Supramolecular Synthesis of Molecular Clusters: Topological Control of Hybrid Nanomagnets

Lead Research Organisation: University of Edinburgh
Department Name: Sch of Chemistry

Abstract

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Publications

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Wilson LRB (2022) The coordination chemistry of p-tert-butylcalix[4]arene with paramagnetic transition and lanthanide metal ions: an Edinburgh Perspective. in Dalton transactions (Cambridge, England : 2003)

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Tian J (2012) Selective metal cation capture by soft anionic metal-organic frameworks via drastic single-crystal-to-single-crystal transformations. in Journal of the American Chemical Society

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Taylor SM (2012) Oxacalix[3]arene-supported supertetrahedron. in Chemical communications (Cambridge, England)

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Taylor SM (2012) Calixarene-supported clusters: employment of complementary cluster ligands for the construction of a ferromagnetic [Mn5] cage. in Chemical communications (Cambridge, England)

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Taylor SM (2011) A family of calix[4]arene-supported [Mn(III)2Mn(II)2] clusters. in Chemistry (Weinheim an der Bergstrasse, Germany)

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Taylor SM (2012) p-tert-Butylcalix[8]arene: an extremely versatile platform for cluster formation. in Chemistry (Weinheim an der Bergstrasse, Germany)

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Taylor S (2011) Calix[4]arene supported clusters: a dimer of [Mn III Mn II ] dimers in Chem. Commun.

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Meally ST (2012) Investigating the solid state hosting abilities of homo- and hetero-valent [Co7] metallocalix[6]arenes. in Dalton transactions (Cambridge, England : 2003)

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McLellan R (2014) Discovering the pivotal role of carbonate in the formation of a bis-phenolate supported Co15 cluster. in Chemical communications (Cambridge, England)

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McIntosh RD (2011) p-tert-Butylcalix[8]arene: a support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties. in Dalton transactions (Cambridge, England : 2003)

 
Description The first use of calix[n]arenes to construct homo- and heterometallic cluster compounds for use as single-molecule magnets and magnetic refrigerants.
Exploitation Route Fundamental chemistry and physics which underpins potential application in materials science.
Sectors Chemicals
URL http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin