DEcarbonisation of Low TemperAture Process Heat Industry, DELTA PHI
Lead Research Organisation:
Loughborough University
Department Name: CREST
Abstract
The provision of low temperature industrial process heat in 2018 was responsible for over 30% of total industrial primary energy use in the UK. The majority of this, 75%, was produced by burning oil, gas and coal. Low temperature process heat is a major component of energy use in many industrial sectors including food and drink, chemicals and pharmaceuticals, manufacture of metal products and machinery, printing, and textiles. To reduce greenhouse gas emissions associated with low temperature process heat generation and meet UK targets, in the long term, will require a transition to zero carbon electricity, fuels or renewable heat. In the short term this is not feasible. We propose an approach in which heat is more effectively used within the industrial process, and/or exported to meet heat demands in the neighbouring area allowing significant reductions in greenhouse gas emissions per unit industrial production to be achieved and potentially provide an additional revenue source.
We are going to perform a programme of research that will help provide a no regrets route through the transition to eventual full decarbonisation. The research consists of,
i) fundamental and applied research to cost effectively improve components and systems performance for improved heat recovery, heat storage, heat upgrading, high temperature heat pumping and transporting heat with low loss, and
ii) develop new temporal modelling approaches to predict how these technologies can be effectively integrated to utilise heat across a multi-vector energy system and evaluate a transactive modelling platform to address the complexity of how heat can be reutilised economically within energy systems.
A series of case studies analysing the potential greenhouse gas reductions and cost benefits and revenues that may be achieved will be undertaken for selected industrial processes including a chemical production facility in Hull, to assess the benefits of i) individual technologies, ii) when optimally integrated within a heating/cooling network, or iii) when combined in a multi-vector energy system.
We are going to perform a programme of research that will help provide a no regrets route through the transition to eventual full decarbonisation. The research consists of,
i) fundamental and applied research to cost effectively improve components and systems performance for improved heat recovery, heat storage, heat upgrading, high temperature heat pumping and transporting heat with low loss, and
ii) develop new temporal modelling approaches to predict how these technologies can be effectively integrated to utilise heat across a multi-vector energy system and evaluate a transactive modelling platform to address the complexity of how heat can be reutilised economically within energy systems.
A series of case studies analysing the potential greenhouse gas reductions and cost benefits and revenues that may be achieved will be undertaken for selected industrial processes including a chemical production facility in Hull, to assess the benefits of i) individual technologies, ii) when optimally integrated within a heating/cooling network, or iii) when combined in a multi-vector energy system.
Planned Impact
The initial direct beneficiaries will be industries that can manufacture the newly developed range of systems. The next group of beneficiaries will be industries with large amounts of low/medium temperature process heat, e.g. food and drink, chemicals and pharmaceuticals, manufacture of metal products and machinery, printing, and textiles. These industries will gain from utilising more effective energy systems and technologies, that help them, in a cost effective ordered way, meet the UK targets of reducing net greenhouse gas emissions to zero by 2050 while, importantly, remaining competitive. By participating in invited project workshops, progress meetings and hosting visits, industry partners will have the opportunity to learn about the research progress and be in a prime position to commercially exploit the project outputs. All the involved universities have business development teams that have experience of the successful commercial exploitation of research work. Intellectual property arising will be patented when appropriate to facilitate commercial exploitation. Industries, bodies and regions seeking to develop integrated multi vector energy systems will benefit from the knowledge learned from the assessment of the application of a transactive energy approach to case studies based on real data.
The development of a successful transactive energy approach will facilitate the transition to an integrated, distributed energy system that maximises use of available resources to deliver the required energy service at least cost. This will benefit all energy consumers and prosumers in the network area.
Government policy makers will benefit in that the reduction in effective primary energy consumption per unit industrial production will reduce greenhouse gas emissions while maintaining or increasing competitiveness. They will also benefit in that this project will deliver case study data that can be used to promote the role out of the technologies and methodology developed to other suitable regions which will help meet the three goals of the energy trilemma, energy security, energy equity and environmental sustainability.
The development of a successful transactive energy approach will facilitate the transition to an integrated, distributed energy system that maximises use of available resources to deliver the required energy service at least cost. This will benefit all energy consumers and prosumers in the network area.
Government policy makers will benefit in that the reduction in effective primary energy consumption per unit industrial production will reduce greenhouse gas emissions while maintaining or increasing competitiveness. They will also benefit in that this project will deliver case study data that can be used to promote the role out of the technologies and methodology developed to other suitable regions which will help meet the three goals of the energy trilemma, energy security, energy equity and environmental sustainability.
Publications
Ahmad A
(2021)
A thermochemical energy storage based cooling and heating system: Modelling, experimental validation and lab-scale demonstration
in Energy Conversion and Management
Albert M
(2022)
Operation and performance of Brayton Pumped Thermal Energy Storage with additional latent storage
in Applied Energy
Anagnostopoulos A
(2021)
Effect of carbon on the performance of red mud-molten salt composites for thermal management and waste heat recovery applications
in Journal of Energy Storage
Anagnostopoulos A
(2022)
Valorization of phosphogypsum as a thermal energy storage material for low temperature applications
in Journal of Cleaner Production
Anagnostopoulos A
(2021)
Red mud-molten salt composites for medium-high temperature thermal energy storage and waste heat recovery applications.
in Journal of hazardous materials
Anagnostopoulos A
(2022)
Microstructural improvement of solar salt based MgO composites through surface tension/wettability modification with SiO2 nanoparticles
in Solar Energy Materials and Solar Cells
Camacho I
(2022)
On the anticorrosion mechanism of molten salts based nanofluids
in Solar Energy Materials and Solar Cells
Chen B
(2024)
Thermochemical splitting of CO2 on perovskites for CO production: A review
in Journal of Energy Chemistry
Chen B
(2024)
Unlocking thermochemical CO2/H2O splitting by understanding the solid-state enthalpy and entropy of material reduction process
in International Journal of Hydrogen Energy
Cohen R
(2022)
Briefing: The 2021 Glasgow Climate Pact: steps on the transition pathway towards a low carbon world
in Proceedings of the Institution of Civil Engineers - Energy
| Description | The research performed has: i) Confirmed that thin film coatings applied to heat exchanger surfaces can delay onset of solidification of organic phase change materials (PCM) on heat exchanger surfaces during discharging and enhance shedding of solid PCM from heat exchanger surfaces during charging, marginally enhancing thermal store charge and discharge performance. ii) Developed a thermal transformer which realised a temperature lift from 105 to 125 °C for linked salt beds at equal pressure. When the thermal transformer was operated in a non-conventional way with additional valves to separate the salt beds a temperature lift up to 145°C was achieved. iii) A novel lab scale prototype heat storage system was designed, developed and characterised that combined thermochemical and phase change heat storage systems which enabled peak output temperatures and powers to be reduced and constant temperature output to be achieved for an extended time period. iv) The performance of a lab prototype thermo-chemical fluid network was demonstrated and its potential application to capture and store industrial low-grade waste heat to provide dehumidification, cooling and upgraded heating energy services was assessed with case study assessments performed. v) A laboratory-scale, 12kW piston-driven high-temperature heat pump was designed and developed using refrigerant R1233zd(E) as the working fluid. The system was tested with source temperatures ranging from 60 to 80 °C and sink temperatures from 90 to 140 °C. Testing results showed a coefficient of performance (COP) ranging from 3.2 to 2.2, with temperature lifts varying from 30 to 60K, and vi) A number of different case studies to assess the availability of waste heat from local sources i.e. hospitals, supermarkets, substations, glass manufacturing, vehicle manufacturing, etc. and its suitability to meet local head demands have been performed indicating that industrial waste heat can be cost effectively utilised when heat sources are close to demands. |
| Exploitation Route | The systems, approaches and techniques developed are applicable to the decarbonisation of low temperature industrial process heat by i) allowing waste heat to be stored if required and upgraded to higher temperatures for use on site, and ii) facilitate utilisation of industrial waste heat in local district heat networks. Further research and demonstration at realistic scale will be required to enable the outcomes to result in marketable technologies. |
| Sectors | Chemicals Construction Energy Manufacturing including Industrial Biotechology Other |
| Description | The main findings that are being used to date are: i) The case studies developed during the DeltaPhi project, which investigated heat recovery from local sources i.e. hospitals, supermarkets, substations, glass manufacturing, etc. The case studies involved techno-economic modelling with EnergyPro estimated OPEX and carbon savings over a counterfactual of gas boilers and air-sourced HPs. These results are being used to develop and validate the FAST-DHC tool, a feasibility assessment tool for district heating and cooling for local authorities. ii) Findings in the application of liquid desiccants as dual-purpose media for both temperature and humidity control and heat recovery have been presented and discussed with potential industrial partners, such as Durham County Council, Kromek, Nissan, Lhyfe, etc. interested in low-grade heat recovery and district energy applications with project proposals being developed. |
| First Year Of Impact | 2024 |
| Sector | Construction,Energy,Environment,Government, Democracy and Justice,Manufacturing, including Industrial Biotechology,Other |
| Impact Types | Economic Policy & public services |
| Title | Supplementary information files for Super-liquid-repellent thin film materials for low temperature latent heat thermal energy storage: A comprehensive review of materials for dip-coating |
| Description | CC BY 4.0 © The Authors 2024Supplementary files for article Super-liquid-repellent thin film materials for low temperature latent heat thermal energy storage: A comprehensive review of materials for dip-coatingWhen discharging latent heat thermal energy storage (LHTES) systems, performance is influenced by the formation and adherence of a solid layer of phase change material (PCM) on heat eXchange (HX) surfaces. Super-liquid-repellent thin films (STFs) may be able to reduce solidifying PCM adhesion on HX surfaces during discharging, delay PCM solidification to lower temperatures, and by modifying nucleation sites potentially enable long-term seasonal thermal storage. Techniques employed previously to fabricate sintered polymeric STF coatings include chemical vapour deposition, dip-coating, spray-coating, spin-coating, layer-by-layer (LbL) assembly, sol-gel, anodizing, electrodeposition, electrospinning, so on. Dip-coating is considered attractive for fabricating thin films on simple and complex surface geometries due to process maturity, scalability, flexibility and cost-effectiveness. To identify suitable materials for preparing STFs on metal HX surfaces using the dip-coating process, more than 200 journal articles published in English during the period 2010 to 2022 were reviewed and the potential role of STFs in LHTES applications was assessed. The review identified key areas and applications stimulating STF material developments and formulations. The dip-coating of potential STF materials was classified under three major themes driving current research and development (R&D) activities, that is, high performance thin films, eco-friendly thin films and fundamental research formulations. This review provides a platform from which to develop coatings and HX systems to enable the cost-effective implementation of STFs for improved heat transfer in future mobile/stationery LHTES systems. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2024 |
| Provided To Others? | Yes |
| URL | https://repository.lboro.ac.uk/articles/dataset/Supplementary_information_files_for_Super-liquid-rep... |
| Title | Supplementary information files for Super-liquid-repellent thin film materials for low temperature latent heat thermal energy storage: A comprehensive review of materials for dip-coating |
| Description | CC BY 4.0 © The Authors 2024Supplementary files for article Super-liquid-repellent thin film materials for low temperature latent heat thermal energy storage: A comprehensive review of materials for dip-coatingWhen discharging latent heat thermal energy storage (LHTES) systems, performance is influenced by the formation and adherence of a solid layer of phase change material (PCM) on heat eXchange (HX) surfaces. Super-liquid-repellent thin films (STFs) may be able to reduce solidifying PCM adhesion on HX surfaces during discharging, delay PCM solidification to lower temperatures, and by modifying nucleation sites potentially enable long-term seasonal thermal storage. Techniques employed previously to fabricate sintered polymeric STF coatings include chemical vapour deposition, dip-coating, spray-coating, spin-coating, layer-by-layer (LbL) assembly, sol-gel, anodizing, electrodeposition, electrospinning, so on. Dip-coating is considered attractive for fabricating thin films on simple and complex surface geometries due to process maturity, scalability, flexibility and cost-effectiveness. To identify suitable materials for preparing STFs on metal HX surfaces using the dip-coating process, more than 200 journal articles published in English during the period 2010 to 2022 were reviewed and the potential role of STFs in LHTES applications was assessed. The review identified key areas and applications stimulating STF material developments and formulations. The dip-coating of potential STF materials was classified under three major themes driving current research and development (R&D) activities, that is, high performance thin films, eco-friendly thin films and fundamental research formulations. This review provides a platform from which to develop coatings and HX systems to enable the cost-effective implementation of STFs for improved heat transfer in future mobile/stationery LHTES systems. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2024 |
| Provided To Others? | Yes |
| URL | https://repository.lboro.ac.uk/articles/dataset/Supplementary_information_files_for_Super-liquid-rep... |
| Title | Supplementary information for Decarbonisation of heat: Analysis of the potential of low temperature waste heat in UK industries |
| Description | Supplementary files for article Decarbonisation of heat: Analysis of the potential of low temperature waste heat in UK industries The UK will need to decarbonise low temperature industrial waste heat (up to Ëœ250 °C) to achieve net-zero greenhouse gas emission targets. Industrial waste heat production represents an opportunity for reduction in the use of primary fuels used in the production of commodities. Energy inefficient processes in addition to increased emissions raises the cost of plant operation, - an undesirable scenario for both industrial competitiveness and the environment. Less is known about the quantity and potential applications for recovered low temperature industrial waste heat in UK and the quantification and characterisation of the resource can provide the needed impetus for the development and adoption of green technologies to help achieve the 2050 Net-Zero target. In this work the potential magnitude of the low temperature industrial waste heat resource in the UK is analysed by using sector-level energy intensity values for different industries while drawing on corresponding estimates from previous studies in the USA and by closely mapping the UK Standard Industrial Classification (SIC 2007) against sectors in the USA (NAICS [North American Industry Classification System]). The assessment undertaken finds that the recoverable potential of low temperature waste heat up to Ëœ250 °C could be up to 83.7% of the total estimated waste heat potential in UK industry. Significant opportunities exist in this low temperature range for waste heat recovery actions at individual sites. Research and Development (R&D) into alternative improved methods for waste heat recovery, storage, and use (WHRSU) technologies could also produce significant positive environmental and industrial impact. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2022 |
| Provided To Others? | Yes |
| URL | https://repository.lboro.ac.uk/articles/dataset/Supplementary_information_for_Decarbonisation_of_hea... |
| Title | Supplementary information for Decarbonisation of heat: Analysis of the potential of low temperature waste heat in UK industries |
| Description | Supplementary files for article Decarbonisation of heat: Analysis of the potential of low temperature waste heat in UK industries The UK will need to decarbonise low temperature industrial waste heat (up to Ëœ250 °C) to achieve net-zero greenhouse gas emission targets. Industrial waste heat production represents an opportunity for reduction in the use of primary fuels used in the production of commodities. Energy inefficient processes in addition to increased emissions raises the cost of plant operation, - an undesirable scenario for both industrial competitiveness and the environment. Less is known about the quantity and potential applications for recovered low temperature industrial waste heat in UK and the quantification and characterisation of the resource can provide the needed impetus for the development and adoption of green technologies to help achieve the 2050 Net-Zero target. In this work the potential magnitude of the low temperature industrial waste heat resource in the UK is analysed by using sector-level energy intensity values for different industries while drawing on corresponding estimates from previous studies in the USA and by closely mapping the UK Standard Industrial Classification (SIC 2007) against sectors in the USA (NAICS [North American Industry Classification System]). The assessment undertaken finds that the recoverable potential of low temperature waste heat up to Ëœ250 °C could be up to 83.7% of the total estimated waste heat potential in UK industry. Significant opportunities exist in this low temperature range for waste heat recovery actions at individual sites. Research and Development (R&D) into alternative improved methods for waste heat recovery, storage, and use (WHRSU) technologies could also produce significant positive environmental and industrial impact. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2022 |
| Provided To Others? | Yes |
| URL | https://repository.lboro.ac.uk/articles/dataset/Supplementary_information_for_Decarbonisation_of_hea... |
| Description | Organised and ran Heat Pump Conference |
| Form Of Engagement Activity | Participation in an activity, workshop or similar |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Industry/Business |
| Results and Impact | 120 SMEs, entrepreneurs, academics, policymakers, estate managers, corporates, investors and third sector participants involved and/or interested in the heat pump engineering, manufacture and installation supply chain attend the event. |
| Year(s) Of Engagement Activity | 2024 |
| URL | https://www2.bgs.ac.uk/gsni/events/index.html#:~:text=GSNI%20and%20Ulster%20University%20hosted,%2C%... |
