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Responsive Manufacturing of High Value Thin to Thick Films.

Lead Research Organisation: University of Sheffield
Department Name: Chemical & Biological Engineering

Abstract

Thin films with a high technical specification are used in many everyday devices, including displays, solar cells, electronic devices, batteries, and sensors. Printing of the high-value flexible electronic films with insulating, dielectric, semiconducting and conducting materials used in these devices makes a major and rapidly growing contribution to UK industry.The thickness of the films required, the starting materials used and the final high-value functions desired in the finished product vary significantly. However, the scientific principles that govern the behaviour of the printing processes for these diverse applications have many similarities, because they are all formed by selectively spreading a wet film of suspended solid particles and drying it.

At present the optimisation of the printing parameters for these films is commonly achieved through a trial and error process rather than systematic intelligent control. Individual processes are being optimised in isolation without cross-fertilization of knowledge. In a fast changing world, where disruption to supply chains or development of improved materials can change the process input materials, the need to reconfigure the formulations/printing parameters used increases. Furthermore, desired outputs can also change rapidly as the manufacturers and customers seek to meet changing demands of their market for example requiring more precise control of film parameters such as thickness and electrical properties. Adjusting to such continually moving goal posts by relying on trial and error testing is time-consuming, wasteful and costly.

The responsive manufacturing technology we propose to develop will have sufficient flexibility to overcome such problems by utilizing intelligent machine learning to control the printing parameters in real-time and therefore maintain an optimized printing process robustly in the face of variations in feedstock materials and/or the required output. It is surprising that there has been no major attempt to implement this approach to process control and optimisation for solution printed materials. This is despite process monitoring and feedback-based optimisation being proven enabling methods in other sectors such as additive manufacturing.

This will be achieved by developing control algorithms for the printing process that take into account our theoretical understanding of the processes occurring and utilizing high-speed (minimized and proxy) in situ data acquisition to respond autonomously and continuously to perturbations in the feedstock materials or required film properties. We will make use of the wide range of laboratory scale processing systems our project team regularly use for the production of model colloidal films, ceramic dielectrics, photovoltaics and battery electrodes to provide the datasets required to educate the machine learning algorithms, test our theoretical understanding, develop models of the printing processes and to ultimately test the autonomous control system that we develop. Having proven the system works at a laboratory scale we plan to perform a series of demonstration runs at industrial scale in collaboration with project partners CPI who are world leading experts in production of printed electronics. This will provide the evidence needed to prove that this approach can work at an industrial scale in a highly demanding production environment (printed electronics require a high degree of control of the surface chemistry between subsequent layers to perform correctly and are typically made in cleanroom/glove-boxes within strict environmental tolerances). We envisage a future where a deep theoretical understanding of the processes that are taking place is utilised by artificial intelligence to continuously control and optimise the manufacture of 21st century high-value printed films autonomously using the minimum number of high-speed measurements to achieve the desired results.

Publications

10 25 50
 
Description As part of this award, we have scientific streering group, headed up by David Bird, at the CPI.
Their most recent evaluation of the findings and progress this award has made (to date) is shown below in an evaluation summary produced by the head of our steering group in March 2025:

======================== LETTER=========================

RE: Industrial Steering Group progress assessment for the Responsive Manufacturing of High
Value Thin to Thick Films Project
Dear Professor Howse,
Thank you for the opportunity to evaluate the progress of the project investigating the Responsive Manufacturing
of High Value Thin to Thick Films.
The Steering Group members are delighted by the progress that the project has made across all 6 work packages
which have each moved their relevant technology from theoretical models to practical application either on
bench-top equipment or free-standing coating equipment or pilot-scale roll-to-roll production technologies in a
factory environment.
The range of industries where the technologies are applicable is significant, from coating battery slurries to
material for invitro diagnostics. Please see the attached report for the specific feedback on the overall project and
the individual work packages. I look forward to the final report.
Yours sincerely,

Dr David Bird
Head of Technology and Innovation
CPI

Industrial Steering Group Feedback to the Responsive
Manufacturing of High Value Thin to Thick Films project.
Drafted by David Bird (Head of Steering Group)
27/02/2025

Steering Group Members:
• David Bird (Head of Technology and Innovation, CPI)
• George Kerridge (R&D Engineer, Knowles Precision Devices Ltd)
• Martin Kiener (CIO & Founder, FOM Technologies)
• Chris Jones, (COO, Novalia Ltd)
• Nicholas Butcher (Process & Equipment Development Director, Emerson & Renwick Ltd)
• Joe Armstrong (Business Unit Optical Measurement Systems, Polytec GmbH)

Feedback:
The feedback is given for the overall project and then for each work package.

Overall summary
The project has progressed well towards completing the overarching aim of developing a
responsive approach to the manufacture of high value films by addressing the 5 goals set out in
the original proposal (Appendix 1). The investigators have developed several technologies from
concept (TRL1) to demonstration (TRL3) through the course of the project, which the steering
group have expressed interest in their further development and potential commercialisation.
The control algorithms, metrology and sensors have been demonstrated both at the lab-scale
and one running pilot-scale equipment, fulfilling the goals of the project. The life cycle
modelling work has validated the utility of the metrology methods by demonstrating the
significant reduction in environmental impact through efficient production of the final devices.

WP1: Machine Learning & Responsive Control Systems
The testing of the machine learning algorithms for roll-to-roll slot die coating shows great
promise as the evolutionary algorithms have been verified with physical experiments. We look
forward to reading the full paper.
The steering group sees great potential in the sequential optimisation algorithms for the
machine processing conditions; that the machine itself could self-calibrate to a new material
set without expert control has the potential to save significant time when a higher content of

material whose origin is not well controlled or well defined, such as recycled material or bio-
based materials.

WP2: Theory & Simulations
The development of models to understand the fluid mechanics within a drying film are very
useful for the continuous coating of complex materials; the stratification of the particles due to
the accelerated drying front is relevant to a wide range of coatings that contain dispersed
materials from battery slurries to conductive inks. The modelling to understand the edge-effects
to reduce the 'coffee ring' effect are highly relevant to multi-layer coatings, particularly where
subsequent coating layers must completely coat the underlying surface, and peaks due to a
coffee ring effect could cause unwanted contacts between electrically functional layers.
The modifications to the diffusion pheresis to account for differing rates of motion for particles
with different charges is highly relevant to stabilised, colloidal systems, which form the bulk of
thick-film coatings.

WP3: Inline Sensors
The creation of the database of defects shows clear relevance to known coating defects. The
edge detection and mapping of residues from receding drying fronts is applicable to a range of
device types, particularly those that require multi-layer printing where the one functional layer
overlaps another such as a solar cell. The detection level of 0.65 microns of surface roughness
is suitable for many applications where the overall feature size would be orders of magnitude
larger, such as sensors, photovoltaics and batteries.
The application of the technology to electronic invitro diagnostic devices, either on plastic or
paper substrate is worthy of investigation as the complex paper surface will be more difficult to
deconvolute the underlying surface from the printed material.

WP4: Real & Model systems and Data Collection
The telecentric illumination is a novel approach to the issue if getting optics into the heart of a
fast-moving, complex machine. The calibration artefacts are suitable for mimicking a wet
droplets or coating-in-progress that has been frozen in time.
The structured illumination is highly relevant to a range of coatings, although the nature of the
transmission of light necessitates the need for a close-to-transparent substrate and coating.
The ability to create a series of profiles that would appear to be a regular-array when viewed
though a 'perfect coating' would allow facile detection of poor coating quality, enabling rapid
diagnosis of coating faults without needing an expert in the coating process.
The stroboscopic broadband metrology combined with DNA code mapping analytical software

show significant promise for estimating the thickness of coatings beyond those served by thin-
film metrology such as ellipsometry.

WP5: Demonstrator & Pilot Scale Plans
The demonstration of the measurement tools on the pilot-scale roll-to-roll coater has shown
that the metrology is suitable for real-world working conditions, not just measuring samples on
an optical bench, by coping with machine vibrations and factory-floor conditions.

The adaptation from a bench-top roll-to-roll coater at the University of Sheffield, to the roll-to-
roll coater at the University of Huddersfield to the pilot-scale coater at CPI shows that the

technologies have been trialled in relevant environments.

WP6: Sustainability & Process Efficiencies
The Productivity Analysis, particularly the Category Function show significant potential for
enabling a greater number of organisations to estimate the environmental impact of
manufacturing decisions without having to consult with deep specialists. While real industrial
processes will require a thorough understanding of the life cycle of the materials they are
processing, the Category Function offers a light-touch way of considering the implications of
using differing manufacturing processes for a desired device type. Follow on work should
consider how to roll this out to other device types, an whether it can be applied to more
manufacturing scenarios.
The Activity Modelled LCA for perovskite cells, comparing lab-scale production to pilot-scale
production has shown the value of metrology in that the impact of scrap is significant at any
point in the process, but becomes worse the more that a substrate has been processed,
therefore ensuring that the metrology can identify defects so that they can be eliminated is
critical to responsive manufacturing that requires the use of a wider range of raw materials.
Exploitation Route See notes above from Steering committee.
Sectors Electronics

Energy

Healthcare

Manufacturing

including Industrial Biotechology

 
Title The Dynamic Slot Die 
Description A rapid and simple method of adjusting coating flow within a slot die, unlocking efficient manufacturing and performance benefits for batteries and solar panels. The Dynamic Slot Die offers extensive control over the coating fluid resulting in several significant benefits: Improved end-device performance: fluid flow can be precisely tuned for better coating properties, including coating uniformity. Tests show that the Dynamic Slot Die can improve coating uniformity by 25% compared to traditional slot dies. Reduced downtime: blockages can be swiftly cleared, allowing production to resume quickly, minimising downtime. New coating materials: the Dynamic Slot Die can handle materials that are currently difficult to coat due to coating uniformity issues, large particle size or lack of coating solution stability. Ease of use: simple set-up and cleaning make it easy for operators to integrate this device into existing projects. Intelligent manufacturing: optional computer control allows integration with sophisticated control algorithms and machine learning optimisation methods. 
Type Of Technology New/Improved Technique/Technology 
Year Produced 2024 
Impact Patent filed (No.2412706.0) 
URL https://www.sheffield.ac.uk/commercialisation/current-opportunities/dynamic-slot-die
 
Description 16th International Conference on Hybrid & Organic Photvoltaics (HOPV24) 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Conference to discuss organic perovskite, and oxide photovoltaics, materials & device optimisation, spectroscopy of photovoltaic materials, emerging characterisation techniques, PV scale up and industrialisation
Year(s) Of Engagement Activity 2024
 
Description 6th International conference of Perovskite Solar Cells and Optoelectronics. Invited Talk 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Conference in Oxford, England as an invited speaker to members of academia and businesses. Talk produced questions from interested parties and connections were made for future research ideas.
Year(s) Of Engagement Activity 2023
URL https://www.psco-conference.org/
 
Description AICHE Annual Meeting 27th - 31st October, San Diego, USA 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Conference for Chemical Engineers at all career stages. Prof Rachael Rothman led debates and panel discussions regarding the sustainability element of this research grant, alongside PDRA Dr Nathan Dodd.
Year(s) Of Engagement Activity 2024
 
Description Attendance at High Polymer Research Group 61st conference: Polymers in water 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact "The High Polymer Research Group is a charity whose objective is to ensure that leading edge developments in polymer science and engineering are made available and fully discussed by industrial and academic researchers engaged in the field. We do this by organizing conferences that have been held annually since 1960 (Origins and History of the High Polymer Research Group) and we aim to make participation as diverse and as international as possible. Equally we interpret polymer science and engineering in a broad way encompassing biopolymers as well as synthetic polymers and their use in devices, engineering and medicine. In addition to fundamental and applied research the High Polymer Research Group (HPRG) also endeavours to address societal aspects of polymer science."
Attendance at this conference was to promote the work of this research grant, and to discuss further with interested parties.
Year(s) Of Engagement Activity 2023
URL https://highpolymer.org.uk/programme.php
 
Description Attendance at the MACH 2022 Exhibition 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact Attendance by project member and WP5 lead, Dr Hussam Muhamedsalih. Engaged with other attendees at the exhibition and promoted the work of the group in his discussions.
Year(s) Of Engagement Activity 2022
URL https://www.machexhibition.com/
 
Description CONTROL 2024: 14th United Kingdom Automatic Control Council (UKACC) International Conference on Control 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Control Systems / Modelling / Robotics / Industrial Manufacturing
Year(s) Of Engagement Activity 2024
 
Description Digital Precision: Lab Self-Optimisation for Nanoparticle Manufacturing 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact Event coordinated by Centre for Process Innovation (CPI), Leeds, Sheffield, York Universities.
CO-I George Panoutsos attended a panel discussion and PDRA Dr Zezhi Tang provided a poster presentation and narrative.
Year(s) Of Engagement Activity 2024
 
Description EPSRC CMAC Hub Open Day 2025 - Invited poster presentation 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact invited to give a poster presentation at the CMAC open day
Year(s) Of Engagement Activity 2025
URL https://cmac.ac.uk/open-days-2025
 
Description EPSRC Net Zero event 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Policymakers/politicians
Results and Impact Attendance by WP5 lead (Dr Hussam Muhamedsalih) and WP6 lead (Prof Rachael Rothman). This was an event related to the governments Net Zero event that was part of COP26 in Glasgow.
The event was a hybrid event so it is difficult to understand the audience and the reach. Both our attendees were there in person.
Dr Muhamedsalih was an invited attendee as an Early Career Researcher and he provided a video that was relevant to the project and lead discussions afterwards.
Prof. Rothman attended as WP6 lead which relates to sustainability so talked with industry and government officials about the project.
Year(s) Of Engagement Activity 2022
URL https://www.ukri.org/events/epsrc-engineering-net-zero-showcase/
 
Description EPSRC Responsive Manufacturing Showcase 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Met with other members of the group who also manage EPSRC responsive manufacturing grants. This has become an annual meeting to discuss our grants, advances made and to present details.
Year(s) Of Engagement Activity 2023
 
Description EPSRC Responsive Manufacturing meeting 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Prof Howse was invited to attend a meeting of other EPSRC funded academics who had been awarded similar responsive manufacturing grants. This was an opportunity to network and make connections with people of a similar research background. This will become an ongoing meeting following this first meeting.
Year(s) Of Engagement Activity 2022
 
Description EUSPEN 23rd International Conference & Event (Copenhagen, Denmark) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Invited talk to discuss advances in traditional precision engineering fields such as metrology, ultra precision machining, additive and replication processes, precision mechatronic systems & control and precision cutting processes. Provided a talk and presentation relating to aspects of the project.
Asked to provide a 1 day workshop at next years event (to be held in Dublin) relating to this project.
Year(s) Of Engagement Activity 2023,2024
URL https://www.euspen.eu/events/23rd-international-conference-exhibition-12th-16th-june-2023-2/?subid=2...
 
Description EUSPEN 24th International Conference & Event (Dublin, Ireland) 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact A dedicated workshop for this grant as part of the £4k funding awarded for impact. This was an outreach event to discuss progressive research & technical developments and to connect with academia and industry for further collaborations.
Year(s) Of Engagement Activity 2024
 
Description European Student Colloid Conference 2024, Bordeaux 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Conference on colloidal materials manufacturing and research
Year(s) Of Engagement Activity 2024
 
Description HPRG 61st conference: Polymers in water 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Attended a conference and took part in discussions.
Year(s) Of Engagement Activity 2023
URL https://highpolymer.org.uk/programme.php
 
Description Invited talk at the ICIT (25th IEEE International Conference on Industrial Technology) plus engagement on invited talks and panels 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Invited to speak at the conference, and also took part on panel interviews and invited talks
Year(s) Of Engagement Activity 2024
 
Description Materials Research Society Fall meeting & Exhibit 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Interdisciplinary cutting edge research and innovative new technologies. Presentation and opportunities for networking and collaboration
Year(s) Of Engagement Activity 2024
 
Description New Trends in Metrology, Lublin University of Technology and the Central Office of Weights and Measures 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact WP3 lead Dr Liam Blunt alongside Dr Hussam Mohamedsalih and Dr Mothana Hassan presented to an audience of industry and academics, including work that is relevant to this project.
Year(s) Of Engagement Activity 2022
URL https://polishscience.pl/en/international-metrology-conference-new-trends-in-metrology-held-in-lubli...
 
Description SPIE (Smart Structures & Nondestructive Evaluation) CA, USA 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact WP3 lead (Dr Liam Blunt) and WP5 lead (Dr Hussam Muhamedsalih) were invited to provide an abstract and to be invited speakers at this event in Long Island, California.
Year(s) Of Engagement Activity 2022
URL https://spie.org/conferences-and-exhibitions/smart-structures-nde?SSO=1
 
Description The Phd students linked to this grant have produced 3 documents for one of our industry sponsors, Ossila. 
Form Of Engagement Activity Engagement focused website, blog or social media channel
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact The articel documents can be viewed at https://www.ossila.com/pages/bar-coating https://www.ossila.com/pages/solution-processing-techniques-comparison https://www.ossila.com/pages/slot-die-coating-theory These articles have 1000s of views and are completely open access to the public. They also are among top google results for some relevant keywords; for example if you google "slot die coating" and "bar coating" these articles are among the first results.
Year(s) Of Engagement Activity 2024
URL https://www.ossila.com/pages/bar-coating
 
Description The Second GULF Metrology Forum 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Policymakers/politicians
Results and Impact Forum by the Ministry of Industry & Advance Technology (MOIAT) & Gulf Association of Metrology (GULFMET) - Key notes, panel discussions, etc.
Year(s) Of Engagement Activity 2024