 
Type Of Material Improvements to research infrastructure 
Year Produced 2020 
Provided To Others? No  
Impact Still to be determined. 
 
Title Nanomaterial Preparation Method 
Description Described is a method of preparing transition metal nanoparticles on a graphene support, in which a tertiary graphite intercalation compound is provided with intercalated metal ions such that the tertiary graphite intercalation compound comprises a graphene sheet having a negative charge. The graphene sheet is contacted with a transition metal salt to cause reduction of the transition metal salt by the graphene sheet, and to form transition metal nanoparticles. Also described are products arising from the method, and uses of those products. 
IP Reference US2020407227 
Protection Patent application published
Year Protection Granted 2020
Licensed No
Impact None as of yet, but hoping to start a spin out company based on this IP as soon as possible.