Dispersion Strengthened Magnesium Alloys - Solidification of Nanocolloids
Lead Research Organisation:
Brunel University London
Department Name: BCAST
Abstract
Vehicle lightweighting represents a vital strand of an integrated national approach to transport decarbonisation. There is a general agreement that the CO2 emissions from cars needs to be cut by at least 50% to prevent the well-to-wheels carbon emission from the world car fleet rising above 7bn tonnes rather than the more sustainable 4bn tonnes by 2050. The UK Government has set an even higher target of a 60% reduction in transport sector CO2 emissions by 2030. Implementation of lightweighting across all classes of vehicles plays an important role in achieving this target.
Magnesium (Mg), as a lightest structural metal combined with superior damping capacity, has tremendous potential in achieving lightweighting in vehicles with improved noise, vibration and harshness performance. Recent Mg market research suggests that the global Mg alloys market will increase from £1 billion in 2018 to £2.8 billion by 2026, at a CAGR of ~12.7% between 2019 and 2026 which is expected to be driven by demand for Mg alloys from the automotive & transportation applications due to fuel efficiency and emission regulations. The automotive industry is aiming to increase Mg content from 8.6kg/car in 2017 to 45kg/car by 2030. Among variety of Mg alloys, aluminium containing Mg (Mg-Al) alloys are being used in automotive sector due to their competitive cost. However, their widespread use in vehicle is hindered by their lower strength. To help realise this growth and to meet the stringent design and safety criteria for lightweighting, it is necessary to enhance the strength of existing cost-effective Mg-Al alloys significantly.
The addition of rare-earth (RE) elements and noble metals in magnesium has been successfully utilised to achieve a significant improvement in strength. The alloys that have high RE content exhibit improved strength that meets lightweight design requirement. However, due to the resource scarcity and high cost, the alloys containing RE elements are impractical for their mass structural applications in automotive sector. The role of precipitation hardening in Mg alloys could be fulfilled by ex-situ phase particles, if they are dispersed within the Mg matrix rather than segregated at the grain boundaries. Substantiated by the proof-of-concept study, the proposed research programme aims to develop high strength, cost effective dispersion strengthened magnesium (DSM) alloys. It also investigates the criteria for the stability of nanocolloids, solidification behaviour and establishes process maps suitable for manufacturing DSM alloys using practical casting processes.
Technologically, the DSM alloys represent a step change in the manufacturing technology to produce lightweight automotive components. If certain Al and steel are replaced with DSM alloys, the expected weight saving would be significant. In the longer term, it will lead to a significant reduction in CO2 emissions and offer sizable fuel savings. The industrial partners, comprising a materials supplier, component producers, alloy designer and an end user are an added value and help to accelerate the knowledge transfer activity from academia to industry.
Magnesium (Mg), as a lightest structural metal combined with superior damping capacity, has tremendous potential in achieving lightweighting in vehicles with improved noise, vibration and harshness performance. Recent Mg market research suggests that the global Mg alloys market will increase from £1 billion in 2018 to £2.8 billion by 2026, at a CAGR of ~12.7% between 2019 and 2026 which is expected to be driven by demand for Mg alloys from the automotive & transportation applications due to fuel efficiency and emission regulations. The automotive industry is aiming to increase Mg content from 8.6kg/car in 2017 to 45kg/car by 2030. Among variety of Mg alloys, aluminium containing Mg (Mg-Al) alloys are being used in automotive sector due to their competitive cost. However, their widespread use in vehicle is hindered by their lower strength. To help realise this growth and to meet the stringent design and safety criteria for lightweighting, it is necessary to enhance the strength of existing cost-effective Mg-Al alloys significantly.
The addition of rare-earth (RE) elements and noble metals in magnesium has been successfully utilised to achieve a significant improvement in strength. The alloys that have high RE content exhibit improved strength that meets lightweight design requirement. However, due to the resource scarcity and high cost, the alloys containing RE elements are impractical for their mass structural applications in automotive sector. The role of precipitation hardening in Mg alloys could be fulfilled by ex-situ phase particles, if they are dispersed within the Mg matrix rather than segregated at the grain boundaries. Substantiated by the proof-of-concept study, the proposed research programme aims to develop high strength, cost effective dispersion strengthened magnesium (DSM) alloys. It also investigates the criteria for the stability of nanocolloids, solidification behaviour and establishes process maps suitable for manufacturing DSM alloys using practical casting processes.
Technologically, the DSM alloys represent a step change in the manufacturing technology to produce lightweight automotive components. If certain Al and steel are replaced with DSM alloys, the expected weight saving would be significant. In the longer term, it will lead to a significant reduction in CO2 emissions and offer sizable fuel savings. The industrial partners, comprising a materials supplier, component producers, alloy designer and an end user are an added value and help to accelerate the knowledge transfer activity from academia to industry.
Organisations
- Brunel University London (Lead Research Organisation)
- Caen University (Collaboration)
- Shanghai Jiao Tong University (Collaboration)
- Osaka University (Collaboration)
- SuperSTEM (Collaboration)
- Alloyed (Collaboration, Project Partner)
- Toyota Motor Europe NV SA (Project Partner)
- Shiloh Industries, Inc. (Project Partner)
- Magontec Group (Project Partner)
Publications
Cai Q
(2024)
Crack healing via electropulsing treatment applied to additive-manufactured TiC/316L stainless steel composites
in Materials Letters
Ignacio Ahuir-Torres J
(2024)
Corrosion behaviour of SiC particulate reinforced AZ31 magnesium matrix composite in 3.5 % NaCl with and without heat treatment
in Materials Chemistry and Physics
Nishi, S
(2025)
ISPlasma2025
| Description | We have demonstrated very high strength (700 MPa in comparison with 50-250 MPa in base alloys) in Mg alloys via dispersion of nano-scale particles in conventional casting methods. This has been also demonstrated in additive manufacturing of stainless steel and Nickel super-alloy. As the strengthening is originated from stable ceramic particles, this led to enhanced properties at elevated temperatures. |
| Exploitation Route | Demonstration of this to industries via collaborative partnerships |
| Sectors | Aerospace Defence and Marine Transport |
| Description | Aluminium alloy design strategy for sustainable manufacturing |
| Amount | £524,520 (GBP) |
| Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
| Sector | Public |
| Country | United Kingdom |
| Start | 03/2024 |
| End | 03/2027 |
| Description | Funding awarded to specific piece of research work |
| Amount | £50,000 (GBP) |
| Funding ID | 12502100 |
| Organisation | Alloyed |
| Sector | Private |
| Country | United Kingdom |
| Start | 04/2022 |
| End | 05/2023 |
| Description | International Collaboration |
| Amount | £12,000 (GBP) |
| Organisation | The Royal Society |
| Sector | Charity/Non Profit |
| Country | United Kingdom |
| Start | 03/2023 |
| End | 02/2025 |
| Description | International Exchanges 2023 Cost Share (NSFC) |
| Amount | £12,000 (GBP) |
| Funding ID | IEC\NSFC\233699 |
| Organisation | The Royal Society |
| Sector | Charity/Non Profit |
| Country | United Kingdom |
| Start | 03/2024 |
| End | 03/2026 |
| Description | Studentship |
| Amount | £48,000 (GBP) |
| Organisation | The Worshipful Company of Tin Plate Workers alias Wire Workers |
| Sector | Charity/Non Profit |
| Country | United Kingdom |
| Start | 03/2022 |
| End | 03/2026 |
| Description | Studentship |
| Amount | £48,000 (GBP) |
| Funding ID | 12486100 |
| Organisation | Alloyed |
| Sector | Private |
| Country | United Kingdom |
| Start | 03/2022 |
| End | 03/2026 |
| Description | Collaboration |
| Organisation | Alloyed |
| Country | United Kingdom |
| Sector | Private |
| PI Contribution | Hari Nadendla was invited to present light metals research at Alloyed. The team at alloyed interested in know-how of composites processing and how these could be achievable in additive manufacturing. |
| Collaborator Contribution | Alloyed offered extensive support in the form of offering AM machine hours, engineers time and contribution towards experimental plan. |
| Impact | Physical AM samples. Printing strategy development. |
| Start Year | 2022 |
| Description | Collaboration |
| Organisation | Caen University |
| Country | France |
| Sector | Academic/University |
| PI Contribution | In an invited lecture at ISS2022, Tsukuba, Prof Nadendla presented particle pushing trapping and role of nano-scale inclusions within the matrix and its impact on superconducting performance. This lecture caught attention of team at Crismat, University of Caen and we have had initiated collaboration work to explore the possibilities of creating in-situ formed reactive products within the matrix (rather than at grain boundaries). |
| Collaborator Contribution | Crismat offered an unique powder based manufacturing method to test the hypothesis of creating unique micro-structures. Extended technical support in help optimising the processing parameters. They hosted Professor Nadendla's visit to the lab for two weeks. Brunel University is currently assessing the mechanical properties of these materials. |
| Impact | Physical samples and property data-set |
| Start Year | 2022 |
| Description | International Exchanges 2022 Cost Share (JSPS) |
| Organisation | Osaka University |
| Country | Japan |
| Sector | Academic/University |
| PI Contribution | This collaboration was initiated during an invited lecture in Japan. Professor Nadendla has discussed the possible scientific reason for particle dispersion in liquid metals and entrapment of nano-particle by the solid growth front. This has attracted a research team who are specialised in producing nano-scale materials using a process which is typically used for producing electronic and Li-ion battery materials. There is a mutual interest here to understand entrapment or decoration of nanoparticles with some other phases. |
| Collaborator Contribution | The team offered Brunel to produce nano-scale metallic or ceramic or combined product to test the hypothesis. The team produced a first batch of material and Brunel just initiated the tests. |
| Impact | Japan team produced powders. Brunel conducted preliminary tests. |
| Start Year | 2022 |
| Description | Investigation of Metal-Ceramic interface in a dispersion strengthened magnesium alloy with advanced mechanical performance |
| Organisation | SuperSTEM |
| Country | United Kingdom |
| Sector | Public |
| PI Contribution | To fully utilize the lightweight properties of Mg alloys for reducing CO2 emissions in the automotive industry, a ceramic nano-phase strengthened Mg material has been fabricated using a liquid metal infiltration process in Brunel University of London. This ex-situ nano-ceramic strengthened pure Mg demonstrates a remarkable improvement in strength, achieving approximately 600 MPa compared to ~50 MPa for the reference pure Mg sample. This result confirms that Orowan strengthening can be achieved with ex-situ nano-phases, which function similarly to in-situ-formed precipitates. |
| Collaborator Contribution | To better understanding the underlying science that enables the infiltration of the nano particles with Mg melt, our collaborator investigated nano-phase strengthened Mg material. Using SuperSTEM facility, the following are examined • The chemical information of each atom in the region of the metal-ceramic interface. • The atomic distance, and crystallographic orientations between the nano phase and the metal phase on the interface. • The nature of the ceramic nano particles, chemical information, atomic structure and structural uniformity. |
| Impact | Results are being used in preparing a manuscript |
| Start Year | 2024 |
| Description | Tackling the strength-ductility trade off by nano particle reinforced metal matrix composite via non equilibrium solidification |
| Organisation | Shanghai Jiao Tong University |
| Country | China |
| Sector | Academic/University |
| PI Contribution | BUL discovered a reactive interfacial tuning (RIT) method for Mg/MgB2 system that can overcome these challenges. This method leads to favourable interfacial energies, resulting in uniform particle distribution within matrix grains, preserving ductility. |
| Collaborator Contribution | SJTU team has developed Ti-TiB system for high temperature applications, but leading to undesirable microstructure in which TiB particle segregates at grain boundaries. In this project, as Mg B and Ti-B systems are thermodynamically analogous to each other |
| Impact | Technical outputs are yet to be communicated. |
| Start Year | 2024 |
| Title | METHOD FOR CARBIDE DISPERSION STRENGTHENED HIGH PERFORMANCE METALLIC MATERIALS |
| Description | A method of preparing a mixture of a metal or metal alloy and (NbxTi1-x)C (where 0 |
| IP Reference | WO2022023738 |
| Protection | Patent / Patent application |
| Year Protection Granted | 2022 |
| Licensed | No |
| Impact | This patent application is now filed in various countries (EU, USA, Brazil and China). The European Patent Application No is 21765969.7. Application numbers for USA , Brazil and China are yet to be known from the patent attorney. |
| Title | Powder mixture for 3D printing |
| Description | The present invention relates to a flowable mixture for use in 3D printing, a method of preparing the same, and to a method of 3D printing using the mixture. In particular, it relates to a mixture of particles of a metal or metal alloy which are decorated with ceramic particles to aid flowability. |
| IP Reference | |
| Protection | Patent / Patent application |
| Year Protection Granted | |
| Licensed | No |
| Description | Invitation to deliver series of lectures in Continuous profession Development course on "Solidification" accredited by IOM3 and TMS professional bodies |
| Form Of Engagement Activity | A formal working group, expert panel or dialogue |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Industry/Business |
| Results and Impact | Over 20 industrial personnel have registered for this training workshop. Professor Nadendla delivered 5 sessions. During this one week intensive training programme, we have shared range of technical aspects which has the potential to raise their skill set so that it contributed quality and productivity in their industrial work places. The feedback is so encouraging that this course has become an annual event. |
| Year(s) Of Engagement Activity | 2024 |
| Description | Invited lecture at a company (Chinalco Materials Application Research Institute Co., Ltd, China) |
| Form Of Engagement Activity | A talk or presentation |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Industry/Business |
| Results and Impact | 30 people have attended and the location is in Suzhou Industrial Park, Jiangsu Province, China. Presentation date is 12th March. The talk was focused on high strength multi-component diecasting alloys. |
| Year(s) Of Engagement Activity | 2024 |
| Description | Invited lecture on high pressure die casting at Degree Apprenticeship for Jaguar and Land Rover engineers and technicians |
| Form Of Engagement Activity | A formal working group, expert panel or dialogue |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Industry/Business |
| Results and Impact | Delivered a lectures on Fundamentals in solidification (related to die casting); Principles and key process cycle in HPDC; Alloys selection and typical automotive castings made from HPDC; Basic approaches in die design and mould filling; Casting defects and current approaches in enhancing casing integrity; Advantages/limitations of HPDC; Challenges & opportunities; Recent developments in giga casting. |
| Year(s) Of Engagement Activity | 2024 |
| Description | The 12th National Academic Conference on Special Casting and Non-ferrous Alloys |
| Form Of Engagement Activity | A talk or presentation |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Industry/Business |
| Results and Impact | Dr Qing Cai has delivered lecture on "The development of high strength of low pressure die casting alloys applied in elevated temperatures" |
| Year(s) Of Engagement Activity | 2024 |