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Realising Functional Cellulosic Bio-based Composites

Lead Research Organisation: University of Bristol
Department Name: Aerospace Engineering

Abstract

The worldwide transition from the use of oil-based to more sustainable feedstocks for plastics is underway. This transition is due to dwindling oil stocks and a realisation that current levels of the use of this resource is no longer sustainable. More sustainable sources for materials use exist in the form of cellulose from plants. This material is a very versatile polymer and is in fact the most utilised material worldwide. For the last 20+ years I have been researching the structure-property relationships of cellulose and am ideally placed to play a key role in the transition to renewable materials. Nature makes use of cellulose to good effect. Being intrinsically strong and stiff means that cellulose fibres, per weight, can compete mechanically with most synthetic alternatives such as glass. In nature's most prevalent natural composite - wood - cellulose forms the basis of its outstanding structural performance. All our attempts to replicate the composite performance of wood and plants have fallen short, and this fellowship seeks to address these issues, while also using the intrinsic properties of plant fibres and wood themselves. The proposed research aims to do this in the context of both natural and synthetic materials, adding functionality to the composites, while also addressing in a cross-cutting sense the sustainability credentials of the materials and structures proposed.

Planned Impact

The pathways to impact for my fellowship will be through the key areas of knowledge, society people and the economy.

Knowledge: This fellowship will allow me to build on my established career in cellulose and renewable materials to further grow an internationally leading group in functional materials. Research will focus on fundamental research into sustainable functional composites leading to high impact publications in leading journals, and attendance at influential and significant scientific meetings, growing the reputation of UK science in this area. In addition to attending meetings, a workshop is planned, showcasing the very best science in this area, building a community of people engaged in this research. Industrial translation of knowledge, from laboratory to application, will be enhanced by the engagement of a number of industrial companies, and the National Composites Centre, with whom a roadmap will be developed to assist in the production of a stage-gated application to the funding councils (InnovateUK/EPSRC) towards the end of the fellowship. Other routes to both dissemination and translation of knowledge are through networks (eg. KTNs) and the setting up of a start-up company.

Society: There are clear benefits to society through the development of more sustainable composite materials. The applications that will be developed, including the organic based composite solar cells, will have benefits to society in terms of cleaner energy. The lightweighting agenda of the fellowship could result in reduced CO2 emissions for transport, and better solutions for end-of-life use of the materials. A number of public engagement activities are planned throughout the fellowship, including science cafes, art displays

People: The researchers working on the fellowship will benefit from the research through the development of their careers, and the fact that this will lead them into new groundbreaking areas of endeavour. With the adventurous programme of work they will stand-out from other researchers working in this area. Other beneficiaries will be minority groups, in particular BME students intersected with gender, with whom a very targeted plan of engagement is planned. This will ensure that a very wide range of people from lots of different backgrounds are engaged with the research.

Economy: The fellowship will generate income from the invested funds through the spin-out companies, IP, industrial support and additional applications made to this the take-up of technology from the supporting companies will provide a source of income for the UK economy.

Publications

10 25 50
 
Description The award has resulted in the running of several outreach events - including schools visits to the University of Bristol by Black and Black heritage young people. We also took part in some outreach and design of classroom materials with CARGO which resulted in some local press (https://www.bristol.ac.uk/news/2023/july/cargo-school-visit.html). We have undertaken some training and coaching with the faculty of science at Bristol for work on anti-racism, resulting in a report that is now being acted on in the University. With additional funding from the University we have launched a programme called "Breaking Barriers to Black Academia" which is developing a support network and series of workshops to address access and awarding of funding for Black academics working in STEM subjects. The fellowship funding has been specifically useful for supporting these events as part of the EDI programme.
Sector Education
Impact Types Cultural

Societal

 
Title FTIR, TGA and DSC characterisation 
Description Raw material sulfated CNCs, Br-CNC macroinitiators and polyvinyl acetate-CNC copolymers were characterised with FTIR and TGA. DSC was used to characterise the polyvinyl acetate-CNC copolymers and the final composite. 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://figshare.com/articles/dataset/FTIR_TGA_and_DSC_characterisation/27919041
 
Title Investigating Electrospun Oil Sorbents Derived From Cigarette Filters 
Description Data for https://doi.org/10.1016/j.matlet.2023.133965 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
URL https://data.bris.ac.uk/data/dataset/34dxpfqqvujcq2fyppvaag1f6r/
 
Title Self-Healing Composite Coating Fabricated with a Cystamine Cross-Linked Cellulose Nanocrystal-Stabilized Pickering Emulsion 
Description This is data from the publication "Self-Healing Composite Coating Fabricated with a Cystamine Cross-Linked Cellulose Nanocrystal-Stabilized Pickering Emulsion" https://doi.org/10.1021/acs.biomac.3c00915 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://data.bris.ac.uk/data/dataset/8dqpdkcdchsc2vqzlf8qsrgax/
 
Title Solid-state NMR 
Description ssNMR was used to measure the degree of substitution of Br-CNC macroinitiators and the degree of polymerisation of polyvinyl acetate-CNC copolymer. 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://figshare.com/articles/dataset/Solid-state_NMR/27926082
 
Title XPS 
Description XPS was used for chemical analysis of Br-CNC macroinitiators. 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://figshare.com/articles/dataset/XPS/27926400
 
Description Tokyo University of Agriculture and Technology 
Organisation Tokyo University of Agriculture and Technology
Country Japan 
Sector Academic/University 
PI Contribution We worked together on a joint publication around ionic liquid modified cellulose nanofibrils
Collaborator Contribution They provided some nanofibrils of cellulose for the study and helped us understand their properties. A joint publication was produced.
Impact This paper resulted from the collaboration https://www.sciencedirect.com/science/article/pii/S0144861724007458
Start Year 2023
 
Description VTT Sample analysis 
Organisation VTT Technical Research Centre of Finland Ltd
Country Finland 
Sector Academic/University 
PI Contribution We worked together on a joint publication.
Collaborator Contribution They carried out some measurements on our samples (namely QCM-D analysis)
Impact This paper https://www.sciencedirect.com/science/article/pii/S0144861724013821
Start Year 2024
 
Description Black Mentors programme 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Schools
Results and Impact The activity was aimed at engaging with Black pupils within local schools within Bristol. They came to learn about STEM subjects, take part in demonstrations, and hear life journeys from other Black STEM professionals (academic and industry)
Year(s) Of Engagement Activity 2021,2022,2023,2024
 
Description Breaking Barriers to Black Academia 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Other audiences
Results and Impact This was a programme that sought to find the barriers of Black academics to research funding, and then hold a series of workshops with a cohort of academics to better understand and overcome those barriers.
Year(s) Of Engagement Activity 2024
URL https://www.bristol.ac.uk/news/2024/june/breaking-barriers-to-black-academia.html