Terahertz-frequency sensors for atmospheric chemistry and space research (renewal)

Lead Research Organisation: University of Leeds
Department Name: Electronic and Electrical Engineering

Abstract

When we look into space with existing infrared, radio and microwave sensors, we see less than half the light in our galaxy. Most of this "missing" light lies in the terahertz (THz) or far-infrared part of the spectrum (1-10 THz, 30-300 micron wavelength). Indeed, the "invisible" gases in the Earth's atmosphere and the "dark" dust and gas clouds between stars all glow with distinctive THz fingerprints, providing a wealth of hidden information urgently needed by atmospheric and space scientists.

Despite this great potential, existing THz sensor systems are too large, fragile and complex for most applications outside the laboratory and lack the sensitivity needed for studying reactive gases. Furthermore, this lack of technological readiness limits the prospects for THz systems being deployed in space. A short time-window is available for the UK to invest in real-world demonstrations of key THz components and sensing techniques and secure a place in forthcoming space missions, for example, via the ESA Earth Explorer 12 (or 13) programmes. Without this, the potential for a UK researcher to lead the world in this emerging area will be lost.

In this fellowship, I am overcoming limitations of THz gas sensors by developing high-sensitivity systems based on quantum-cascade lasers (QCLs) - highly compact sources of THz radiation, which yield >1000 times the power of any similar-sized device. I have developed new project partnerships to exploit extremely fast and stable TeraFET detectors, enabling tiny changes in gas concentrations to be measured in real time. Unlike previous THz-QCL-based gas-sensing schemes, I am developing high-precision analytical chemistry techniques, and have developed the first custom-made multi-pass gas cell in which THz radiation passes repeatedly through the gas under study, yielding an estimated 100x improvement in sensitivity.

In this Renewal phase of the fellowship, I will adapt my internationally-leading THz gas sensing instrumentation to use an ultraviolet (UV) laser to simulate the behaviour of gases in the upper atmosphere, and "trigger" chemical reactions at a precise time. This will allow me to study the behaviour of volatile organic compounds (VOCs) such as formaldehyde as they react in the atmosphere, and resolve the huge uncertainties in the effect of these reactions on climate change. By developing fast detection schemes, I will provide the means to study the concentrations of industrial and agricultural pollutants in real time, and I will investigate the potential for UV-pump/THz-probe "step-scan" detection technique to probe the dynamics of upper-atmospheric reactions on microsecond timescales.

Through my partnership with RAL Space, I have demonstrated the world's first integration of THz QCLs with precision-micromachined waveguides, antennas, and "on-chip" stabilisation subsystems. This Renewal phase will provide a further step-change in capability, by developing the first satellite-compatible THz laser stabilisation schemes, through the use of integrated power and frequency control systems, within "sugarcube"-sized satellite-compatible modules. I will work with RAL Space, and TK Instruments to demonstrate this capability within a space-qualified cryocooler, including bespoke THz optics and calibration targets, on a satellite-test "breadboard", underpinning its future deployment on a satellite platform.

To sustain my research vision, and establish THz sensing as a key tool for atmospheric and space research, I will work closely with my project partners to secure follow-on funding for THz chemistry, Earth observation and critical satellite payload instrumentation. I will produce a roadmap for in-orbit deployment, and commercialisation, including developing the science and technology case for a European Space Agency satellite mission through the Earth Explorer programme.
 
Description The findings of this work (principally, the development of the first compact, and integrated THz systems) have advanced the design and development of the KEYSTONE atmospheric sounding mission. This satellite proposal has been accepted for a Phase-0 study under the European Space Agency (ESA) Earth Explorer 12 programme, and aims to provide the first global mapping of key gas species in the Earth's upper atmosphere, using THz receivers, and providing critical missing data for climate models. As an invited academic presenter, Dr Valavanis has engaged in round-table consultations with senior leaders from UK industry as part of a CEOI Industrial Consultation Workshop on Millimetre-Wave, Microwave and Terahertz Remote Sounding. The discussion incorporated the results of this programme, including the newly developed compact THz spectroscopy apparatus and integration techniques. This meeting has led to the publication of a consultation document, which will be used by the CEOI and the wider UK Space Agency to inform the focus for future funding and to maximise the potential for space-related technologies to be used in wider non-space industrial fields.
First Year Of Impact 2024
Sector Electronics,Environment
Impact Types Policy & public services

 
Description Enhancements in terahertz spectrometry and beam profiling at the University of Leeds
Amount £210,383 (GBP)
Funding ID RP16W506420D02 
Organisation UK Space Agency 
Sector Public
Country United Kingdom
Start 11/2024 
End 03/2025
 
Title Data associated with "Power stabilization of a terahertz-frequency quantum-cascade laser using a photonic-integrated modulator" 
Description This dataset is associated with the manuscript "Power stabilization of a terahertz-frequency quantum-cascade laser using a photonic-integrated modulator". We demonstrate a technique to stabilize the emission from a ~3.5 THz quantum-cascade laser against long-term power drifts, using a recently developed Photonic Integrated Circuit (PIC) structure formed by coupling a racetrack resonator with a ridge waveguide. Successful locking over >600 s was achieved using a proportional-integral control loop. A technique for integrating the PIC with a precision micromachined rectangular metallic waveguide module has also been demonstrated. 
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
Impact This data underpinned a publication in Optics Express https://doi.org/10.1364/OE.529879 
URL https://archive.researchdata.leeds.ac.uk/1308/
 
Description Rutherford Appleton Labs - FLF partnership 
Organisation Rutherford Appleton Laboratory
Department RAL Space
Country United Kingdom 
Sector Academic/University 
PI Contribution Fabrication and optimisation of terahertz-frequency quantum-cascade lasers for use in integrated satellite-borne receivers. Characterisation of integrated QCL devices and far-field THz power mapping. Development and calibration of multi-pass gas spectroscopy instrumentation.
Collaborator Contribution Development of micromachined waveguides and antennas for THz sources; integration of THz sources with Schottky-barrier mixers; characterisation of materials; phase-locking of THz sources; provision of bespoke gas-cell optics; simulation and analysis of THz gas spectra.
Impact Invited conference presentations at CLEO, San Jose (DOI:10.1364/CLEO_AT.2019.AW3P.5) and IEEE MTT-S, Guangzhou (DOI:10.1109/IEEE-IWS.2019.8803875). This is a multi-disciplinary collaboration, bringing together expertise in laser spectroscopy (D. Weidmann, RAL Space), atmospheric retrieval simulations (D. Gerber, RAL Space), millimetre-wave engineering and manufacturing (B. Ellison & D. Pardo, RAL Space), with atmospheric chemistry (J. Lehman, Leeds) and THz quantum-cascade instrumentation (A. Valavanis, Leeds)
Start Year 2019
 
Description TeraFET development 
Organisation Goethe University Frankfurt
Country Germany 
Sector Academic/University 
PI Contribution Characterisation of TeraFET detectors, and applications development. Hosting of two visiting postgraduate researchers during placement visits. Laboratory access, and design consultation from senior academic staff. Contribution to the writing of a successful DFG funding proposal to develop THz mixers and fast detectors based on FET technology.
Collaborator Contribution Design and supply of TeraFET detectors at frequencies applicable to quantum-cascade laser sources. Meetings and design consultations with senior academic staff.
Impact Successful DFG funding proposal to develop THz mixers and fast detectors based on FET technology.
Start Year 2022
 
Description Invited research seminar (Ajou University) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Approx 20 postgraduate researchers attended a public-interest talk on the outputs of this programme. This was followed by a discussion about bilateral UK-Korea opportunities for collaborative THz research, which fed into an application for an EPSRC THz network proposal.
Year(s) Of Engagement Activity 2024
 
Description Invited research seminar (Queen Mary University London) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Postgraduate students
Results and Impact Approximately 20 postgraduate researchers and academic staff attended a public interest talk on the outputs of this programme. This was followed by a discussion with potential collaborators for a bilateral UK-German research funding bid.
Year(s) Of Engagement Activity 2024
URL https://www.qmul.ac.uk/eecs/news-and-events/events/items/seminar-terahertz-quantum-cascade-laser-ins...
 
Description Terahertz, Microwave and Millimetre Technologies for Earth Observation Workshop 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact A consultation meeting took place between academic researchers, grant awarding bodies, and industrial beneficiaries. The workshop contributed to a roadmapping exercise, which will influence UK Space technology strategy.
Year(s) Of Engagement Activity 2025
URL https://ceoi.ac.uk/events/terahertz-microwave-and-millimetre-technologies-for-earth-observation/