Solution-processed inorganic Thin-Film photovoltaic devices (SolPV)

Lead Research Organisation: Northumbria University
Department Name: Fac of Engineering and Environment

Abstract

Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.

Publications

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Title Data from photoluminescence spectroscopy, admittance spectroscopy, photoelectron emission microscopy, current-voltage characteristics, and spectral response of quantum efficiency measurements on Cu2ZnZnSnS4 (CZTS) films and solar cells as a function of... 
Description This is the dataset used in the journal article to be published in American Chemical Society's Applied Energy Materials. Article Title: Mapping the Energetics of Defect States in Cu2ZnSnS4 films and the Impact of Sb DopingAuthors: Devendra Tiwari, Michael V. Yakushev, Tristan Koehler, Mattia Cattelan, Neil Fox, Robert W. Martin, Reiner Klenk and David J FerminDOI: https://10.1021/acsaem.1c03729 The dataset was produced in collaboration with colleagues from University of Bristol, Strathclyde University and Helmholtz Zentrum Berlin. The dataset contains .csv files and can be accessed can be using any text editor or any spreadsheet software. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
URL https://figshare.northumbria.ac.uk/articles/dataset/Data_from_photoluminescence_spectroscopy_admitta...
 
Title Data from photoluminescence spectroscopy, admittance spectroscopy, photoelectron emission microscopy, current-voltage characteristics, and spectral response of quantum efficiency measurements on Cu2ZnZnSnS4 (CZTS) films and solar cells as a function of... 
Description This is the dataset used in the journal article to be published in American Chemical Society's Applied Energy Materials. Article Title: Mapping the Energetics of Defect States in Cu2ZnSnS4 films and the Impact of Sb DopingAuthors: Devendra Tiwari, Michael V. Yakushev, Tristan Koehler, Mattia Cattelan, Neil Fox, Robert W. Martin, Reiner Klenk and David J FerminDOI: https://10.1021/acsaem.1c03729 The dataset was produced in collaboration with colleagues from University of Bristol, Strathclyde University and Helmholtz Zentrum Berlin. The dataset contains .csv files and can be accessed can be using any text editor or any spreadsheet software. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
Impact This dataset formed the basis for the publication: Mapping the Energetics of Defect States in Cu2ZnSnS4 films and the Impact of Sb Doping, Devendra Tiwari, Michael V Yakushev, Tristan Koehler, Mattia Cattelan, Neil Fox, Robert W Martin, Reiner Klenk, David J Férmin, ACS Applied Energy Materials, Volume 5, Pages 3933-3940, Year 2022. This led to the basis for rational optimisation of the performance of CZTS-based solar cells, which is one of two key chalcogenide materials being investigated in this SolPV project. 
URL https://figshare.northumbria.ac.uk/articles/dataset/Data_from_photoluminescence_spectroscopy_admitta...
 
Description Employability Panel (ReNU CDT Northumbria University) 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Postgraduate students
Results and Impact Dr. Nicole Fleck as a panel member for this discussion. The purpose of this career panel was to allow CDT students to ask questions about academic careers in all aspects. These were submitted in advance. Answers and potential concerns of students at the end of their postgraduate program were discussed by the panel and answered in the session. Students reported feeling more confident about their career choices and possible future pathways into STEM/academia or industry.
Year(s) Of Engagement Activity 2023
 
Description Faraday Discussion on Emerging inorganic materials in thin-film photovoltaics 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other audiences
Results and Impact Dr. Nicole Fleck and I presented a poster on IMO as an alternative partner layer for Sb2Se3 solar cells. Author on the paper presented by Mr. Matthew Naylor on Ge as a dopant for CZTSSe absorber materials for solar cells. We also participated in the topical discussions. All together this resulted in the publication of the following peer reviewed papers:

Bulk and surface characterisation techniques of solar absorbers: general discussion
JW Andreasen, J Breternitz, M Bär, PJ Dale, M Dimitrievska, DJ Fermin, ...
Faraday Discussions 239, 180-201

Novel chalcogenides, pnictides and defect-tolerant semiconductors: general discussion
JW Andreasen, E Arca, JW Bowers, M Bär, J Breternitz, PJ Dale, ...
Faraday Discussions 239, 287-316

Indium-free CIGS analogues: general discussion
JW Andreasen, JW Bowers, J Breternitz, PJ Dale, M Dimitrievska, ...
Faraday Discussions 239, 85-111

Ex situ Ge-doping of CZTS nanocrystals and CZTSSe solar absorber films
MC Naylor, D Tiwari, A Sheppard, J Laverock, S Campbell, B Ford, X Xu, ...
Faraday Discussions 239, 70-84
Year(s) Of Engagement Activity 2022
URL https://www.rsc.org/events/detail/46796/emerging-inorganic-materials-in-thin-film-photovoltaics-fara...
 
Description Local school workshop (Blyth, Newcastle-upon-Tyne) 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Schools
Results and Impact Facilitated by Dr Nicole Fleck, the PDRA on the project. Arranged at the request of the Ogden Trust.
Demonstration and hands-on workshop on fabrication of dye-sensitised solar cells by Year 6 school students (total cohort size 60 students). Discussions about the processing and operation of solar cells and renewable energy technologies in general. A key outcome engagement of the students with the scientific method and inquiry.
Year(s) Of Engagement Activity 2023
 
Description Oral presentation of research work at Materials Research Society (spring meeting, 2022, Hawaii) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other audiences
Results and Impact Oral presentation of research work by Dr Nicole Fleck on IMO as an alternative partner layer for Sb2Se3 solar cells based on work started during their PhD. Co-authored by Dr. Jon Major (University of Liverpool), Dr. Tom Shalvey (University of Liverpool), Dr. Frank Jaeckel (University of Liverpool).
Year(s) Of Engagement Activity 2022
URL https://www.mrs.org/meetings-events/spring-meetings-exhibits/past-spring-meetings/2022-mrs-spring-me...
 
Description ReNU CDT cohort 4 technical induction lecture 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Postgraduate students
Results and Impact Dr. Nicole Fleck and I presented the induction lecture on Photoelectron Spectroscopy for cohorts 3 and 4 of the CDT. This constituted essential training on one of the key materials characterisation techniques in the field. This prompted questions and discussion on the topic.
Year(s) Of Engagement Activity 2022