Understanding and engineering function in switchable molecular crystals
Lead Research Organisation:
University of Bath
Department Name: Chemistry
Abstract
Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.
Organisations
Publications
Kulmaczewski R
(2017)
The role of symmetry breaking in the structural trapping of light-induced excited spin states.
in Chemical communications (Cambridge, England)
Kulmaczewski R
(2023)
Di-Iron(II) [2+2] Helicates of Bis-(Dipyrazolylpyridine) Ligands: The Influence of the Ligand Linker Group on Spin State Properties.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Deeth RJ
(2018)
Ab Initio Ligand Field Molecular Mechanics and the Nature of Metal-Ligand p-Bonding in Fe(II) 2,6-di(pyrazol-1-yl)pyridine Spin Crossover Complexes.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Kulmaczewski R
(2021)
Structural Transformations and Spin-Crossover in [FeL2 ]2+ Salts (L=4-{tert-Butylsulfanyl}-2,6-di{pyrazol-1-yl}pyridine): The Influence of Bulky Ligand Substituents.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Pask CM
(2020)
Elucidating the Structural Chemistry of a Hysteretic Iron(II) Spin-Crossover Compound From its Copper(II) and Zinc(II) Congeners.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Kulmaczewski R
(2021)
Influence of ligand substituent conformation on the spin state of an iron(II)/di(pyrazol-1-yl)pyridine complex.
in Dalton transactions (Cambridge, England : 2003)
Greatorex S
(2020)
Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn-Teller Distortion.
in Inorganic chemistry
Leroy L
(2021)
Controlled Light and Temperature Induced Valence Tautomerism in a Cobalt-o-Dioxolene Complex.
in Inorganic chemistry
Capel Berdiell I
(2021)
Structures and Spin States of Iron(II) Complexes of Isomeric 2,6-Di(1,2,3-triazolyl)pyridine Ligands
in Inorganic Chemistry
Halcrow MA
(2019)
Relationship between the Molecular Structure and Switching Temperature in a Library of Spin-Crossover Molecular Materials.
in Inorganic chemistry
Description | The is a second component of the grant with the same title in my portfolio, and is now held in Bath because Professor Robert Deeth, formerly of the University of Warwick, has moved to Bath. He has been undertaking computational studies on spin crossover complexes, and we are using his input to direct and underpin our synthetic studies. We have established control over the temperature related switching properties of new classes of spin crossover materials. |
Exploitation Route | Other may use the knowledge that we have gained in the control of the spin crossover temperature and the width of the hysterisis loop to design magnetically switching materials. |
Sectors | Digital/Communication/Information Technologies (including Software),Electronics,Energy |