Nickel Superalloy Design for Corrosion Resistance
Lead Research Organisation:
Imperial College London
Department Name: Materials
Abstract
My fellowship will lead a research programme employing state of the art experimental and computational techniques to provide new, fundamental insight into the environmental degradation of nickel superalloys and steels that occur as a result of interactions with the corrosive gaseous species they encounter in-service. I have published some preliminary work from my corrosion and oxidation research program, though the full potential benefits for the development of corrosion resistant high temperature materials, have barely been explored. I plan to address these questions through advanced characterisation of samples exposed to corrosive environments in laboratory furnaces, during high temperature mechanical tests and a study of ex-service components provided by my industrial collaborators. The results will then be used to design a new generation of alloys, whose corrosion resistance will be tailored to their specific applications.
To maximise the impact of my research, I will work closely with my industrial collaborators such as Rolls-Royce plc, as well as my academic collaborators, including Prof Michael Moody (Atom probe Tomography Group, University of Oxford), to characterise the samples, inform alloy design and produce new superalloys with improved corrosion resistance. Corrosion research is extremely timely and globally important with potential for substantial future savings and component lifetime extension.
To maximise the impact of my research, I will work closely with my industrial collaborators such as Rolls-Royce plc, as well as my academic collaborators, including Prof Michael Moody (Atom probe Tomography Group, University of Oxford), to characterise the samples, inform alloy design and produce new superalloys with improved corrosion resistance. Corrosion research is extremely timely and globally important with potential for substantial future savings and component lifetime extension.
Planned Impact
My research will lead to the development of improved corrosion-resistant nickel-based superalloys. Where applicable, intellectual property rights arising from my fellowship will be protected for valuable innovations with significant commercial potential.
The Institute of Materials, Minerals and Mining (IoM3),of which I am an active member, provides me with mechanisms to reach other UK based companies with interests in corrosion resistant high temperature materials. I am a member of their High Temperature Materials Committee, which puts me in contact with industrial partners and academic collaborators on a regular basis. I will continue to attend a broad range of meetings, workshops and conferences to ensure dissemination of my research. To ensure that my work reaches industrial as well as academic audiences, I intend to organise a workshop, in collaboration with the High Temperature Materials Committee. The structure of this workshop will involve long overview presentations as well as allowing time for discussion and for setting up collaborations.
For an academic audience, the primary dissemination route will be through peer-reviewed publications and conference presentations. My fellowship will continue to produce high-quality peer-reviewed publications and submit them to respected journals in the field. Publications will be open access, therefore attracting the widest possible readership particularly from companies which may not have access to publications otherwise.
Direct industrial collaborations with leading UK enterprises such as Rolls-Royce plc, Good Fabrications Performance Exhausts and others will be direct beneficiaries of the innovations arising from my research fellowship.
Outreach and public engagement are of particular importance to me. My plan to increase the impact of my research includes the publication of articles for The Naked Scientist and Materials World, visits to local schools and public talks. I am a registered STEM ambassador and plan on continuing that work throughout my fellowship and involving my students in outreach programs too, with a particular focus on equality, diversity and women in engineering. My membership of the IoM3 High Temperature Materials Committee facilitates my involvement in outreach and public engagement activities through publications aimed at a non-specialist audience and by providing me with an education slideshow aimed at school children about high temperature materials and their uses.
Through these dissemination paths, my research will be reaching the widest possible audience of academic collaborators, industrial partners and the general public.
The Institute of Materials, Minerals and Mining (IoM3),of which I am an active member, provides me with mechanisms to reach other UK based companies with interests in corrosion resistant high temperature materials. I am a member of their High Temperature Materials Committee, which puts me in contact with industrial partners and academic collaborators on a regular basis. I will continue to attend a broad range of meetings, workshops and conferences to ensure dissemination of my research. To ensure that my work reaches industrial as well as academic audiences, I intend to organise a workshop, in collaboration with the High Temperature Materials Committee. The structure of this workshop will involve long overview presentations as well as allowing time for discussion and for setting up collaborations.
For an academic audience, the primary dissemination route will be through peer-reviewed publications and conference presentations. My fellowship will continue to produce high-quality peer-reviewed publications and submit them to respected journals in the field. Publications will be open access, therefore attracting the widest possible readership particularly from companies which may not have access to publications otherwise.
Direct industrial collaborations with leading UK enterprises such as Rolls-Royce plc, Good Fabrications Performance Exhausts and others will be direct beneficiaries of the innovations arising from my research fellowship.
Outreach and public engagement are of particular importance to me. My plan to increase the impact of my research includes the publication of articles for The Naked Scientist and Materials World, visits to local schools and public talks. I am a registered STEM ambassador and plan on continuing that work throughout my fellowship and involving my students in outreach programs too, with a particular focus on equality, diversity and women in engineering. My membership of the IoM3 High Temperature Materials Committee facilitates my involvement in outreach and public engagement activities through publications aimed at a non-specialist audience and by providing me with an education slideshow aimed at school children about high temperature materials and their uses.
Through these dissemination paths, my research will be reaching the widest possible audience of academic collaborators, industrial partners and the general public.
Publications
Anzini E
(2020)
The effect of manganese and silicon additions on the corrosion resistance of a polycrystalline nickel-based superalloy
in Corrosion Science
Gasparrini C
(2022)
Water Chemistry in Fusion Cooling Systems: Borated Water for DTT Vacuum Vessel
in IEEE Transactions on Plasma Science
Gasparrini C
(2024)
Corrosion of 316L exposed to highly concentrated borated water used as shield in nuclear fusion experimental reactors cooling circuits
in Corrosion Science
Hiew Sze Kei S
(2023)
A Review of the Factors That Can Increase the Risk of Sulfide Stress Cracking in Thermomechanical Controlled Processed Pipeline Steels
in Advanced Engineering Materials
Kim S
(2023)
Atom probe analysis of BaTiO3 enabled by metallic shielding
in Scripta Materialia
Pedrazzini S
(2023)
Effect of Substrate Bed Temperature on Solute Segregation and Mechanical Properties in Ti-6Al-4V Produced by Laser Powder Bed Fusion
in Metallurgical and Materials Transactions A
Pek M
(2022)
Development of a Novel, Impurity-Scavenging, Corrosion-Resistant Coating for Ni-Based Superalloy CMSX-4
in High Temperature Corrosion of Materials
Rodenkirchen C
(2023)
Effect of Alloying on the Microstructure, Phase Stability, Hardness, and Partitioning Behavior of a New Dual-Superlattice Nickel-Based Superalloy
in Metallurgical and Materials Transactions A
Rodenkirchen C
(2022)
A review on atom probe and correlative microscopy studies of corrosion in nickel-based superalloys
in MRS Bulletin
Description | Corrosion and high temperature oxidation often limit the service life of aero-engine components, oil and gas and chemical plants. Their corrosion and oxidation resistance will depend on the chemical composition of the alloy, which is often very complex (up to 10-12 elements at a time). The effect of each of them needs to be understood in order to understand, predict and influence the corrosion resistance of the overall alloy. The effect of svarious elements on the corrosion resistance of nickel-based superalloys was studied and published so far as part of this award. The effect of oxidation and under-deposit corrosion of steel was also investigated. This project is ongoing and further elemental compositions are being investigated. |
Exploitation Route | The findings are published in an open access format, which can be taken by others and built upon. Also the industrial collaborators Rolls-Royce plc and Royal Dutch Shell are taking and implementing some of the outcomes in-service. All work on oil and gas is done to prevent oil/gas leaks and pipeline failures as well as to direct research towards renewable alternatives. |
Sectors | Aerospace, Defence and Marine,Chemicals,Energy,Transport |
Description | Our findings are informing new alloy compositions to be used in aero-engines by Rolls-Royce plc, the UK's flagship aero-engine manufacturer. Also wider discussions and dissemination with the manufacturers of industrial gas turbines for power generation (Siemens and Solar Turbines) are widening the industrial impact of this work and speeding up implementation. In addition, our work with Royal Dutch Shell has a direct service impact on their components. |
Sector | Aerospace, Defence and Marine,Chemicals,Energy,Transport |
Impact Types | Economic |
Description | Imperial College Africa Research fund |
Organisation | University of Mauritius |
Country | Mauritius |
Sector | Academic/University |
PI Contribution | £1000 was given from the Imperial College Africa Research fund to collaborate on a project with the University of Mauritius on the corrosion of steel structures exposed to their main port (salt water) conditions. It funded a Masters student |
Collaborator Contribution | Samples |
Impact | No outputs yet as the project just started, but we are aiming for a publication. |
Start Year | 2022 |
Description | Rolls-Royce studentships |
Organisation | Rolls Royce Group Plc |
Country | United Kingdom |
Sector | Private |
PI Contribution | This is a contrinution for two part-funded studentships, co-funded by EPSRC DTP awards and by Rolls-Royce, plus 4 summer internships which I supervised. |
Collaborator Contribution | Rolls-Royce co-funded and co-supervised the studentships. |
Impact | Two PhD students were funded, Declan Clarke and Cynthia Rodenkirchen. Declan Clarke has used the Diamond Light Source EPSIC national facility for electron microscopy. Cynthia has received an poster prize and an invitation to present said poster at the London Society for Women Engineer conference 2022. |
Start Year | 2019 |
Description | Shell studentships |
Organisation | Royal Dutch Shell plc |
Country | Netherlands |
Sector | Private |
PI Contribution | Three research studentships co-funded by Shell and the Qatar National Research Foundation have started working on the corrosion/oxidation of steels. In addition two more Shell iCASE awards have been given in support of the corrosion program, one who just started and one being recruited for next year |
Collaborator Contribution | Funding, intellectual contributions, samples |
Impact | Multi discipliary collaboration which has so far resulted in further funding and 5 people being recruited to do further research. In addition, the capabilities for research (equipment) are being improved thanks to the additional funding. We are about to submit our first publication from this partnership |
Start Year | 2020 |
Description | Great Exhibition Road Festival |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Public/other audiences |
Results and Impact | Workshop on corrosion at the Great Exhibition Road Festival, which was attended by 400 people |
Year(s) Of Engagement Activity | 2022 |
Description | Invited seminar - East Midlands Materials Society |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Professional Practitioners |
Results and Impact | Dr Stella Pedrazzini delivered the most well-attended seminar of the east midlands materials society. The society is part of our professional body: the Institute for Materials, Minerals and Mining. They organise talks to engage industry with academia. >60 people signed up on eventbrite and attended the talk. |
Year(s) Of Engagement Activity | 2020 |
URL | https://www.iom3.org/group/east-midlands-materials-society-emms/meeting.html?id=4ABFEA6C-0032-4792-9... |
Description | Invited seminar - Friedrich Alexander University of Erlangen Nuremberg |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Over 50 people (academics, students and staff) attended an invited seminar delivered by Dr Stella Pedrazzini at the Friedrich-Alexander university of Erlangen Nuremberg. The seminar led to helpful discussions and an exchange, in which a Prof from Erlangen came to deliver a seminar at Imperial College. |
Year(s) Of Engagement Activity | 2020 |
Description | Invited seminar - London Center for Nanotechnology |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Professional Practitioners |
Results and Impact | over 50 people attended a London Center for Nanotechnology lunchtime seminar delivered by Dr Stella Pedrazzini. The purpose of the seminar is cross-disciplianry engagement and this led to lots of questions and helpful discussions. It also led to a further invitation to present a brunch seminar at the Salters livery company. |
Year(s) Of Engagement Activity | 2020 |
Description | Invited seminar - University of Cambridge |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Professional Practitioners |
Results and Impact | ~50 students, staff and academics attended a lunchtime seminar delivered by Dr Stella Pedrazzini at the University of Cambridge. This led to helpful discussions and was part of a long-standing collaboration with their Rolls-Royce UTC. |
Year(s) Of Engagement Activity | 2020 |
Description | Invited seminar - University of Sheffield |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Professional Practitioners |
Results and Impact | 50 people attended an invited seminar delivered by Dr Stella Pedrazzini at the University of Sheffield, which sparked questions and discussions afterwards. |
Year(s) Of Engagement Activity | 2019 |
Description | Oxmet Technologies lunchtime seminar |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Professional Practitioners |
Results and Impact | 30 engineers from Oxmet technologies joined a lunchtime seminar delivered by Dr Stella Pedrazzini. Engagement was good, lots of questions and discussions followed. This sparked a new collaboration in the form of co-supervision of a PhD studentship and Masters project on corrosion of titanium alloys. |
Year(s) Of Engagement Activity | 2020 |
Description | Representative of Imperial College on a national outreach working group for materials science |
Form Of Engagement Activity | A formal working group, expert panel or dialogue |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Schools |
Results and Impact | I am a member of a national outreach working group who is writing articles for Materials world magazine, organising Q&A sessions with schools and building a website. The reach is mostly school children, and the purpose is to make the subject area of materials science more visible and gender balanced. |
Year(s) Of Engagement Activity | 2020,2021 |
Description | Rolls-Royce Lunch and Learn |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Professional Practitioners |
Results and Impact | Rolls-Royce Lunchtime seminar delivered to talk about corrosion to an audience of 50 Rolls-Royce engineers. Engaging with industry built a stronger link, in order to lead to faster implementaiton of the innovations from the EPSRC fellowship. |
Year(s) Of Engagement Activity | 2019 |
Description | Salters institute video series |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Series of videos for the Salters institute Chemistry club, which have been viewed ~150 times each on Youtube and more times onthe Salters institute chemistry club platform. HEre are some links: https://www.saltersinstitute.co.uk/chemistry-club-2/ https://www.youtube.com/watch?v=gyH4u7w6Ngs https://www.youtube.com/watch?v=BI-iGGXDyHM https://vimeo.com/680041610/cb9c3f60e2 |
Year(s) Of Engagement Activity | 2020,2021,2022 |
URL | https://www.youtube.com/watch?v=gyH4u7w6Ngs |
Description | Women in science talk |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Dr Stella Pedrazzini recorded a talk on inspirational women in science, which is now live on youtube. |
Year(s) Of Engagement Activity | 2021 |
URL | https://www.youtube.com/watch?v=iI1mCMdIFZQ |
Description | Youtube talk - Introduction to high temperature materials |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Dr Pedrazzini delivered a non-specialist talk on high temperature materials which was recorded and posted on youtube in July 2020, amounting to over 500 views to date and generating social media interest on Twitter and LinkedIn. |
Year(s) Of Engagement Activity | 2020 |
URL | https://www.youtube.com/watch?v=yKk6qkzzJgE&t=147s |