Manufacturing Bio-inspired "Artificial Wood" from (Low-Cost) Ionic Liquids
Lead Research Organisation:
Imperial College London
Department Name: Aeronautics
Abstract
There is currently a timely need to design and manufacture renewable materials for high volume structural applications and decouple our economy from fossil-derived non-renewable resources. Cellulose-based natural fibres are the prime candidate for the production of low-cost high-performance renewable composites. However, there is still a property-performance gap between natural fibre-reinforced polymers and traditional fossil-derived engineering materials (see Fig. 1), as the high tensile stiffness (up to 165 GPa) and strength (at least 1 GPa) of cellulose microfibrils have yet to be fully exploited in a composite setting. Nature has been very efficient at manipulating and exploiting cellulose microfibrils in wood (a natural composite) to produce high performance materials. This project will take inspiration from wood and manufacture the world's first "artificial wood", i.e. cellulose microfibril-reinforced lignin composites with the native cellulose-I structure preserved (mimicking wood cell wall), using simple and intrinsically scalable manufacturing concepts. The proposed research activities are structured around (i) manufacturing "artificial wood" from (low cost) ionic liquid, (ii) design and manufacture of unidirectional and continuous "artificial wood" fibre-reinforced renewable composites and (iii) optimising the techno-economics and lifecycle of "artificial wood"
manufacturing. It is envisaged that the resulting "artificial wood" will target engineering applications that cannot be achieved by conventional bio-based polymers or renewable natural fibre-reinforced polymers alone and could serve as alternative to traditional glass fibre-reinforced polymers.
manufacturing. It is envisaged that the resulting "artificial wood" will target engineering applications that cannot be achieved by conventional bio-based polymers or renewable natural fibre-reinforced polymers alone and could serve as alternative to traditional glass fibre-reinforced polymers.
Description | We found that lignin can be extracted and re-deposited onto the surface of wood particles. This then allowed us to "fuse" discrete wood particles together through the softening of the lignin on the surface, consolidating them into a homogenous "artificial wood" structure. |
Exploitation Route | The aforementioned method could be applicable to re-use saw dust, which is typically burned in open fields. |
Sectors | Construction |
Description | Co-creation partnership fund |
Amount | £25,000 (GBP) |
Organisation | Unilever |
Sector | Private |
Country | United Kingdom |
Start | 12/2021 |
End | 11/2022 |
Description | EPSRC-iCASE: Flexible packaging films derived solely from lignocellulosic biomass - how far can we go to replace fossil-derived flexible plastic packaging |
Amount | £150,000 (GBP) |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 10/2023 |
End | 09/2027 |
Description | Imperial College London President's Excellence Fund for Frontier Research |
Amount | £315,970 (GBP) |
Organisation | Imperial College London |
Sector | Academic/University |
Country | United Kingdom |
Start | 10/2021 |
End | 09/2024 |
Description | Unilever |
Organisation | Unilever |
Department | Unilever UK R&D Centre Port Sunlight |
Country | United Kingdom |
Sector | Private |
PI Contribution | On the use of specific ionic liquids to manufacture cellulose/lignin films with barrier properties comparable to those of fossil-derived resources. |
Collaborator Contribution | Additional funding (on other projects), database, industrial confidential knowledge. |
Impact | Two iCASE awards, one co-creation partnership fund, one Royce Industrial Collaboration Partnership fund. |
Start Year | 2021 |