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North East Ultrafast Transient Absorption Spectroscopy Facility

Lead Research Organisation: Newcastle University
Department Name: Sch of Natural & Environmental Sciences

Abstract

This unique national facility for ultrafast transient absorption spectroscopy (and microscopy) aims to fulfil a strategically and critically important research infrastructure gap in the North East.

Transient absorption spectroscopy is a key tool that enables scientists to probe the identity, formation and fate of short-lived, energetic species formed on excitation with light (e.g. from a laser). Once a molecule or material has absorbed light, there are a number of possible pathways it could follow, including re-emission, thermal relaxation, energy or electron transfer and a chemical reaction (including decomposition). Probing with broad-band UV-NIR light at various time delays after excitation enables difference spectra to be captured, providing information on the electronic excited states (which have distinct absorption spectra from the ground state) and their lifetime (which depends on the electronic state and fate of the excited species). These processes occur over a range of timescales, mostly ranging from femtoseconds to microseconds for energy or charge-transfer and chemical reactivity. The information is vital across chemistry, physics, biology and engineering. Transient absorption spectroscopy is a vital tool for fundamental understanding of processes such as energy harvesting in photosynthetic organisms, multi-exciton generation semiconductor quantum dots and charge-recombination in printable photovoltaics.

The Helios-EOS Fire Transient Absorption Spectrometer will give us access to the entire timescale of physical phenomena that take place during chemical reactions and light-induced processes more broadly. This will foster and open new research areas, stimulating collaborations with groups working in physics, chemical/synthetic biology and engineering, and will make spectroscopy capabilities in the North East internationally competitive. With the broad temporal and spectral window, together with microscope extension and Newcastle University expertise of operando experiments, it will provide critical knowledge required to address the scientific challenges preventing commercialisation of novel optoelectronic devices (stability, conversion efficiency etc.). The national facility will reduce the need to depend on international collaborators, increasing the capacity and ambition of the research, and strengthens the North East region's capacity to provide for spectroscopists and materials scientists.

The multidisciplinary science enabled by the national facility underpins all four EPSRC Prosperity Outcomes and the four Industrial Strategy Grand Challenges. It will support the development of light-responsive molecules and materials for sensors and communication devices that transmit or are powered by light for applications in AI and the Data Driven Economy. The facility will provide information on charge-separation, accumulation and recombination in solar cells and artificial photosynthetic devices for sustainable fuels and feedstocks for Clean Growth and Future Mobility (such as green power and hydrogen for transport). It will address innovation for the Ageing Society by supporting the design of new phototherapies or diagnostic tools such as bioimaging.
These grand challenges align with the research pillars at Newcastle University and the surrounding institutions, and a facility situated in the North East will support regional, national and international collaboration to accelerate discoveries and innovation in these societally important areas. It will also support blue-skies research in light-matter interactions from atoms to systems that will have long-term impact in future innovation.
 
Description So far, we have discovered the relationship between the structure of a variety of charge-transport materials in solar cells and the dynamics of charge transfer, which determines the solar conversion efficiency (i.e. the performance of the device). A post-doctoral researcher who is a regular user of the facility has been awarded a post-doctoral fellowship. Several papers are still under review.

We have learned how coatings on semiconductors affects the lifetime of the free charge carriers after the material absorbs light. This information is being used to develop better materials and devices for solar power and solar fuels and chemicals. A recent paper was published in Dalton Transactions (front cover).

We have explored the charge-transfer between the inorganic electrodes and biofilms, with promising results. The ability to tune the wavelengths and extended timescales from fs to us is extremely helpful. A paper has been submitted to Nature Catalysis. Further research will be conducted to establish the mechanism for electron transfer into
Electrotrophs.
Exploitation Route We are attracting further collaborations based on these results, with more internships planned (Liverpool, Strathclyde, Sheffield, Cambridge, Dublin). New design rules for materials can be generally applied in the field. Translating approach to soft matter and healthcare applications.
Sectors Aerospace

Defence and Marine

Chemicals

Digital/Communication/Information Technologies (including Software)

Energy

Environment

Manufacturing

including Industrial Biotechology

 
Description Recruitment and training of key staff, retention of key staff, new collaborations with industry (studentships with P&G, JM; IAA proposals awarded with in-kind support - PSRC-MRC IAA Ideas to Innovation: Optical Pathology (£16 928, NU-019073) with Croda, P&G 19/4/2024 to 19/7/2024). Further applications have been made to the NNZA Place Based Impact Accelerator to move up the devices studied further along the technology readiness pathway.
First Year Of Impact 2023
Sector Aerospace, Defence and Marine,Chemicals,Digital/Communication/Information Technologies (including Software),Education,Energy,Environment,Healthcare
Impact Types Societal

Economic

 
Description EP/X035050/1 Newcastle University EPSRC Core equipment Award 2022, PI Prof Ian Head.
Amount £870,047 (GBP)
Funding ID EP/X035050/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 01/2023 
End 07/2024
 
Description EPSRC Centre for Doctoral Training in Renewable Energy Northeast Universities Plus (ReNU+)
Amount £5,289,248 (GBP)
Funding ID EP/Y035542/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 05/2024 
End 09/2032
 
Description Newcastle University EPSRC Core Equipment Award 2022
Amount £870,047 (GBP)
Funding ID EP/X035050/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 01/2023 
End 07/2024
 
Description The Solar Chemicals Network
Amount £222,023 (GBP)
Funding ID EP/X035301/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 06/2023 
End 06/2026
 
Title Ideas to Innovation: Optical Pathology 
Description PI EPSRC-MRC IAA (£16 928, NU-019073) with Croda, P&G We have begun to develop a new method for providing information on skin health using transient absorption microscopy of melanin in skin. 
Type Of Material Improvements to research infrastructure 
Year Produced 2024 
Provided To Others? No  
Impact So far were were able to resolve different types of melanin according to their transient absorption spectra and lifetime. However further work is needed because we were unable to scale from solution to cells. 
 
Title Time-resolved spectroelectrochemistry with spatial resolution 
Description At the facility we are particularly interested in interrogating more developed photovoltaic devices. To this end we have been focusing on developing our capability in performing transient spectra on samples that are under a potential bias as active devices are likely to show differences as compared to results seen without potential applied. Devices in operation will have a voltage across them in operation so we wish to see how the kinetics of systems change under bias. In addition we use this method with a microscope attachment allowing us to target specific pixels on cells to understand device variability. 
Type Of Material Improvements to research infrastructure 
Year Produced 2023 
Provided To Others? No  
Impact We have established the technique and are applying it to various cells and this will inform our future direction. 
 
Title CCDC 2232318: Experimental Crystal Structure Determination 
Description Related Article: Richard D. James, Linah S. Alqahtani, John Mallows, Heather V. Flint, Paul G. Waddell, Owen J. Woodford, Elizabeth A. Gibson|2023|Sustainable Energy Fuels|7|1494|doi:10.1039/D2SE00977C 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
Impact contribution to paper - scientific impact through downloads and cites 
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc2dxx8j&sid=DataCite
 
Title CCDC 2232319: Experimental Crystal Structure Determination 
Description Related Article: Richard D. James, Linah S. Alqahtani, John Mallows, Heather V. Flint, Paul G. Waddell, Owen J. Woodford, Elizabeth A. Gibson|2023|Sustainable Energy Fuels|7|1494|doi:10.1039/D2SE00977C 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
Impact contribution to paper - scientific impact through downloads and cites 
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc2dxx9k&sid=DataCite
 
Description Biohybrid devices for Artificial Photosynthesis 
Organisation Northumbria University
Country United Kingdom 
Sector Academic/University 
PI Contribution Our team provides the analytical expertise and facilities to characterise devices constructed using photocathodes developed in our research lab. This includes advanced spectroscopy from the EPSRC NU TAS facility.
Collaborator Contribution The partners at Northumbria provide expertise in engineering biology to grow the functional biofilms on the electrodes. The current or hydrogen provided by the photocathodes under illumination from simulated sunlight (experiments at Newcastle) generate fuel and feedstocks from water and CO2. The choice of microbe determines the product.
Impact This is sponsored by Johnson Matthey and P&G and funding has been received from the Solar Chemicals Network - two PhD students so far and travel money to support collaboration. Publications are listed.
Start Year 2023
 
Description Collaboration with Liverpool University 
Organisation University of Liverpool
Country United Kingdom 
Sector Academic/University 
PI Contribution The NU TAS facility was used to explore the photophysics of high entropy alloy co-catalysts on metal oxides - specifically in the ns-us regime.
Collaborator Contribution Liverpool provided access to their ultrafast spectroscopy facility for the NU TAS scientific officer to test dyes and electron transport materials for new solar cells. This also gave him experience of ultrafast spectroscopy ready for the installation of our own system.
Impact new skills new knowledge The papers are included in the relevant section. More are expected to be published in the near future.
Start Year 2022
 
Description Durham University - Novel Materials 
Organisation Durham University
Country United Kingdom 
Sector Academic/University 
PI Contribution We will perform Transient Spectroscopy on some novel materials with engineered intra bandgap states.
Collaborator Contribution Partners have developed novel materials
Impact At data collection stage
Start Year 2024
 
Description Glasgow perovskites 
Organisation University of Glasgow
Country United Kingdom 
Sector Academic/University 
PI Contribution Recording transient spectra of non-transmissive perovskite materials.
Collaborator Contribution Glasgow team members prepare multi-layer films of perovskite materials.
Impact These initial experiments will inform future direction and are intended to be in support of imminent funding applications.
Start Year 2023
 
Description Internship Student from Poland: Erasmus funding for 'traineeship'. 
Organisation West Pomeranian University of Technology
Country Poland 
Sector Academic/University 
PI Contribution Daria Baranowska was hosted at Newcastle University to conduct research on photocatalysis, (photo)eletrocatalysis, hydrogen generation using carbon nitride materials. She was provided access to the NU TAS facility to characterise her materials. We conducted several weeks of experiments to support her post-graduate research project.
Collaborator Contribution Daria Baranowska brought functionalised Carbon Nitride materials to test for hydrogen evolution and transient absorption spectroscopy.
Impact The results have not yet been published. The student learned about transient absorption spectroscopy and how the technique applies to her materials and their applications.
Start Year 2023
 
Description NiO Photosensitizers from Dublin City University 
Organisation Dublin City University
Country Ireland 
Sector Academic/University 
PI Contribution We have tested the transient absorption spectroscopy of some photocatalysts immobilised on NiO. Successful combinations were tested in photoelectrochemical devices for hydrogen evolution.
Collaborator Contribution Student at DCU prepared new photocatalysts which we tested.
Impact Paper at draft stage. Training: Student visited Newcastle for 2 weeks in November/December 2024.
Start Year 2024
 
Description Polyoxometalate-bodipy hybrids 
Organisation Sorbonne University
Country France 
Sector Academic/University 
PI Contribution Our research team prepared dye-sensitized photocathodes using their POM-bodipy hybrids and tested them in solar cells and using transient absorption spectroscopy (using the EPSRC NU TAS facility). The results enabled them to re-configure their structure to improve charge-transfer and device performance.
Collaborator Contribution The partners are based at CNRS France - IRN Network - Chemical and energy research - artificial photosynthetic devices They initially prepared three samples of POM-bodipy hybrids that were designed to promote light-induced charge transfer when adsorbed on NiO. Further samples are being sent with improved performance based on the data we provide from our experiments. This is an ongoing collaboration and publications are expected in due course.
Impact Inorganic Chemistry, Physical Chemistry, Materials Science.
Start Year 2023
 
Description University of Huddersfield 
Organisation University of Huddersfield
Country United Kingdom 
Sector Academic/University 
PI Contribution We have recorded spectra on the NE transient absorption spectroscopy facility.
Collaborator Contribution The Huddersfield team have prepared novel photoactive compounds.
Impact Publication in draft
Start Year 2023
 
Description CPACT Webinar 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact Presented research on renewable power, fuel and feedstocks to CPACT, which is a consortium of businesses via webinar
Year(s) Of Engagement Activity 2024
 
Description IoP Solar Hydrogen Webinar 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Participated in international webinar on solar routes to hydrogen led by the IoP
Year(s) Of Engagement Activity 2024
 
Description Keynote talk ISPPCC Ulm 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Keynote lecture at International Conference, stimulated further discussion and collaboration.
Year(s) Of Engagement Activity 2023
URL https://www.uni-ulm.de/isppcc/home/
 
Description P&G visit to Newcastle 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact Visit to demonstrate facility to P&G. Proposal submitted for collaboration through proof of concept award.
Year(s) Of Engagement Activity 2023
 
Description Visit from Johnson Matthey 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact Team from Johnson Matthey visited to discuss future collaborations
Year(s) Of Engagement Activity 2024